公开(公告)号：WO2019094191A1

公开(公告)日：2019-05-16

申请号：PCT/US2018/057284

申请日：2018-10-24

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： SAVO, Andrew M. ,  SCHULTZ, Alfred K. ,  LAUGHLIN, Kenneth ,  REFFNER, John

IPC: C08F12/36 ,  C08F12/08 ,  C08F2/18 ,  C08L25/08

CPC classification number: C08F2/18 ,  C08F12/36 ,  C08F212/08 ,  C08F212/36

Abstract: Provided is a collection of polymeric beads, wherein the beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV; wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units; wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000; wherein MVRATIO = MVSEQ / MVAV; and wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.

公开(公告)号：WO2017222978A1

公开(公告)日：2017-12-28

申请号：PCT/US2017/038123

申请日：2017-06-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： CARLIN, William ,  CRAWFORD, Patricia ,  DEETZ, Martin ,  ROHANNA, John C. ,  SCHULTZ, Alfred K. ,  VERSAGLI, Lauren

IPC: C08F8/26 ,  C08F12/18 ,  C08F12/24 ,  B01J20/26 ,  C02F1/28 ,  C02F1/42 ,  C02F101/20 ,  C08F212/08 ,  C08F212/36 ,  C08F8/24 ,  C08F8/12 ,  C08F8/02

Abstract: Provided is a method of treating a vinyl aromatic resin (I) comprising (a) bringing the vinyl aromatic resin (I) into contact with an alcohol, and maintaining the contact between the vinyl aromatic resin (I) and the alcohol for 10 minutes or more, and (b) bringing the vinyl aromatic resin into contact with a base. wherein the vinyl aromatic resin (I), prior to steps (a) and (b), has benzyl chloride groups, benzyl alcohol groups, and methylene bridge groups.

Abstract translation: 提供了一种处理乙烯基芳族树脂（I）的方法，所述方法包括：（a）使乙烯基芳族树脂（I）与醇接触，并保持乙烯基芳族树脂（I ）和醇10分钟以上，（b）使乙烯基芳香族树脂与碱接触。 其中在步骤（a）和（b）之前，乙烯基芳族树脂（I）具有苄基氯基团，苯甲醇基团和亚甲基桥基团。

公开(公告)号：WO2017048749A1

公开(公告)日：2017-03-23

申请号：PCT/US2016/051581

申请日：2016-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： SLAGT, J. Marc ,  SCHULTZ, Alfred K.

IPC: C02F1/42 ,  B01J49/00

CPC classification number: C02F1/42 ,  B01J47/028 ,  B01J49/08 ,  B01J49/57 ,  C02F2303/16

Abstract: Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of -1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RB) having pH of 10 or higher, to form a mixture B2RB, (C) then separating acrylic resin (B4) from said mixture B2RB.

Abstract translation: 本发明提供一种再生丙烯酸树脂（B2）的方法，其包括（A）提供计算出Hansch参数为-1.0至2.5的丙烯酸树脂（B2）的颗粒的集合，其中一种或多种腐殖酸，一种或多种富勒烯 酸或其混合物被吸附到所述丙烯酸树脂（B2）上，和（B）使丙烯酸树脂（B2）的颗粒的收集与pH为10或更高的水溶液（RB）接触以形成 混合物B2RB，（C）然后从所述混合物B2RB分离丙烯酸树脂（B4）。

公开(公告)号：WO2014204686A1

公开(公告)日：2014-12-24

申请号：PCT/US2014/041458

申请日：2014-06-09

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： GREEN, George D. ,  ROHANNA, John C. ,  SCHULTZ, Alfred K.

IPC: C08F8/30 ,  C08F8/04 ,  C08F212/36 ,  C08F212/08 ,  B01J41/12

CPC classification number: B01J41/14 ,  B01J41/05 ,  B01J41/07 ,  B01J41/13 ,  B01J45/00 ,  C08F8/04 ,  C08F8/30 ,  C08F212/36 ,  C08F212/08

Abstract: A method for making an anion exchange or chelant resin comprising a vinyl aromatic polymer including a repeating unit comprising an aromatic ring substituted with an aliphatic amino group, wherein the method comprises the step of reacting a vinyl aromatic polymer with a nitro compound comprising from 1 to 12 carbon atoms with the proviso that the α carbon includes at least one hydrogen.

