公开(公告)号：WO1991012204A1

公开(公告)日：1991-08-22

申请号：PCT/US1990000406

申请日：1990-02-06

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  VALYOCSIK, Ernest, William

IPC: C01B33/32

CPC classification number: B01J29/049 ,  C01B33/38

Abstract: A method for synthesizing a crystalline Kenyaite-type silicate comprises preparing a mixture comprising sources of alkali metal cations (AM), silica, a non-alkali metal (M) of valence n, water and an organic compound (R), selected from an alkylamine, a trialkylamine, a tetraalkylammonium compound and trimethylhexamethylene diamine, said alkyl having 1 to 12 carbon atoms, and said mixture having a composition, in terms of mole ratios, within the following ranges: SiO2/MmOn at least about 40, H2O/SiO2 5 to 200, OH /SiO2 0 to 5, AM/SiO2 0.05 to 3, R/SiO2 0.01 to 3. The mixture is maintained under sufficient conditions to form crystals of the required silicate and the silicate crystals are then recovered. The invention further includes a method for pillaring the resulting layered silicate.

Abstract translation: 合成结晶肯尼斯型硅酸盐的方法包括制备包含碱金属阳离子（AM），二氧化硅，n价的非碱金属（M），水和有机化合物（R）的混合物的混合物，其选自 烷基胺，三烷基胺，四烷基铵化合物和三甲基六亚甲基二胺，所述烷基具有1至12个碳原子，所述混合物的摩尔比在下列范围内：SiO2 / MmOn至少约40，H 2 O / SiO 2 5至200，OH - / SiO 2 0至5，AM / SiO 2 0.05至3，R / SiO 2 0.01至3。将混合物保持在足够的条件下以形成所需硅酸盐的晶体，然后回收硅酸盐晶体。 本发明还包括用于支撑所得到的层状硅酸盐的方法。

公开(公告)号：WO1989008608A1

公开(公告)日：1989-09-21

申请号：PCT/US1989000824

申请日：1989-02-27

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  VALYOCSIK, Ernest, William

IPC: C01B25/45

CPC classification number: B01J29/84 ,  B01J29/85 ,  C01B37/08

Abstract: A crystalline metalloaluminophosphate molecular sieve has the X-ray diffraction lines, (table I), and is crystallized from a reaction mixture comprising a C5-C7 alkyldiamine as directing agent.

Abstract translation: 结晶的金属铝磷酸盐分子筛具有X射线衍射线（表I），并从包含C5-C7烷基二胺作为引导剂的反应混合物中结晶。

公开(公告)号：WO1989004818A1

公开(公告)日：1989-06-01

申请号：PCT/US1988003944

申请日：1988-11-04

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  CHEN, Nai, Yuen ,  DESSAU, Ralph, Moritz ,  PARTRIDGE, Randall, David ,  VALYOCSIK, Ernest, William ,  VARTULI, James, Clarke ,  VENKAT, Chaya, Rao

IPC: C07C05/333

CPC classification number: C10G35/095 ,  B01J29/035 ,  B01J29/061 ,  B01J29/405 ,  B01J29/44 ,  B01J29/7057 ,  B01J29/7069 ,  B01J29/74 ,  B01J29/7415 ,  B01J29/85 ,  B01J29/86 ,  C07C5/417

Abstract: A catalyst composition comprises a hydrogenation/dehydrogenation metal, and a non-acidic crystalline microporous material containing indium, tin, thallium or lead. The catalyst composition is particularly useful for reforming light naphtha fractions.

Abstract translation: 催化剂组合物包含氢化/脱氢金属和含有铟，锡，铊或铅的非酸性结晶微孔材料。 催化剂组合物特别可用于重整轻石脑油馏分。

公开(公告)号：WO1989008607A1

公开(公告)日：1989-09-21

申请号：PCT/US1989000811

申请日：1989-02-27

Applicant: MOBIL OIL CORPORATION

Inventor： MOBIL OIL CORPORATION ,  VALYOCSIK, Ernest, William

IPC: C01B25/36

CPC classification number: B01J29/83 ,  C01B37/04

Abstract: A crystalline aluminophosphate composition comprising crystals exhibiting the characteristic X-ray diffraction pattern (I) is synthesized from a reaction mixture containing a C5-C7 alkyldiamine as directing agent.

Abstract translation: 包含表现出特征X射线衍射图（I）的晶体的结晶磷酸铝组合物由含有C5-C7烷基二胺作为引导剂的反应混合物合成。