公开(公告)号：WO2015113957A1

公开(公告)日：2015-08-06

申请号：PCT/EP2015/051571

申请日：2015-01-27

Applicant: LANXESS ELASTOMERS B.V.

Inventor： DOREMAELE, Van Gerardus Henricus Josephus ,  BERTHOUD, Alexandra ,  QUIROGA NORAMBUENA, Victor ,  RUPNICKI, Leszek ,  KARBAUM, Peter

IPC: C08F10/00 ,  C08F4/6592 ,  C07F17/00

CPC classification number: C08F4/6592 ,  C07F7/28 ,  C08F4/65912 ,  C08F210/16 ,  C08F210/18 ,  C08F2420/04 ,  C08F10/00 ,  C08F210/06 ,  C08F2500/17 ,  C08F236/20 ,  C08F2500/25

Abstract: The present invention relates to a A metal complex of formula (1), CyYMLjXn (formula 1) wherein Cy is a cyclopentadienyl-type ligand; M is a metal of group 4; L is a neutral Lewis basic ligand wherein the number of said neutral ligands "j" is in the range of 0 to the amount that satisfies the 18-electron rule; X is an anionic ligand; n is an integer denoting the number of anionic ligands X and is 1 or 2, preferably is 2; Y is a cyclic amidine-containing ligand moiety represented by formula (2), wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom N 2 ; S is a -CH2- unit, and t is the integer number denoting the number of S and is in the range of 1-4, more preferably in the range of 1-2, most preferably is 1; Sub 1 is an aliphatic cyclic or linear substituent comprising a group 14 atom through which Subi is bonded to the amine nitrogen atom N 1 ; Sub2 is an optionally substituted C2 unit in which the 2 carbon atoms may be sp 2 or sp 3 hybridized.

Abstract translation: 本发明涉及式（1）的A金属络合物，CyYMLjXn（式1），其中Cy是环戊二烯基型配体; M是第4组的金属; L是中性的路易斯碱性配体，其中所述中性配体“j”的数量在满足18电子规则的量的0的范围内; X是阴离子配体; n是表示阴离子配体X的数的整数，为1或2，优选为2; Y是由式（2）表示的含环状脒的配体部分，其中含有脒的配体通过亚胺氮原子N2共价结合到金属M上; S是-CH2-单元，t是表示S数的整数，并且在1-4的范围内，更优选在1-2的范围内，最优选的是1; Sub1是包含Subi与胺氮原子N1键合的14族原子的脂族环状或线性取代基; Sub2是任选取代的C2单元，其中2个碳原子可以是sp2或sp3杂交的。

公开(公告)号：WO2014180922A1

公开(公告)日：2014-11-13

申请号：PCT/EP2014/059377

申请日：2014-05-07

Applicant: LANXESS ELASTOMERS B.V.

Inventor： BERTHOUD, Alexandra ,  QUIROGA NORAMBUENA, Victor ,  VAN DOREMAELE, Gerhard ,  ZUIDEVELD, Martin Alexander ,  MOUNTFORD, Philip ,  SCOTT, Richard Thomas William

IPC: C07F7/00 ,  C07C251/86

CPC classification number: C08F210/18 ,  C07C249/02 ,  C07C251/24 ,  C07C257/18 ,  C07C2101/10 ,  C07C2601/10 ,  C07F7/006 ,  C07F7/28 ,  C08F4/6592

Abstract: The present invention relates to a new metal complex of the formula (1), wherein: M is a group 4-6 metal R 1 means is a substituent comprising a heteroatom of group 15, through which R 1 is bonded to the imine carbon atom; R 2 -R 5 are the same or different and each represents a hydrogen atom, an optionally substituted C1 -10 alkyl group, an optionally substituted C1 -10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyi group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1 -20 hydrocarbon group(s), a C1 -20 hydrocarbon-substituted amino group or the adjacent R 2 -R 5 may be linked to each other to form a ring; R 6 -R 9 are the same or different and each represents a hydrogen atom, a halogen atom, an optionally substituted C1 -10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyi group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1 -20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 6 -R 9 may be linked to each other to form a ring; L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L; and X is an anionic ligand, and r is an integer denoting the number of anionic ligands X.

Abstract translation: 本发明涉及式（1）的新的金属络合物，其中：M为4-6族金属，R1为含有第15族杂原子的取代基，R1与亚胺碳原子键合; R 2 -R 5相同或不同，各自表示氢原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6-20芳氧基 ，任选取代的C 7-20芳烷基，任选取代的C 7-20芳烷氧基，被任选取代的C 1-20烃基取代的甲硅烷基，C 1-20烃取代的氨基或相邻的R 2 -R 5 可以相互链接形成环; R6-R9相同或不同，各自表示氢原子，卤素原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6 -20芳氧基，任选取代的C7-20芳烷基，任选取代的C7-20芳烷氧基，被任选取代的C1-20烃基取代的甲硅烷基，C1-20烃取代的氨基或 相邻的R6-R9可以彼此连接形成环; L是任选的中性路易斯碱性配体，j是表示中性配体L的数量的整数; X为阴离子配位体，r为阴离子配体数X的整数。

公开(公告)号：WO2015052184A1

公开(公告)日：2015-04-16

申请号：PCT/EP2014/071438

申请日：2014-10-07

Applicant: LANXESS ELASTOMERS B.V.