Abstract translation: 一种阴离子交换剂或螯合树脂的制造方法，其包含乙烯基芳族聚合物，所述乙烯基芳族聚合物包括由脂肪族氨基取代的芳香环的重复单元，其中所述方法包括使乙烯基芳族聚合物与硝基化合物反应的步骤，所述硝基化合物包含1〜 12个碳原子，条件是α碳包括至少一个氢。

公开(公告)号：WO2018120024A1

公开(公告)日：2018-07-05

申请号：PCT/CN2016/113515

申请日：2016-12-30

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY ,  COSTEUX, Chunxia ,  ZU, Chengli ,  YANG, Liu ,  SCHULTZ, Alfred K.

Inventor： COSTEUX, Chunxia ,  ZU, Chengli ,  YANG, Liu ,  SCHULTZ, Alfred K.

IPC: C07C37/20 ,  B01J31/10 ,  C07C39/16

Abstract: Provided is a catalyst composition comprising (a) a collection of resin beads having sulfonic acid functional groups, (b) a promoter having a thiol group and an amine group, and (c) an antioxidant having the structure (I), wherein each of R 1 and R 2 , and R 3 is hydrogen or a substituted or unsubstituted alkyl or alkenyl group wherein n is 0 to 10, with the proviso that when R 3 contains one or more nitrogen atoms, n is not 1 or 2.

公开(公告)号：WO2017222981A1

公开(公告)日：2017-12-28

申请号：PCT/US2017/038128

申请日：2017-06-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： CARLIN, William ,  ROHANNA, John C. ,  SCHULTZ, Alfred K. ,  SUMMERFIELD, James

IPC: B01J20/26 ,  C02F101/20

CPC classification number: B01J20/261 ,  B01J20/265 ,  B01J20/3085 ,  B01J45/00 ,  B01J47/04 ,  C02F1/285 ,  C02F2101/20

Abstract: A method of removing colloidal cobalt from an aqueous composition comprising bringing the aqueous composition into contact with a vinyl aromatic resin, wherein the vinyl aromatic resin comprises benzyl alcohol groups, benzyl ether groups, and methylene bridge groups, wherein the vinyl aromatic resin has a chlorine content, by weight based on the weight of resin, of 10,000 ppm or less.

Abstract translation: 一种从含水组合物中除去胶态钴的方法，包括使所述含水组合物与乙烯基芳族树脂接触，其中所述乙烯基芳族树脂包含苯甲醇基，苄醚基和亚甲基桥基， 其中乙烯基芳族树脂的氯含量以树脂的重量计为10,000ppm或更低

公开(公告)号：WO2017222980A1

公开(公告)日：2017-12-28

申请号：PCT/US2017/038125

申请日：2017-06-19

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： BURNETT, G. Leslie ,  DE ALANIZ, Javier Read ,  ROHANNA, John C. ,  SCHULTZ, Alfred K. ,  ROSENBERG, Steven

IPC: C08F8/26 ,  C08F8/06 ,  C08F8/12 ,  C08F8/02 ,  C02F1/28 ,  B01D15/00 ,  B01J20/26 ,  B01J39/18 ,  C08F212/08

Abstract: Provided is vinyl aromatic resin comprising benzyl alcohol groups, benzyl ether groups, and methylene bridge groups, wherein the mole ratio of the benzyl ether groups to the methylene bridge groups is from 0.002:1 to 0.1:1, wherein the vinyl aromatic resin either has no amine groups or else has amine groups in a mole ratio of the sum of all amine groups to aromatic rings of 0.1:1 or lower.

