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    POLYETHERSULFONE COMPOSITION, METHOD OF MAKING AND ARTICLES THEREFROM
    2.
    发明申请
    POLYETHERSULFONE COMPOSITION, METHOD OF MAKING AND ARTICLES THEREFROM 审中-公开
    聚烯烃组合物，制备方法及其制品

    公开(公告)号：WO2007112198A1

    公开(公告)日：2007-10-04

    申请号：PCT/US2007/063774

    申请日：2007-03-12

    申请人： GENERAL ELECTRIC COMPANY ,  JOHNSON, Donald, Scott ,  STEIGER, Daniel ,  BRUNELLE, Daniel, Joseph ,  ARMSTRONG, Sean, Elliot

    发明人： JOHNSON, Donald, Scott ,  STEIGER, Daniel ,  BRUNELLE, Daniel, Joseph ,  ARMSTRONG, Sean, Elliot

    IPC分类号： C08G75/23

    CPC分类号： C08G65/40 ,  C08G75/23 ,  C08L71/10 ,  C08L81/06

    摘要： A polyethersulfone composition is disclosed which comprises structural units derived from bisphenol-A and 4,4'-biphenol, the structural units derived from 4,4'-biphenol being present in an amount corresponding to greater than 65 mole percent based on total moles of structural units derived from diphenolic monomers, wherein the polyethersulfone has a weight average molecular weight (M w ) of at least 54,000 grams per mole as measured by gel permeation chromatography. The polyethersulfone compositions of the invention display outstanding impact strength as measured using ASTM D256. Surprisingly, the polyethersulfone compositions of the invention show enhanced impact strength relative to known polyethersulfones such as RADEL R, a commercially available polyethersulfone engineering thermoplastic comprised of structural units derived from a dihalodiarylsulfone and 4,4'-biphenol and having a Notched Izod impact strength of about 700 Joules per meter.

    摘要翻译： 公开了一种聚醚砜组合物，其包含衍生自双酚A和4,4'-联苯酚的结构单元，衍生自4,4'-联苯酚的结构单元的存在量相当于基于总共摩尔数 衍生自二元酚单体的结构单元，其中聚醚砜的重均分子量（M max）为每摩尔至少54,000克，通过凝胶渗透色谱测定。 本发明的聚醚砜组合物显示出优异的冲击强度，使用ASTM D256测量。 令人惊奇的是，本发明的聚醚砜组合物相对于已知的聚醚砜如RADEL R显示出增强的冲击强度，RADEL R是由二卤代芳基砜和4,4'-联苯酚衍生的结构单元的市售聚醚砜工程热塑性塑料，其具有缺口伊佐德冲击强度 约700焦耳/米。

    PHASE TRANSFER CATALYZED METHOD FOR PREPARATION OF POLYETEHRIMIDES
    4.
    发明申请
    PHASE TRANSFER CATALYZED METHOD FOR PREPARATION OF POLYETEHRIMIDES 审中-公开
    用于制备聚烯烃的相转移催化方法

    公开(公告)号：WO2005021618A2

    公开(公告)日：2005-03-10

    申请号：PCT/US2004/025799

    申请日：2004-08-10

    申请人： GENERAL ELECTRIC COMPANY ,  BRUNELLE, Daniel, Joseph ,  ACAR, Havva, Yagci ,  KHOURI, Farid, Fouad ,  GUGGENHEIM, Thomas, Link ,  WOODRUFF, David, Winfield ,  JOHNSON, Norman, Enoch

    发明人： BRUNELLE, Daniel, Joseph ,  ACAR, Havva, Yagci ,  KHOURI, Farid, Fouad ,  GUGGENHEIM, Thomas, Link ,  WOODRUFF, David, Winfield ,  JOHNSON, Norman, Enoch

    IPC分类号： C08G73/10

    CPC分类号： C08G73/124 ,  C08G73/121

    摘要： Polyether polymers, such as polyetherimides, are prepared by the reaction of a dihydroxy-substituted aromatic hydrocarbon alkali metal salt, such as bisphenol A disodium salt, with a bis(N-(chlorophthalimido))aromatic compound, such as 1,3-and/or 1,4-bis[N-(4-chlorophthalimido)]benzene, in a solvent such as o-dichlorobenzene and in the presence of a phase transfer catalyst such as a hexaalkylguanidinium chloride. Several embodiments may be employed to improve the method. They comprise employing substantially dry reagents, employing a high solids level in solvent, beginning with an excess of bis(N-(chlorophthalimido))-aromatic compound and incrementally adding alkali metal salt, employing alkali metal salt of small particle size, and using reagents of high purity.

