公开(公告)号：WO2014180922A1

公开(公告)日：2014-11-13

申请号：PCT/EP2014/059377

申请日：2014-05-07

Applicant: LANXESS ELASTOMERS B.V.

Inventor： BERTHOUD, Alexandra ,  QUIROGA NORAMBUENA, Victor ,  VAN DOREMAELE, Gerhard ,  ZUIDEVELD, Martin Alexander ,  MOUNTFORD, Philip ,  SCOTT, Richard Thomas William

IPC: C07F7/00 ,  C07C251/86

CPC classification number: C08F210/18 ,  C07C249/02 ,  C07C251/24 ,  C07C257/18 ,  C07C2101/10 ,  C07C2601/10 ,  C07F7/006 ,  C07F7/28 ,  C08F4/6592

Abstract: The present invention relates to a new metal complex of the formula (1), wherein: M is a group 4-6 metal R 1 means is a substituent comprising a heteroatom of group 15, through which R 1 is bonded to the imine carbon atom; R 2 -R 5 are the same or different and each represents a hydrogen atom, an optionally substituted C1 -10 alkyl group, an optionally substituted C1 -10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyi group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1 -20 hydrocarbon group(s), a C1 -20 hydrocarbon-substituted amino group or the adjacent R 2 -R 5 may be linked to each other to form a ring; R 6 -R 9 are the same or different and each represents a hydrogen atom, a halogen atom, an optionally substituted C1 -10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyi group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1 -20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 6 -R 9 may be linked to each other to form a ring; L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L; and X is an anionic ligand, and r is an integer denoting the number of anionic ligands X.

Abstract translation: 本发明涉及式（1）的新的金属络合物，其中：M为4-6族金属，R1为含有第15族杂原子的取代基，R1与亚胺碳原子键合; R 2 -R 5相同或不同，各自表示氢原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6-20芳氧基 ，任选取代的C 7-20芳烷基，任选取代的C 7-20芳烷氧基，被任选取代的C 1-20烃基取代的甲硅烷基，C 1-20烃取代的氨基或相邻的R 2 -R 5 可以相互链接形成环; R6-R9相同或不同，各自表示氢原子，卤素原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6 -20芳氧基，任选取代的C7-20芳烷基，任选取代的C7-20芳烷氧基，被任选取代的C1-20烃基取代的甲硅烷基，C1-20烃取代的氨基或 相邻的R6-R9可以彼此连接形成环; L是任选的中性路易斯碱性配体，j是表示中性配体L的数量的整数; X为阴离子配位体，r为阴离子配体数X的整数。

公开(公告)号：WO2014180913A1

公开(公告)日：2014-11-13

申请号：PCT/EP2014/059354

申请日：2014-05-07

Applicant: LANXESS ELASTOMERS B.V.

Inventor： SCOTT, Richard, Thomas, William ,  ZUIDEVELD, Martin, Alexander ,  MOUNTFORD, Philip

IPC: C07F17/00 ,  C08F4/00

CPC classification number: C08F210/16 ,  C07F7/28 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F2420/04 ,  C08F210/18 ,  C08F4/65927 ,  C08F210/06 ,  C08F232/06 ,  C08F2500/25

Abstract: A metal complex of the formula (1) CyAMX(L) n wherein Cy is a cyclopentadienyl-type ligand, M is a metal of group 4; A is an amidine-containing ligand moiety, represented by formula 2: wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1is a substituent comprising a group 14 atom through which Sub1is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom; X is an allyl borateligandderived from a conjugated diene ligand, D, and a borane, B and L is a neutral Lewis basic ligand wherein the number of said metal ligands "n" is in the range of 1 to the amount that specifies the 18-electron rule.

Abstract translation: 式（1）CyAMX（L）n的金属络合物，其中Cy是环戊二烯基型配体，M是第4族的金属; A是含有脒的配体部分，由式2表示：其中含脒配体通过亚胺氮原子与金属M共价结合，Sub1是包含与亚氨基碳键合的第14族原子的取代基 原子，Sub2是包含第15族杂原子的取代基，Sub2与亚氨基碳原子键合; X是从共轭二烯配体D和硼烷中衍生的烯丙基硼烷，B和L是中性路易斯碱性配体，其中所述金属配体“n”的数目在1至指定18- 电子规则。