Inventor： BERTHOUD, Alexandra ,  VAN DOREMAELE, Gerardus, Henricus, Josephus ,  QUIROGA NORAMBUENA, Victor ,  SCOTT, Richard, Thomas, William

IPC: C08F10/02 ,  C08F210/16 ,  C08F4/6592

CPC classification number: C08F210/06 ,  B01J31/0251 ,  B01J31/146 ,  B01J31/38 ,  C08F4/65908 ,  C08F10/06 ,  C08F210/02 ,  C08F2420/03 ,  C08F10/02 ,  C08F4/6592 ,  C08F210/16 ,  C08F2500/05 ,  C08F2500/17

Abstract: A catalyst system comprising: a) a metal complex of the formula CyLMZ p , wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2 Cy is a cyclopentadienyl-type ligand and, L is a ligand of the formula (A) wherein each A is independently selected from the group consisting of nitrogen and phosphorus and R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of hydrogen, unsubstituted or substituted hydrocarbyl, unsubstituted or substituted silyl and unsubstituted or substituted germyl residues, and b) a boron containing activator, characterized in that the molar ratio of the boron of the activator to M of the metal complex is greater than 2.5.

Abstract translation: 一种催化剂体系，包括：a）式CyLMZp的金属络合物，其中M为第4族金属Z为阴离子配位体，p为1〜2，优选为2个Cy为环戊二烯基型配体，L为 式（A）的配体，其中每个A独立地选自氮和磷，并且R 1，R 2，R 3和R 4独立地选自氢，未取代或取代的烃基，未取代或取代的甲硅烷基和未取代的 或取代的生物残基，和b）含硼活化剂，其特征在于活化剂的硼与金属络合物的M的摩尔比大于2.5。

公开(公告)号：WO2014202644A1

公开(公告)日：2014-12-24

申请号：PCT/EP2014/062783

申请日：2014-06-18

Applicant: LANXESS ELASTOMERS B.V.

Inventor： BERTHOUD, Alexandra ,  VAN DOREMAELE, Gerard ,  QUIROGA NORAMBUENA, Victor ,  SCOTT, Richard Thomas William ,  ZUIDEVELD, Martin Alexander ,  ARTS, Henricus Johannes

IPC: C07F17/00 ,  C07F7/28 ,  C08F10/00

CPC classification number: C07F7/28 ,  C07C257/18 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/02 ,  C08F210/16 ,  C08F210/18 ,  C08F2410/03 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/17 ,  C08F2500/03

Abstract: The present invention relates to a new bimetallic complex of the formula (1) wherein: M is a group 4-6 metal R 1 means is a substituent comprising a heteroatom of group 15, through which R 1 is bonded to the imine carbon atom; R 2 -R 6 are the same or different and each represents a hydrogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 2 -R 6 may be linked to each other to form a ring; R 7 -R 10 are the same or different and each represents a hydrogen atom, a halogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 7 -R 10 may be linked to each other to form a ring; L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L; and X is an anionic ligand, and r is an integer denoting the number of anionic ligands X and wherein the two cyclopentadienyl-amidinato-metal-containing moieties as in the brackets are the same or different.

Abstract translation: 本发明涉及式（1）的新的双金属络合物，其中：M是4-6族金属，R1表示包含第15族杂原子的取代基，R1与亚胺碳原子键合; R 2 -R 6相同或不同，各自表示氢原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6-20芳氧基 ，任选取代的C7-20芳烷基，任选取代的C7-20芳烷氧基，被任选取代的C 1-20烃基取代的甲硅烷基，C 1-20烃取代的氨基或相邻的R 2 -R 6 可以相互链接形成环; R7-R10相同或不同，各自表示氢原子，卤素原子，任选取代的C 1-10烷基，任选取代的C 1-10烷氧基，任选取代的C 6-20芳基，任选取代的C 6 -20芳氧基，任选取代的C7-20芳烷基，任选取代的C7-20芳烷氧基，被任选取代的C 1-20烃基取代的甲硅烷基，C 1-20烃取代的氨基或 相邻的R7-R10可以彼此连接形成环; L是任选的中性路易斯碱性配体，j是表示中性配体L的数量的整数; X是阴离子配体，r是表示阴离子配位体X的数的整数，其中括号中的两个环戊二烯基 - 脒基金属的部分相同或不同。