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1.
公开(公告)号:WO2020081360A1
公开(公告)日:2020-04-23
申请号:PCT/US2019/055637
申请日:2019-10-10
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: JUNGONG, Christian , MERKEL, Daniel C. , WANG, Haiyou , PHAM, Hang T. , HULSE, Ryan J.
IPC: C09K5/04
Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF 3 I) and 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and trifluoroiodomethane (CF 3 I) to form an azeotrope or azeotrope-like comprising 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and trifluoroiodomethane (CF 3 I) having a boiling point of about -22.70°C ± 30°C at a pressure of about 14.30 psia ± 0.30 psia.
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2.
公开(公告)号:WO2023288199A1
公开(公告)日:2023-01-19
申请号:PCT/US2022/073601
申请日:2022-07-11
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: JUNGONG, Christian , KOPKALLI, Haluk , WANG, Haiyou , YANG, Terris , CHEN, John Qianjun
IPC: C01B7/13 , B01J23/755 , B01J21/04 , B01J38/02
Abstract: The present invention provides a process for producing hydrogen iodide. The process includes providing a vapor-phase reactant stream comprising hydrogen and iodine and reacting the reactant stream in the presence of a catalyst to produce a product stream comprising hydrogen iodide. The catalyst includes at least one selected from the group of nickel, cobalt, cobalt halides, iron, nickel oxide, nickel halides, copper, copper oxide, copper halides, cobalt oxide, ferrous chloride, ferric chloride, iron oxide, zinc, zinc oxide, zinc halides, molybdenum, tungsten, magnesium, magnesium oxide, and magnesium halides. The catalyst is supported on a support.
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3.
公开(公告)号:WO2020214766A1
公开(公告)日:2020-10-22
申请号:PCT/US2020/028437
申请日:2020-04-16
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: YANG, Terris , WANG, Haiyou , CHIU, Yuon , WILCOX, Richard , JUNGONG, Christian , KOPKALLI, Haluk
IPC: C01B7/13 , B01J23/755
Abstract: The present invention provides a process for producing hydrogen iodide. The process includes providing a vapor-phase reactant stream comprising hydrogen and iodine and reacting the reactant stream in the presence of a catalyst to produce a product stream comprising hydrogen iodide. The catalyst includes at least one selected from the group of nickel, cobalt, iron, nickel oxide, cobalt oxide, and iron oxide. The catalyst is supported on a support.
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公开(公告)号:WO2020132534A1
公开(公告)日:2020-06-25
申请号:PCT/US2019/067998
申请日:2019-12-20
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: YANG, Terris , WANG, Haiyou , CHIU, Yuon , WILCOX, Richard , JUNGONG, Christian
IPC: C07C17/093 , C07C19/16
Abstract: The present disclosure provides a process for producing trifluoroiodomethane (CF 3 I). The process may include providing a vapor-phase reactant stream comprising trifluoroacetic acid and iodine and reacting the reactant stream in the presence of a catalyst to produce a product stream comprising the trifluoroiodomethane. The catalyst includes silicon carbide.
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公开(公告)号:WO2023288201A1
公开(公告)日:2023-01-19
申请号:PCT/US2022/073603
申请日:2022-07-11
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: KOPKALLI, Haluk , WANG, Haiyou , CERRI, Gustavo , BEKTESEVIC, Selma , CHIU, Yuon , JUNGONG, Christian , HORWATH, Richard D. , MERKEL, Daniel C. , MCCLAINE, Jennifer W. , YANG, Terris , WILCOX, Richard , CLOSE, Joshua , MALLEPALLY, Rajendar
Abstract: The present disclosure provides an integrated process for producing trifluoroiodomethane (CF3I), in three steps: a) reacting a first reactant stream comprising hydrogen (H2) and iodine (I2) in the presence of a first catalyst to produce a first product stream comprising hydrogen iodide (HI); (b) reacting the first product stream with a second reactant stream comprising trifluoroacetyl chloride (TFAC) in the presence of a second catalyst to produce an intermediate product stream comprising trifluoroacetyl iodide (TFAI); and (c) reacting the intermediate product stream to produce a final product stream comprising trifluoroiodomethane. (CF3I).