    摘要翻译： 聚醚聚合物如聚醚酰亚胺通过二羟基取代的芳族烃碱金属盐如双酚A二钠盐与双（N-（氯代邻苯二甲酰亚氨基））芳族化合物例如1,3-和 /或1,4-双[N-（4-氯邻苯二甲酰亚氨基）]苯，在溶剂如邻二氯苯中，并在相转移催化剂如六烷基氯化胍的存在下进行。 可以采用几个实施例来改进该方法。 它们包括使用基本上干燥的试剂，在溶剂中使用高固体含量，从过量的双（N-（氯代邻苯二甲酰亚胺基）） - 芳族化合物开始，并逐渐加入碱金属盐，使用小粒径的碱金属盐，并使用试剂 高纯度。

    METHOD FOR PREPARING OXYDIPHTHALIC ANHYDRIDES USING GUANIDINIUM SALT AS CATALYST
    5.
    发明申请
    METHOD FOR PREPARING OXYDIPHTHALIC ANHYDRIDES USING GUANIDINIUM SALT AS CATALYST 审中-公开
    使用胍盐作为催化剂制备氧化非离子型的方法

    公开(公告)号：WO2004076399A1

    公开(公告)日：2004-09-10

    申请号：PCT/US2004/004743

    申请日：2004-02-17

    申请人： GENERAL ELECTRIC COMPANY ,  BRUNELLE, Daniel, Joseph ,  YE, Qing

    发明人： BRUNELLE, Daniel, Joseph ,  YE, Qing

    IPC分类号： C07C51/567

    CPC分类号： C07C51/567 ,  C07C65/24

    摘要： Oxydiphthalic anhydrides such as 4-oxydiphthalic anhydride are prepared by the reaction of a halophthalic anhydride with an alkali metal carbonate such as potassium carbonate. The reaction proceeds in the presence of a hexaalkylguanidinium halide or α,ω-bis(pentaalkylguanidinium)alkane halide as a phase transfer catalyst.

    摘要翻译： 氧代二邻苯二甲酸酐如4-氧代二邻苯二甲酸酐通过卤代邻苯二甲酸酐与碱金属碳酸盐如碳酸钾的反应来制备。 反应在六烷基胍卤化物或α，ω-双（五烷基胍）烷烃卤化物作为相转移催化剂存在下进行。

    POLYETHERSULFONE COMPOSITIONS WITH HIGH HEAT AND GOOD IMPACT RESISTANCE
    6.
    发明申请
    POLYETHERSULFONE COMPOSITIONS WITH HIGH HEAT AND GOOD IMPACT RESISTANCE 审中-公开
    具有高耐热和耐冲击性的聚醚类组合物

    公开(公告)号：WO2008051651A1

    公开(公告)日：2008-05-02

    申请号：PCT/US2007/075782

    申请日：2007-08-13

    申请人： GENERAL ELECTRIC COMPANY ,  BRUNELLE, Daniel, Joseph ,  STEIGER, Daniel

    发明人： BRUNELLE, Daniel, Joseph ,  STEIGER, Daniel

    IPC分类号： C08G75/00 ,  C08G75/23

    CPC分类号： C08G75/23 ,  C08L81/06

    摘要： Polyethersulfones having Tg greater than about 225°C and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol% to less than about 40 mol% structural units of formula 1; and from greater than about 60 mol% to about 95 mol% structural units of formula 2 wherein R 1 , R 2 , and R 3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C 1 -C 12 aliphatic radical, C 3 -C 12 cycloaliphatic radical, or a C 3 -C 12 aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C 3 -C 20 cycloaliphatic radical, or a C 3 -C 20 aromatic radical.

    摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2，R 3和R 3是 卤素原子，硝基，氰基，C 1 -C 12脂肪族基，C 3 -C 12脂环族基团或C 3 -C 12芳族基团; n，m，q各自独立地为0至4的整数; 和Q是C 3 -C 20脂环族基团或C 3 -C 20芳族基团。

    METHOD OF MAKING BLOCK COPOLYMERS BY SOLID STATE POLYMERIZATION
    8.
    发明申请
    METHOD OF MAKING BLOCK COPOLYMERS BY SOLID STATE POLYMERIZATION 审中-公开
    通过固态聚合制备嵌段共聚物的方法

    公开(公告)号：WO2003040208A1

    公开(公告)日：2003-05-15

    申请号：PCT/US2002/032085

    申请日：2002-10-07

    申请人： GENERAL ELECTRIC COMPANY

    发明人： O'NEIL, Gregory, Allen ,  DAY, James ,  BRUNELLE, Daniel, Joseph ,  SURIANO, Joseph, Anthony ,  MCCLOSKEY, Patrick, Joseph ,  SMIGELSKI, Paul, Michael, Jr.