Abstract translation: 提供了包含苄醇基团，苄醚基团和亚甲基桥基团的乙烯基芳族树脂，其中苄基醚基团与亚甲基桥基团的摩尔比为0.002：1至0.1：1 其中所述乙烯基芳族树脂不具有胺基或者具有胺基，所有胺基与芳环之和的摩尔比为0.1：1或更低。

公开(公告)号：WO2017048748A1

公开(公告)日：2017-03-23

申请号：PCT/US2016/051580

申请日：2016-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： SLAGT, J. Marc ,  SCHULTZ, Alfred K.

IPC: C02F1/42 ,  B01J49/00

CPC classification number: C02F1/42 ,  B01J47/028 ,  B01J49/08 ,  B01J49/57 ,  C02F2303/16

Abstract: Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of -1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RA) having pH of 4 or lower, to form a mixture B2RA, (C) then separating acrylic resin (B3) from said mixture B2RA.

Abstract translation: 提供一种再生丙烯酸树脂（B2）的方法，其包括（A）提供计算出Hansch参数为-1.0至2.5的丙烯酸树脂（B2）的颗粒的集合，其中一种或多种腐殖酸，一种或多种富勒烯 酸或其混合物被吸附到所述丙烯酸树脂（B2）上，和（B）使丙烯酸树脂（B2）的颗粒的收集与pH为4或更低的水溶液（RA）接触以形成 混合物B2RA，（C）然后从所述混合物B2RA分离丙烯酸树脂（B3）。

公开(公告)号：WO2017048746A1

公开(公告)日：2017-03-23

申请号：PCT/US2016/051577

申请日：2016-09-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： SLAGT, J. Marc ,  SCHULTZ, Alfred K.

IPC: C02F1/42 ,  B01J49/00

CPC classification number: C02F1/42 ,  B01J47/028 ,  B01J49/08 ,  B01J49/57 ,  C02F2001/422 ,  C02F2303/16

Abstract: Provided is a method of purifying water comprising (a) providing an aqueous solution (A) that has pH of 5.5 or lower and that comprises (i) one or more dissolved organic compounds in an amount of 5 mg/L or more, measured as dissolved organic carbon, and (ii) 95% or more water by weight based on the weight of the aqueous solution (A), and (b) bringing the aqueous solution (A) into contact with a collection of particles of acrylic resin (B) that has calculated Hansch parameter of -1.0 to 2.5, and (c) then separating an aqueous solution (C) from the collection of particles of acrylic resin (B).

Abstract translation: 提供一种净化水的方法，其包括（a）提供pH5.5或更低的水溶液（A），并且包含（i）一种或多种溶解的有机化合物，其量为5mg / L或更高，以 溶解的有机碳，和（ii）基于水溶液（A）的重量的95重量％以上的水，和（b）使水溶液（A）与丙烯酸树脂（B ），计算出Hansch参数为-1.0〜2.5，（c）然后从丙烯酸树脂（B）的颗粒收集液中分离水溶液（C）。

公开(公告)号：WO2014058756A1

公开(公告)日：2014-04-17

申请号：PCT/US2013/063637

申请日：2013-10-07

Applicant: ROHM AND HAAS COMPANY ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： SCHULTZ, Alfred K. ,  CARDOEN, Gregoire ,  HARRIS, William I. ,  HARRIS, William J. ,  MARSTON, Charles R. ,  MOLL, David J.

IPC: C08F2/18

CPC classification number: C08F224/00 ,  B01J39/20 ,  B01J41/14 ,  C08F2/18 ,  C08F8/30 ,  C08F8/34 ,  C08F12/22 ,  C08F212/08 ,  C08F212/14 ,  C08F212/36

Abstract: A water-insoluble copolymer including an epoxide containing structural unit represented by Formula (I), wherein: the epoxide containing group is positioned meta, ortho or para on the ring relative to the bond linkage with the polymer backbone; L is an optional linking group; and R 1 , R 2 and R 3 are independently selected from: hydrogen, or a substituted or unsubstituted hydrocarbyl group.

Abstract translation: 一种包含由式（I）表示的含环氧化物的结构单元的水不溶性共聚物，其中：所述环氧化物基团相对于与聚合物主链的键键在环上位于环上，邻位或对位; L是可选的连接基团; 并且R 1，R 2和R 3独立地选自：氢或取代或未取代的烃基。