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公开(公告)号:WO1992003483A1
公开(公告)日:1992-03-05
申请号:PCT/US1991004954
申请日:1991-07-12
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
IPC: C08F02/50
CPC classification number: C08G18/637 , C08F2/48 , C09D4/00 , C08F222/1006
Abstract: A tough polymeric mixture comprises the polymerized product of admixture I or II, wherein admixture I comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one free-radically polymerizable monomer, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one set of polyurethane precursors, and admixture II comprises 5 to 45 weight percent of a first monomer and a photoinitiator therefor, said first monomer being at least one set of polyurethane precursors, and 95 to 55 weight percent of a second monomer and a photoinitiator therefor, said second monomer being at least one free-radically polymerizable monomer, said polymeric mixture having been prepared by a process involving two sequential actinic radiations of wavelength ranges centered around μ1 and μ2, respectively, wherein μ1 and μ2 differ from each other by at least 30 nm, and wherein the actinic radiation centered around μ1 does not substantially polymerize the second monomer, and wherein the area under a stress-strain curve as determined by ASTM D638-89 for said polymeric mixture is at least 10 percent greater, preferably 20 percent greater, and more preferably at least 50 percent greater when said precursor monomers are cured by said sequential photoinitiation process compared to when the same mixture is cured by a single photostage cure.
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公开(公告)号:WO1994025507A1
公开(公告)日:1994-11-10
申请号:PCT/US1994002731
申请日:1994-03-14
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
Inventor: MINNESOTA MINING AND MANUFACTURING COMPANY , WRIGHT, Bradford, B. , FAROOQ, Omar , DEVOE, Robert, J.
IPC: C08G75/02
CPC classification number: C08G75/02 , Y10S522/904
Abstract: Polymeric triarylsulfonium salts are provided having a repeating structural unit with formula (I) where R represents a substituted or unsubstituted aryl group; X represents a non-nucleophilic anion, n represents an integer greater than or equal to 0 and p represents an integer greater than or equal to 2 and may be prepared by combining: (a) an arylbis(p-fluorophenyl) substituted sulfonium salt with a bis(trimethylsilylated)dithiol in a polar aprotic solvent.
Abstract translation: 提供具有式(I)的重复结构单元的聚合三芳基锍盐,其中R表示取代或未取代的芳基; X - 表示非亲核阴离子,n表示大于或等于0的整数,p表示大于或等于2的整数,可以通过以下方法制备:(a)芳基双(对氟苯基)取代的 锍盐与极性非质子溶剂中的双(三甲基硅烷基化)二硫醇。
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公开(公告)号:WO1998045382A1
公开(公告)日:1998-10-15
申请号:PCT/US1997016861
申请日:1997-09-23
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
Inventor: MINNESOTA MINING AND MANUFACTURING COMPANY , BOYD, Gary, T. , DEVOE, Robert, J. , GORODISHER, Ilya , YLITALO, David, A.
IPC: C09J05/00
CPC classification number: B41J2/16 , B41J2/162 , B41J2/1623 , B41J2/1637 , B41J2/164
Abstract: A shaped adhesive article is prepared by a method comprising the steps of shaping an adhesive mixture in a mold, said mold having one or more featured surfaces, said mixture including a first polymer precursor and a second polymer precursor, or a first polymer precursor and a thermoplastic polymer, polymerizing said first polymer precursor in said mold, to produce a shaped adhesive article having one or more featured surfaces, removing said shaped adhesive article from said mold, and adhering one or more of said featured surfaces to a substrate.
Abstract translation: 通过一种方法制备成型的粘合剂制品,该方法包括以下步骤:在模具中成型粘合剂混合物,所述模具具有一个或多个特征表面,所述混合物包括第一聚合物前体和第二聚合物前体,或第一聚合物前体和 热塑性聚合物,在所述模具中聚合所述第一聚合物前体,以产生具有一个或多个特征表面的成形粘合剂制品,将所述成形的粘合剂制品从所述模具中移出,并将所述特征表面中的一个或多个粘附到基材上。
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公开(公告)号:WO1998012021A1
公开(公告)日:1998-03-26
申请号:PCT/US1997000911
申请日:1997-01-23
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
Inventor: MINNESOTA MINING AND MANUFACTURING COMPANY , DEVOE, Robert, J. , DAHLKE, Gregg, D. , HARMON, Kimberly, K. , MASMAR, Craig, A.
IPC: B24D03/28
CPC classification number: B24D3/28 , B24D11/00 , Y10T442/2746 , Y10T442/2754
Abstract: A coated abrasive article comprises a backing, a first binder (i.e., a make coat) on the backing, and a plurality of abrasive particles in the first binder. The first binder precursor is an energy-curable melt-processable resin containing an epoxy resin, a polyester component, a polyfunctional acrylate component, and a curing agent for cross-linking the epoxy resin that is cured to provide a cross-linked make coating. The invention also relates to a method of producing such coated abrasive articles and a surface-treated porous cloth material.
Abstract translation: 涂覆的磨料制品包括背衬,背衬上的第一粘合剂(即,底漆)和第一粘合剂中的多个磨料颗粒。 第一粘合剂前体是含有环氧树脂,聚酯组分,多官能丙烯酸酯组分和用于交联环氧树脂的固化剂的能量可固化的可熔融加工的树脂,其被固化以提供交联的制造涂层。 本发明还涉及生产这种涂覆的磨料制品和表面处理的多孔布材料的方法。
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公开(公告)号:WO1996013538A3
公开(公告)日:1996-05-09
申请号:PCT/US1995014098
申请日:1995-10-31
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
Inventor: MINNESOTA MINING AND MANUFACTURING COMPANY , KAISAKI, David, A. , MITRA, Sumita, B. , SCHULTZ, William, J. , DEVOE, Robert, J.
IPC: C08G59/68
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公开(公告)号:WO1995003338A1
公开(公告)日:1995-02-02
申请号:PCT/US1994006263
申请日:1994-06-02
Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY
Inventor: MINNESOTA MINING AND MANUFACTURING COMPANY , LAMANNA, William, M. , PALAZZOTTO, Michael, C. , DEVOE, Robert, J. , MCCORMICK, Fred, B. , OLOFSON, Jeffrey, M. , SIEDLE, Allen, R. , WILLETT, Peggy, S.
IPC: C08F04/00
Abstract: Salts having a cationic portion of either a mono-, polyvalent metal center, onium salts or organometallic salts and a nonnucleophilic anion are useful as catalysts and initiators that may be photochemically or thermally-activated, and polymerizable compositions containing such catalysts and initiator salts and at least one of a cationic or free-radical addition polymerizable monomers, or catalyzed step-growth polymerizable monomers.
Abstract translation: 具有单价,多价金属中心,鎓盐或有机金属盐和非亲核阴离子的阳离子部分的盐可用作可光化学或热活化的催化剂和引发剂,以及含有这些催化剂和引发剂盐的聚合性组合物, 阳离子或自由基加成聚合单体中的至少一种或催化的步进生长可聚合单体。
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