公开(公告)号：WO1995001219A1

公开(公告)日：1995-01-12

申请号：PCT/US1994006942

申请日：1994-06-20

Applicant: MINNESOTA MINING AND MANUFACTURING COMPANY ,  McMASTER UNIVERSITY

Inventor： MINNESOTA MINING AND MANUFACTURING COMPANY ,  McMASTER UNIVERSITY ,  RILLING, Ken ,  DICKSON, James ,  CHILDS, Ronald ,  GAGNON, David, R.

IPC: B01D69/14

CPC classification number: B01D67/0088 ,  B01D39/083 ,  B01D39/086 ,  B01D69/141 ,  B01D2239/0414 ,  B01D2239/0471 ,  B01D2239/0618 ,  B01D2239/064 ,  B01D2239/1208 ,  B01D2239/1233 ,  B01J15/005 ,  B01J16/005 ,  B01J31/06 ,  B01J35/004 ,  B01J37/0219 ,  B01J2231/40 ,  B01J2231/52 ,  C08J9/405

Abstract: A method of preparing a porous article is provided. The method includes: contacting a porous substrate with a first reactant that enters pores of the substrate; and contacting the porous substrate bearing the first reactant with a second reactant that is capable of reacting with the first reactant in an interfacial polymerization reaction; the amounts of first and second reactant being selected such that there occurs no, or substantially no, closing of pores of the substrate by the formed polymer. The invention also provides a porous article bearing a compound which is photochemically reactive and capable of undergoing a substantially non-reversible chemical transformation upon exposure to ultraviolet, visible or near infrared irradiation. The photochemically reactive compound can be derivatized by irradiation and further reaction to provide a wide variety of useful membranes, for example, for microfiltration or for biochemical reactions and separations.

Abstract translation: 提供一种制备多孔制品的方法。 该方法包括：使多孔基材与进入基材孔隙的第一反应物接触; 以及使承载所述第一反应物的所述多孔基材与能够在界面聚合反应中与所述第一反应物反应的第二反应物接触; 选择第一和第二反应物的量使得通过所形成的聚合物不发生基本上没有或基本上没有封闭基底的孔。 本发明还提供了一种带有光化学反应性且能够在暴露于紫外线，可见光或近红外辐射时经历基本不可逆化学转化的化合物的多孔制品。 光化学反应性化合物可以通过辐射和进一步的反应进行衍生化，以提供多种有用的膜，例如微量过滤或生化反应和分离。