LITHOGRAPHIC PRINTING PLATE PRECURSORS AND METHOD OF USE

    公开(公告)号:WO2022132444A1

    公开(公告)日:2022-06-23

    申请号:PCT/US2021/061520

    申请日:2021-12-02

    Abstract: Lithographic printing plate precursors have an aluminum-containing substrate prepared using two anodizing processes to provide an inner aluminum oxide layer of average dry thickness of 300-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter of ≤100 nm. An outer aluminum oxide layer is provided with a multiplicity of outer micropores of average outer micropore diameter of 15-30 nm and a dry thickness of 30-650 nm. A hydrophilic layer is disposed on the outer aluminum oxide layer at 0.0002-0.1 g/m2 and has a (1) compound having an ethylenically unsaturated polymerizable groups; a -OM group connected directly to a phosphorus atom, wherein M represents a hydrogen, sodium, potassium, or aluminum atom; and (2) one or more hydrophilic polymers having (a) recurring units comprising an amide group, and (b) recurring units having an -OM' group that is directly connected to a phosphorus atom, wherein M' represents a hydrogen, sodium, potassium, or aluminum atom.

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