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公开(公告)号：WO2016204981A1
公开(公告)日：2016-12-22
申请号：PCT/US2016/035642
申请日：2016-06-03
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： MALANGA, Michael T. , KING, Stephen W. , FRYCEK, George J. , MASY, Jean-Paul , FREGNI, Sabrina
CPC classification number: C08G18/2027 , C08G18/1825 , C08G18/3206 , C08G18/3275 , C08G18/4804 , C08G18/4816 , C08G18/482 , C08G18/4841 , C08G18/4845 , C08G18/5024 , C08G18/5027 , C08G18/632 , C08G18/667 , C08G18/6674 , C08G18/7621 , C08G18/7664 , C08G73/024 , C08G73/0273 , C08G73/0633 , C08G2101/0008 , C08J9/14 , C08J2205/06 , C08J2375/08
Abstract: The present invention discloses a tertiary amine initiator and polymeric polyol compositions made therefrom useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The tertiary amine initiator is one or more partially alkylated amine compound have the Structure II: RR 1 N - (R'-NH) y - (R'-NR 4 ) x-y - R' - NR 2 R 3 wherein R' is a C 1 to C 6 linear or branched alkyl group, R, R 1 , R 2 , and R 3 are independently a hydrogen or a C 1 to C 6 linear or branched alkyl group with the proviso that at least one of R, R 1 , R 2 , and R 3 is not hydrogen, R 4 is a hydrogen or a C 1 to C 6 linear or branched alkyl group, x is from 1 to 33, y is from 0 to 32, and z is from 0 to 15, with the proviso that x-y is equal to or greater than 1 and the number of N-H bonds in (II) is greater than 0 and less than 8.
Abstract translation: 本发明公开了由其制备的叔胺引发剂和聚合多元醇组合物，其用于制备聚氨酯聚合物，特别是聚氨酯泡沫塑料。 所述聚氨酯聚合物泡沫体表现出机械性能，物理性能和低排放物的良好平衡。 叔胺引发剂是具有结构II：RR1N - （R'-NH）y - （R'-NR4）xy-R'-NR2R3的一种或多种部分烷基化的胺化合物，其中R'是C1至C6直链或支链 烷基，R，R 1，R 2和R 3独立地是氢或C 1至C 6直链或支链烷基，条件是R，R 1，R 2和R 3中的至少一个不是氢，R 4是氢或 C1至C6直链或支链烷基，x为1至33，y为0至32，z为0至15，条件是xy等于或大于1，NH键数 在（II）中大于0且小于8。
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2.发明申请
公开(公告)号：WO2021247630A1
公开(公告)日：2021-12-09
申请号：PCT/US2021/035334
申请日：2021-06-02
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： PAPA, Antonio , GUIDETTI, Giuliano , FREGNI, Sabrina
IPC: C08G18/76 , C08G18/12 , C08G18/18 , C08G18/20 , C08G18/79 , C08K5/00 , C08K5/523 , C08G18/1833 , C08G18/2063 , C08G18/7664 , C08G18/7671 , C08G18/794 , C08G18/797
Abstract: The present invention provides self-extinguishing flexible polyurethane foams, reaction mixtures and methods for making them, wherein the foam forming reaction mixture comprises an isocyanate component of one or more aromatic polyisocyanate containing two or more aromatic or phenyl groups, and an aromatic phosphorus containing flame retardant, and, separately, a polyol component which is a mixture of one or more, first polyols and one or more high molecular weight polyols, and from 7.5 to 17.5 wt.%, based on the weight of the polyol component, of a brominated polyether flame retardant having a bromine content of from 30 to 40 wt.%, and having an average hydroxyl functionality of from 2.3 to 3.5, one or more catalysts, and one or more blowing agents. The flexible polyurethane foam has a gross density of from 200 to 280 g/l.
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公开(公告)号：WO2014004237A1
公开(公告)日：2014-01-03
申请号：PCT/US2013/046724
申请日：2013-06-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： CAVALCA, Sara , FREGNI, Sabrina
CPC classification number: B32B5/20 , B29C44/1233 , B29K2075/00 , B29K2105/04 , B29K2627/06 , B32B27/065 , B32B27/20 , B32B27/22 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/365 , B32B2266/0278 , B32B2270/00 , B32B2307/71 , B32B2307/734 , B32B2605/003 , C08G18/4018 , C08G18/4816 , C08G18/482 , C08G18/4833 , C08G18/4841 , C08G18/5021 , C08G18/7664 , C08G2101/0058 , C08J9/35 , C08J2375/08
Abstract: PVC-skinned composites include a substrate, a skin and an intermediate polyurethane layer. The polyurethane layer is characterized in having a low molecular weight between crosslinks, i.e. , is somewhat highly crosslinked. The high level of crosslinking in the polyurethane leads to improved performance of the skin layer. The skin layer retains its original color upon aging, is less prone to shrinking and other loss of physical properties, and adheres better to the polyurethane layer.