    IPC分类号： C08G64/18

    CPC分类号： C08G63/64 ,  C08G63/80

    摘要： A method of preparing block copolymers by solid state polymerization is described. A mixture of a partially crystalline polycarbonate having activated terminal aryloxy groups, for example terminal methyl salicyl groups, when heated together with an oligomeric polyester having reactive terminal hydroxy groups under solid state polymerization conditions affords block copolymers. The activated terminal aryloxy groups play a key role in preserving the block lengths of the starting materials. A control sample in which the partially crystalline polycarbonate lacks activated terminal aryloxy groups, for example polycarbonates substituted by phenol, affords a much lower molecular weight, more highly randomized copolymer product. The product block copolymers are useful as "weatherable" plastic materials.

    摘要翻译： 描述了通过固态聚合制备嵌段共聚物的方法。 当在固态聚合条件下与具有反应性末端羟基的低聚聚酯一起加热时，具有活化的末端芳氧基的部分结晶的聚碳酸酯，例如末端甲基水杨酸酯的混合物得到嵌段共聚物。 活化的末端芳氧基在保留原料的块长度方面起关键作用。 其中部分结晶聚碳酸酯缺乏活化的末端芳氧基的对照样品，例如由苯酚取代的聚碳酸酯，得到低得多的分子量，更高度随机的共聚物产物。 产品嵌段共聚物可用作“耐候性”塑料材料。

    PROCESS FOR THE PRODUCTION OF POLYCARBONATE
    9.
    发明申请
    PROCESS FOR THE PRODUCTION OF POLYCARBONATE 审中-公开

    公开(公告)号：WO2002053623A3

    公开(公告)日：2002-07-11

    申请号：PCT/US2001/049211

    申请日：2001-12-21

    申请人： GENERAL ELECTRIC COMPANY

    发明人： BRACK, Hans-Peter ,  BRUNELLE, Daniel, Joseph ,  CELLA, James, Anthony ,  KARLIK, Dennis

    IPC分类号： C08G64/30

    摘要： A process for the production of polycarbonate be melt-polycondensing an aromatic dihydroxy compound and diphenylcarbonate, the process comprising adding to the polycarbonate under melt conditions a compound of the formula (I) wherein R 1 and R 3 may be the same or different and are selected from the group consisting of alkoxy, phenoxy, benzoxy, aryloxy, phenyl and aryl groups, R 2 is selected from the group consisting of alkyl, phenyl, aryl, or aralkyl groups.

    MIXED-SULFONATION BLOCK COPOLYMERS
    10.
    发明申请
    MIXED-SULFONATION BLOCK COPOLYMERS 审中-公开
    混合磺化嵌段共聚物

    公开(公告)号：WO2007075536A2

    公开(公告)日：2007-07-05

    申请号：PCT/US2006/048185

    申请日：2006-12-18

    申请人： GENERAL ELECTRIC COMPANY ,  HUNG, Joyce ,  ZHOU, Hongyi ,  MOORE, David, Roger ,  HARMON, Marianne, Elisabeth ,  BRUNELLE, Daniel, Joseph ,  LIU, Hongwei

    发明人： HUNG, Joyce ,  ZHOU, Hongyi ,  MOORE, David, Roger ,  HARMON, Marianne, Elisabeth ,  BRUNELLE, Daniel, Joseph ,  LIU, Hongwei

    CPC分类号： C08G65/4012 ,  C08G65/48 ,  C08G75/23

    摘要： Sulfonated block copolymers that may be used as membranes for fuel cells include sulfonated polyaryletherketone blocks and lightly sulfonated polyethersulfone blocks. The sulfonated polyaryletherketone blocks include structural units of formula (I) and the lightly sulfonated polyethersulfone blocks include structural units of formula (II) and (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently C 1 -C 10 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, allyl, alkenyl, alkoxy, halo, or cyano; Z, Z 1 and Z 2 are independently a direct bond or O, S, (CH 2 )r, (CF 2 )r , C(CH 3 ) 2 , C(CF 3 ) 2 , or a combination thereof; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof; a and e are independently 0 or an integer from 1 to 3 ; b, c, d, and f are independently 0 or an integer from 1 to 4; m, n and p are independently 0 or 1 ; and r is an integer from 1 to 5.

    摘要翻译： 可用作燃料电池膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和轻度磺化聚醚砜嵌段。 磺化聚芳醚酮嵌段包括式（I）的结构单元，轻度磺化聚醚砜嵌段包括式（II）和（III）的结构单元，其中R 1，R 2， ，R 3，R 4，R 5和R 6独立地为C 1 / sub C≡C1-10烷基，C≡C12 -C 12环烷基，C≡C14 -C 14环烷基， 芳基，烯丙基，烯基，烷氧基，卤素或氰基; Z，Z 1和Z 2独立地为直接键或O，S（CH 2）r（CF 2） C（CH 3）2，C（CF 3）2，...，C（CH 3） 2或其组合; M为H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物; a和e独立地为0或1至3的整数; b，c，d和f独立地为0或1至4的整数; m，n和p独立地为0或1; r是1到5的整数。