公开(公告)号：WO2015028156A1

公开(公告)日：2015-03-05

申请号：PCT/EP2014/002373

申请日：2014-09-02

Applicant: BIOCHEMTEX S.P.A.

Inventor： RIVAS TORRES, Beatriz ,  GIORDANO, Dario ,  GHISOLFI, Guido ,  BERNARDI, Marco ,  TODARO, Daniela ,  BOZZANO, Irene ,  CRIPPA, Tommaso

IPC: C08G63/16 ,  C08G63/183

CPC classification number: C08G63/183 ,  C08G63/16

Abstract: The present specification discloses a composition comprising a plurality of diols which is useful for the production of polyester bottles, wherein the diols are mainly obtained from the conversion of a ligno-cellulosic biomass feedstock stream. The composition comprises ethylene glycol and at least one diol selected from the group of diols having a formula of C n H z (OH) 2 , wherein n is the total number of carbons and is an integer in the range from 3 to 20, z is an integer in the range from 0 to 2n, and C 1 and C 2 are each attached to one of the OH groups of the formula (e.g. 1,2-Propylene glycol, 1,2-Butanediol and 1,2-Pentanediol) and wherein the composition is substantially free of diols which absorb light at a wavelength of 275nm, so that the percent light transmission of the composition at a wavelength of 275nm is greater than 40%.

Abstract translation: 本说明书公开了一种组合物，其包含可用于生产聚酯瓶的多个二醇，其中二醇主要由木质纤维素生物质原料流的转化获得。 该组合物包含乙二醇和选自具有式CnH 2（OH）2的二醇的至少一种二醇，其中n是碳的总数，并且是3-20的整数，z是整数 在0至2n的范围内，并且C1和C2各自连接到下式的OH基之一（例如1,2-丙二醇，1,2-丁二醇和1,2-戊二醇），其中组合物为 基本上不含吸收波长为275nm的光的二醇，使得组合物在275nm波长处的百分比透光率大于40％。

公开(公告)号：WO2015049060A1

公开(公告)日：2015-04-09

申请号：PCT/EP2014/002707

申请日：2014-10-06

Applicant: BIOCHEMTEX S.p.A.

Inventor： CHERCHI, Francesco ,  GIORDANO, Dario ,  DE FAVERI, Danilo ,  GIUNGATO, Ezio ,  MULUGETA, Kebede

IPC: C10J3/30 ,  F23G5/44

CPC classification number: C10J3/30 ,  C10J2200/158 ,  F23G5/444 ,  F23G2202/30 ,  F23G2205/121 ,  F23G2205/18 ,  F23K2203/103 ,  F23K2203/202 ,  F23K2900/03001

Abstract: It is disclosed a system for feeding a ligno-cellulosic feedstock (50) to a pressurized vessel (200) having a vapor or gas phase of at least one fluid maintaining a vessel pressure greater than or equal to 1 bar. The pressurized vessel comprises a feedstock inlet (230), a feedstock outlet (220), a top and a bottom relative to the force of gravity, wherein the feedstock outlet is closer to the bottom of the pressurized vessel than the feedstock inlet. The feeding system further comprises a plug forming system (100) comprising a plug forming device (105) located in a plug forming chamber (130), the chamber having a first end (110B) and a second end (110A), said first end having a first end operating pressure which is lower than the vessel pressure and said second end being connected to the feedstock inlet and having a second end operating pressure which is greater than the first operating pressure. Said plug forming device is capable of receiving the ligno-cellulosic feedstock at the first end pressure; advancing the ligno-cellulosic feedstock through the plug forming chamber; and forming a plug from the ligno-cellulosic feedstock which prevents the passage of the vapor or gas phase from the pressurized vessel. The feeding system further comprises a sealing head located inside the pressurized vessel, which is movable at a seal opening speed between a sealing position located at the feedstock inlet and a rest position, wherein the sealing head in the sealing position isolates the pressurized vessel from the plug forming chamber. The seal opening speed is fast enough so that the sealing head disengages from the feedstock before or at the moment the sealing head reaches the rest position. The sealing head in the rest position is located at a distance far enough away from the feedstock inlet (sealing head) so that the feedstock entering the pressurized vessel does not contact the sealing head.

Abstract translation: 公开了一种用于将木质纤维素原料（50）进料至具有保持容器压力大于或等于1巴的至少一种流体的蒸汽或气相的加压容器（200）的系统。 加压容器包括原料入口（230），原料出口（220），相对于重力的顶部和底部，其中原料出口比原料入口更靠近加压容器的底部。 所述进料系统还包括塞形成系统（100），其包括位于塞子形成室（130）中的塞子形成装置（105），所述腔室具有第一端（110B）和第二端（110A），所述第一端 具有低于容器压力的第一端操作压力，并且所述第二端连接到原料入口并且具有大于第一操作压力的第二端操作压力。 所述塞子形成装置能够在第一端部压力下接收木质纤维素原料; 推进木质纤维素原料通过塞子形成室; 并从木质纤维素原料形成塞子，其阻止蒸气或气相从加压容器通过。 进料系统还包括位于加压容器内部的密封头，其可以在位于原料入口处的密封位置和静止位置之间的密封打开速度下移动，其中密封位置中的密封头将加压容器与 塞形成室。 密封打开速度足够快，使得密封头在密封头到达静止位置之前或之时脱离原料。 处于静止位置的密封头位于距离原料入口（密封头）足够远的距离处，使得进入加压容器的原料不接触密封头。

公开(公告)号：WO2015062737A3

公开(公告)日：2015-05-07

申请号：PCT/EP2014/002928

申请日：2014-10-31

Applicant: BIOCHEMTEX S.P.A.