Abstract translation: PVC表皮复合材料包括基底，皮肤和中间聚氨酯层。 聚氨酯层的特征在于在交联之间具有低分子量，即有些高度交联。 聚氨酯中的高水平交联导致皮肤层的改善的性能。 老化时皮肤层保持原有的颜色，不容易收缩等物理性能的损失，并且更好地粘附于聚氨酯层。
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Patent Agency Ranking
公开(公告)号：WO2017078990A1
公开(公告)日：2017-05-11
申请号：PCT/US2016/058740
申请日：2016-10-26
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： FREGNI, Sabrina , CAI, Jun , LANDI, Selvaggia
CPC classification number: C08G18/7664 , C08G18/4018 , C08G18/4211 , C08G18/4816 , C08G18/4841 , C08G18/485 , C08G2101/00 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2350/00 , C08K3/04 , C08K2201/005 , C08K2201/011
Abstract: The present invention relates to a reactive formulation used to make a polyurethane foam which is particularly suited for use in under the hood vehicle applications which require sound deadening and vibration management and a process to make said foam. In particular, the polyurethane foam is made from a reactive formulation comprising an A side comprising (i) one or more organic isocyanate and a B side comprising (ii) one or more isocyanate-reactive component, (iii) a carbon nanofiller; and (iv) one or more additional component selected from a catalyst, a blowing agent, a cell opener, a surfactant, a crosslinker, a chain extender, a filler, a colorant, a pigment, an antistatic agent, reinforcing fibers, an antioxidant, a preservative, or an acid scavenger.
Abstract translation: 本发明涉及用于制造聚氨酯泡沫的反应性配制剂，其特别适用于要求消声和振动管理的罩下车辆应用以及制造所述泡沫的过程。 特别地，聚氨酯泡沫由包含A侧的反应性配制物制成，所述A侧包含（i）一种或多种有机异氰酸酯和B侧包含（ii）一种或多种异氰酸酯反应性组分，（iii）碳纳米填料; 和（iv）选自催化剂，发泡剂，开孔剂，表面活性剂，交联剂，扩链剂，填料，着色剂，颜料，抗静电剂，增强纤维，抗氧化剂的一种或多种附加组分 ，防腐剂或除酸剂。
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5.发明申请METHOD FOR PREPARING FLEXIBLE POLYURETHANE FOAM WITH HYDROLYSABLE SILANE COMPOUNDS 审中-公开用可水解硅烷化合物制备柔性聚氨酯泡沫体的方法
公开(公告)号：WO2013032718A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/051031
申请日：2012-08-16
Applicant: DOW GLOBAL TECHNOLOGIES LLC , WALIA, Parvinder, S. , OBI, Bernard, E , MINNIKANTI, Venkat, S. , KOONCE, William, A. , VYAKARANAM, Kamesh, R. , ZHANG, Ling , FREGNI, Sabrina
Inventor： WALIA, Parvinder, S. , OBI, Bernard, E , MINNIKANTI, Venkat, S. , KOONCE, William, A. , VYAKARANAM, Kamesh, R. , ZHANG, Ling , FREGNI, Sabrina
CPC classification number: C08G18/289 , C08G18/10 , C08G18/165 , C08G18/1833 , C08G18/1841 , C08G18/2063 , C08G18/246 , C08G18/3275 , C08G18/4816 , C08G18/4841 , C08G18/6688 , C08G18/7664 , C08G18/778 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08G2101/0083
Abstract: Flexible polyurethane foams are made using certain hydrolysable silane compounds in the foam formulation. The hydrolysable silane compounds contain at least one isocyanate-reactive group and at least one hydrolysable silane group. The presence of the hydrolysable silane compound in the foam formulation leads to improved tensile, tear and elongation properties without an adverse effect on other important foam properties such as resiliency and hysteresis loss.
