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公开(公告)号:WO2019094191A1
公开(公告)日:2019-05-16
申请号:PCT/US2018/057284
申请日:2018-10-24
CPC分类号: C08F2/18 , C08F12/36 , C08F212/08 , C08F212/36
摘要: Provided is a collection of polymeric beads, wherein the beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV; wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units; wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000; wherein MVRATIO = MVSEQ / MVAV; and wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.
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公开(公告)号:WO2019067377A1
公开(公告)日:2019-04-04
申请号:PCT/US2018/052513
申请日:2018-09-25
发明人: LAUGHLIN, Kenneth , SCHULTZ, Alfred, K. , REFFNER, John , REDWINE, Oscar , SAMMLER, Robert , SAVO, Andrew, M.
IPC分类号: C08F212/08 , C08F2/20 , B01J39/20
CPC分类号: B01J39/20 , C08F8/36 , C08F212/08 , C08F2800/20 , C08F2/20 , C08F212/36 , C08F230/06
摘要: A polymeric bead having radius R wherein the polymer comprises 0.3% to 20% by weight, based on the weight of the polymer, of polymerized units of one or more multifunctional vinyl monomer and 80% to 99.7% by weight, based on the weight of the polymer, of polymerized units of one or more monofunctional vinyl monomer, (a) wherein the polymerized units of multifunctional vinyl monomer have radial distribution factor MR of 0.9 to 1.1, and (b) wherein some of the vinyl groups in the polymerized units of multivinyl monomer are unreacted, and the unreacted vinyl groups have a radial distribution factor VR of 2.5 or higher.
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