THREE-DIMENSIONAL PRINTING WITH VARIABLE DIELECTRIC PERMITTIVITY

    公开(公告)号:WO2022256004A1

    公开(公告)日:2022-12-08

    申请号:PCT/US2021/035409

    申请日:2021-06-02

    Abstract: The present disclosure provides methods of three-dimensional printing, including iteratively applying individual build material layers of polyamide particles and selectively applying a fusing agent onto the individual build material layers to form individually patterned object layers. The fusing agent can include water and a radiation absorber. The method can also include selectively applying a pore-promoting agent onto the individual build material layers at some or all of the individually pattered object layers to form a pore-generating region, and iteratively exposing the individual build material layers to electromagnetic energy to generate molten polymer from polyamide particles in contact with the radiation absorber that upon cooling forms fused polymer body. A material used to form the fused polymer body without pores can exhibit a material dielectric permittivity, and the fused polymer body at a location that includes the pores can exhibit a decreased dielectric permittivity.

    THREE-DIMENSIONAL PRINTING WITH PORE-PROMOTING AGENTS

    公开(公告)号:WO2022191857A1

    公开(公告)日:2022-09-15

    申请号:PCT/US2021/022186

    申请日:2021-03-12

    Abstract: The present disclosure provides methods of three-dimensional printing, including iteratively applying individual build material layers of polymer particles having a D50 particle size from about 20 µm to about 150 µm to a build material, and based on a three-dimensional object model, selectively applying a fusing agent onto the individual build material layers to form individually patterned object layers of the three-dimensional object and selectively applying a pore-promoting agent onto the individual build material layers at a discrete location of the individually patterned object layers to form a pore-generating region therein. The method also includes exposing the build material to electromagnetic energy to provide selective heat fusing of the polymer particles and to generate and displace molten polymer leaving a localized void having a void size from about 1 mm to about 20 mm.

    THREE-DIMENSIONAL PRINTING WITH DUCTILITY AGENTS

    公开(公告)号:WO2022150045A1

    公开(公告)日:2022-07-14

    申请号:PCT/US2021/012885

    申请日:2021-01-11

    Abstract: The present disclosure describes multi-fluid kits for three-dimensional printing, three-dimensional printing kits, and methods of three-dimensional printing. In one example, a multi-fluid kit for three-dimensional printing can include a fusing agent and a ductility agent. The fusing agent can include water and electromagnetic radiation absorber. The electromagnetic radiation absorber can absorb radiation energy and convert the radiation energy to heat. The ductility agent can include water, a water-soluble pore-generating compound that chemically reacts at an elevated temperature to generate a gas, and a plasticizer. The plasticizer can have formula (I) wherein n is an integer ranging from 3 to 8; or formula (II) wherein m is an integer ranging from 3 to 8.

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