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公开(公告)号:WO2020180637A1
公开(公告)日:2020-09-10
申请号:PCT/US2020/020256
申请日:2020-02-28
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: JUNGONG, Christian , WANG, Haiyou , YANG, Terris
IPC: C07C17/389 , C07C17/093 , C07C19/16 , B01J31/02
Abstract: The present disclosure provides a process for producing trifluoroiodomethane. The process includes providing a metal trifluoroacetate, iodine, a phase transfer catalyst, and an organic solvent, and reacting the metal trifluoroacetate and iodine in the presence of the phase transfer catalyst and the organic solvent to produce trifluoroiodomethane.
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7.
公开(公告)号:WO2020081359A1
公开(公告)日:2020-04-23
申请号:PCT/US2019/055631
申请日:2019-10-10
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: JUNGONG, Christian , MERKEL, Daniel C. , WANG, Haiyou , PHAM, Hang T. , HULSE, Ryan J.
IPC: C09K5/04
Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF 3 I) and 1,1,3,3,3-pentafluoropropene (HFO-1225zc), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining 1,1,3,3,3-pentafluoropropene (HFO-1225zc) and trifluoroiodomethane (CF 3 I) to form an azeotrope or azeotrope-like comprising 1,1,3,3,3-pentafluoropropene (HFO-1225zc) and trifluoroiodomethane (CF 3 I) having a boiling point of about -25.63°C ± 0.30°C at a pressure of about 14.44 psia ± 0.30 psia.
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公开(公告)号:WO2022155661A1
公开(公告)日:2022-07-21
申请号:PCT/US2022/070178
申请日:2022-01-13
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: CHIU, Yuon , WANG, Haiyou , KOPKALLI, Haluk , JUNGONG, Christian , NAIR, Haridasan K. , SINGH, Rajiv Ratna , MERKEL, Daniel C. , WANG, Tao , YANG, Terris , WILCOX, Richard
Abstract: A method of removing water from a mixture of hydrogen iodide (HI) and water includes providing a mixture comprising hydrogen iodide and water and contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a weak acid to absorb water from the mixture and/or separating the water from hydrogen iodide (HI) by azeotropic distillation to produce anhydrous hydrogen iodide (HI).
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公开(公告)号:WO2022155659A1
公开(公告)日:2022-07-21
申请号:PCT/US2022/070176
申请日:2022-01-13
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: CHIU, Yuon , WANG, Haiyou , KOPKALLI, Haluk , JUNGONG, Christian , NAIR, Haridasan K. , SINGH, Rajiv Ratna , MERKEL, Daniel C. , WANG, Tao , YANG, Terris , WILCOX, Richard
Abstract: A method of removing water from a mixture of iodine (I2) and water includes providing a mixture comprising iodine and water and: contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a concentrated acid to absorb water from the mixture, separating the water from mixture by distillation, contacting the mixture with a gas that is inert to iodine (I2), contacting the mixture with hydrogen iodide (HI), or combinations thereof.
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10.
公开(公告)号:WO2020081364A1
公开(公告)日:2020-04-23
申请号:PCT/US2019/055650
申请日:2019-10-10
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: JUNGONG, Christian , WANG, Haiyou , MERKEL, Daniel C. , PHAM, Hang T. , HULSE, Ryan J.
IPC: C09K5/04
Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CFsl) and hexafluoroacetone (HFA), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining hexafluoroacetone (HFA) and trifluoroiodomethane (CF3I) to form an azeotrope or azeotrope-like comprising hexafluoroacetone (HFA) and trifluoroiodomethane (CF3l) having a boiling point of about -29.84°C ± 0.30°C at a pressure of about 14.40 psia ± 0.30 psia.
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