Abstract:
The present disclosure relates to Quinacridone pigment and a process of preparation thereof. The Quinacridone pigment of the present disclosure exhibit higher chemical resistance to solvents, higher stability and higher resistance to acid and alkali.
Abstract:
The present disclosure provides carbazole-dioxazine pigment of Formula I; wherein, R is C 1 -C 8 alkyl group, preferably R is an ethyl group, R 1 is a chloro group, and R 2 is a -NHC(=O)Ph group. The pigment is synthesized from 3-nitro-N-ethylcarbazole. The first step is nitration of 3-nitro-N-ethylcarbazole to form 3,6-dinitro-N-ethylcarbazole which is reduced to form 3-amino-6-nitro-N-ethylcarbazole. This amino compound is benzoylated to form 3-benzamido-6-nitro-N-ethylcarbazole which is then hydrogenated to form 6-amino-3-benzamido-N-ethylcarbazole. Condensation of 6-amino-3-benzamido-N-ethylcarbazole with chlroanil provides an intermediate. Cyclization of the intermediate in the presence of a cyclization reagent provides the compound of Formula-I. The pigment has wavelength of maximum absorption (λ max ) at 571nm in dimethylformamide as a solvent.
Abstract:
A stable polyetherketones thermoplastic polymer comprises: a) a polyetherketone of the formula -Ar-CO-, wherein Ar is a bivalent aromatic radical; and b) aryl phosphonite compound of formula I(The formula I should be inserted here.), wherein X is selected from the group consisting of Cl, Br and F, the amount of said phosphonite compound being in the range of 0.01 to 4% by weight of the total composition.
Abstract:
The present disclosure relates to a polymer composition comprising a polymer blend of Polyaryl Ether Ketone (PAEK) and Poly(2,5-benzimidazole) characterized with enhanced mechanical and wear resistance properties as compared to commercial polymer blends of Polyaryl Ether Ketone and Polybenzimidazole. The present disclosure also relates to shaped articles derived from the polymer composition of the present disclosure.
Abstract:
A process for preparation of a trifluoromethylsulfinyl pyrazole compound of formula (I) from a compound of formula (III) is provided, wherein R, R 1 and R 2 represent a group containing halogen respectively and R 3 represents a perhaloalkyl.
Abstract:
Disclosed is a process for the preparation of N-alkyl carbazole. Said process comprises: a) chlorinating cyclohexanone to form 2-chlorocyclohexanone; b) reacting 2-chlorocyclohexanone with N-ethyl aniline to form 2-(N-ethyl anilino) cyclohexanone; c) cyclizing 2-(N-ethyl anilino) cyclohexanone by refluxing with simultaneous water removal to obtain 9-ethyltetrahydrocarbazole; d) treating 9-ethyl-tetrahydrocarbazole with concentrated hydrochloric acid followed by water wash for removing N-ethyl aniline; e) dehydrogenating 9-ethyltetrahydrocarbazole by heating 9-ethyltetrahydrocarbazole in a solvent, in presence of a catalyst to obtain N-alkyl carbazole.
Abstract:
The present disclosure relates to a benzoyl substituted carbazole-dioxazine pigment and its preparation. The process involves benzoylation of 3-nitro-N-ethylcarbazole in monochlorobenzene using benzoylchloride and ferric chloride to yield 3-nitro-6-benzoyl-N-ethyl carbazole, which on catalytic hydrogenation and subsequent condensation with chloranil and cyclisation yields benzoyl substituted carbazole-dioxazine pigment.
Abstract:
The present disclosure relates to a bis-quinaldine compound of formula [I] and a process for the same. Wherein R 2 is a substituent selected from the group consisting of H, C 1 - C 20 straight or branched chain alkyl substituents, aromatic substituents, aliphatic substituents, combinations thereof and the like.
Abstract:
In the process of the present disclosure 3,6-dichloro-2-methoxybenzoic acid (DICAMBA) is prepared from 2,5-dichloroaniline in high purity and high yield. DICAMBA is obtained with purity greater than 98.5 %.