Abstract translation: 在泡沫配方中使用某些可水解的硅烷化合物来制造柔性聚氨酯泡沫。 可水解硅烷化合物含有至少一个异氰酸酯反应性基团和至少一个可水解硅烷基团。 可发泡的硅烷化合物在泡沫配方中的存在导致提高的拉伸，撕裂和伸长性能，而对其他重要的泡沫性能如弹性和滞后损失没有不利影响。
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公开(公告)号：WO2017218254A1
公开(公告)日：2017-12-21
申请号：PCT/US2017/036264
申请日：2017-06-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： MALANGA, Michael T. , FREGNI, Sabrina , FRYCEK, George J. , KING, Stephen W. , MASY, Jean-Paul , ONAM, Sadeka
Abstract: The present invention discloses a polymeric polyol composition useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The polymeric polyol composition is the reaction product(s) of (i) a polyamine initiator composition comprising the polymerization product(s) of aminoethylpiperazine with (ii) at least one epoxide compound, at least one glycidyl ether compound, or mixtures thereof.
Abstract translation: 本发明公开了用于制造聚氨酯聚合物，特别是聚氨酯泡沫塑料的聚合物多元醇组合物。 所述聚氨酯聚合物泡沫表现出机械性能，物理性能和低排放物的良好平衡。 聚合物多元醇组合物是（i）包含氨乙基哌嗪的聚合产物与（ii）至少一种环氧化合物，至少一种缩水甘油醚化合物或其混合物的聚胺引发剂组合物的反应产物。 / p>
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公开(公告)号：WO2017210022A1
公开(公告)日：2017-12-07
申请号：PCT/US2017/034016
申请日：2017-05-23
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： GUIDETTI, Giuliano , FREGNI, Sabrina
Abstract: Disclosed is a method for producing an open cell low-density semi-rigid polyurethane foam suitable for general use as a thermal insulating material and/or acoustical applications. The method comprises producing a flame-retardant open-celled semi-rigid polyurethane foam having an overall density of 5 to 30 kg/m 2 by reacting (a) a polyisocyanate and (b) a polyol having a molecular weight of 100 to 10,000, in the presence of (c) 2,2-bis(chloromethyl)-trimethylene bis(bis(2-chloroethyl)phosphate, (d) blowing agent, and (e) optional additional components.
Abstract translation: 公开了一种用于生产适用于通常用作绝热材料和/或声学应用的开孔低密度半硬质聚氨酯泡沫的方法。 该方法包括通过使（a）多异氰酸酯和（b）多元醇反应制备总密度为5至30kg / m 2的阻燃性开孔半硬质聚氨酯泡沫，所述多元醇具有 （c）2,2-双（氯甲基） - 三亚甲基双（二（2-氯乙基）磷酸酯，（d）发泡剂和（e）任选的附加组分存在下的分子量为100-10,000。 p>
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公开(公告)号：WO2014011375A1
公开(公告)日：2014-01-16
申请号：PCT/US2013/046727
申请日：2013-06-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： CAVALCA, Sara , FREGNI, Sabrina
IPC: C08G18/10 , C08G18/32 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/72 , C08G18/76 , C08G18/79 , C08G101/00
CPC classification number: B32B27/065 , B32B5/20 , B32B27/08 , B32B27/304 , B32B27/40 , B32B37/14 , B32B2266/0278 , B32B2305/72 , C08G18/10 , C08G18/3206 , C08G18/4236 , C08G18/4816 , C08G18/4837 , C08G18/4841 , C08G18/6677 , C08G18/68 , C08G18/725 , C08G18/7664 , C08G18/798 , C08G2101/0016 , C08G2101/0083 , C08J9/04 , C08J2375/04
Abstract: Skinned composites contain a plasticized polymer skin layer adhered to a layer of a polyurethane. The polyurethane is made from a reaction mixture that contains specified amounts of a polyester polyol and an acidic material. The presence of both the polyester polyol and acid leads to significantly improved adhesion between the polyurethane and skin layer. The invention is particularly useful when the skin is highly plasticized.
Abstract translation: 皮革复合材料包含粘附到聚氨酯层的增塑聚合物表层。 聚氨酯由含有特定量的聚酯多元醇和酸性物质的反应混合物制成。 聚酯多元醇和酸的存在导致聚氨酯和表皮层之间的粘合性明显改善。 当皮肤高度塑化时，本发明特别有用。
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