Inventor： OTTONELLO, Piero ,  TORRE, Paolo ,  GIORDANO, Dario ,  PARAVISI, Stefano ,  PREFUMO, Chiara ,  PASTORINO, Pietro

IPC: C07C29/00 ,  D21B1/02 ,  D21B1/04 ,  D21B1/34 ,  D21B1/36

Abstract: A process for producing polyols from a low viscosity slurry comprising a thermally treated ligno-cellulosic biomass which has been subjected to a fiber shives reduction step is provided. Specifically, a continuous process for catalyzing the formation of polyol products, such as ethylene glycol and propylene glycol, from the low viscosity slurry is provided.

Abstract translation: 提供了一种由低粘度浆料生产多元醇的方法，所述浆料包含经过纤维碎屑还原步骤的经热处理的木质纤维素生物质。 具体而言，提供了用于催化由低粘度浆液形成多元醇产物（例如乙二醇和丙二醇）的连续方法。

公开(公告)号：WO2015124498A1

公开(公告)日：2015-08-27

申请号：PCT/EP2015/053062

申请日：2015-02-13

Applicant: BIOCHEMTEX S.P.A.

Inventor： BERNARDI, Marco ,  FERRANDO, Patrizia ,  RAGHAVENDRAN, Srinivasan ,  BONANNI, Andrea ,  FRATTINI, Alessandra ,  GIORDANO, Dario

IPC: C07C29/09 ,  C12P7/18 ,  C12P7/42 ,  C07C31/18 ,  C07C31/20 ,  C07C31/26

CPC classification number: C07C29/132 ,  C07C29/60 ,  D21C3/02 ,  D21C3/04 ,  D21C3/06 ,  D21C3/08 ,  D21C3/10 ,  D21C3/12 ,  D21C3/14 ,  D21C11/00 ,  Y02P20/125 ,  C07C31/202 ,  C07C31/205

Abstract: It is disclosed an integrated process for producing at least a cellulosic pulp comprising cellulose in the form of fibers and a polyols stream from a ligno-cellulosic feedstock comprising cellulose, hemicellulose and lignin. The process comprises the steps of: a) Treating the ligno-cellulosic feedstock to produce the cellulosic pulp and at least a liquid sugar stream comprising water and monomeric sugars derived from the hemicellulose of the ligno-cellulosic feedstock; b) Catalytically converting the monomeric sugars of the liquid sugar stream to a polyols mixture, comprising primary polyols and secondary polyols; c) Separating at least a portion of the polyols mixture into at least the polyols stream and a residual stream, wherein the polyols stream comprises the majority by weight of the primary polyols and the residual stream comprises the majority by weight of the secondary polyols; d) Recovering a first thermal energy from the residual stream in a first recovery unit.

Abstract translation: 公开了一种用于生产至少纤维素纸浆的综合方法，所述纤维素纸浆包含纤维形式的纤维素和来自包含纤维素，半纤维素和木质素的木质纤维素原料的多元醇物流。 该方法包括以下步骤：a）处理木质纤维素原料以产生纤维素浆和至少一种包含水的液体糖流和衍生自木质纤维素原料的半纤维素的单体糖; b）将液体糖料流的单体糖催化转化成多元醇混合物，其包含主要多元醇和仲醇; c）将多元醇混合物的至少一部分分离成至少多元醇物流和残余物流，其中多元醇物流主要包含主要多元醇的重量百分比，剩余物流包含主要的次级多元醇; d）在第一回收单元中从残余流中回收第一热能。

公开(公告)号：WO2015063256A3

公开(公告)日：2015-05-07

申请号：PCT/EP2014/073428

申请日：2014-10-31

Applicant: BIOCHEMTEX S.P.A. ,  BETA RENEWABLES S.P.A.

Inventor： OTTONELLO, Piero ,  TORRE, Paolo ,  PARAVISI, Stefano ,  PREFUMO, Chiara ,  PASTORINO, Pietro ,  GIORDANO, Dario

IPC: C08H8/00 ,  C08L97/02 ,  C12P19/02

Abstract: It is disclosed a process forincreasing the enzymatic accessibility of a thermally treated ligno- cellulosic biomass feedstock which has been thermally treated at a severity factor. The process comprises a step of fiber shives reduction, for reducing the amount of long shives. The thermally treated ligno-cellulosic biomass after fiber shives reduction is characterized by having an increased glucans accessibility and by forming a slurry having a low viscosity.

Abstract translation: 公开了一种用于增加热处理过的木质纤维素生物质原料的酶可接近性的方法，所述热处理过的木质纤维素生物质原料已经以苛刻度因子进行热处理。 该过程包括减少纤维碎片的步骤，以减少长鳍的数量。 在纤维碎裂还原后热处理的木质纤维素生物质的特征在于具有增加的葡聚糖可及性并且通过形成具有低粘度的浆料。