摘要:
A thermoplastic composition comprising: a polymer material; and a passivated inorganic chromophore comprising an inorganic chromophore and a passivation layer, wherein the inorganic chromophore has the formula: AM1-xM?xM?yO3+y, wherein A, M, M?, M?, x, and y are as provided herein, and wherein the passivation layer is derived from a passivation material comprising a polysiloxane having at least one functional group that is hydride, hydroxy, alkoxy, aryloxy, epoxy, carboxy, amino, or a combination thereof.
摘要:
A polycarbonate copolymer comprises aromatic carbonate units; optionally siloxane units; and resorcinol arylate ester units derived from a resorcinol composition having a hydroquinone content of 50 to 1200 parts per million, a catechol content of 5 to 29 parts per million, and a phenol content of 0 to 2400, each as determined by high performance liquid chromatography, and further comprising an acid stabilizer.
摘要:
The disclosure concerns compositions and methods to improve remote phosphor optical properties in polycarbonate. One method includes combining a phosphor component and a polycarbonate component to form a phosphor-polycarbonate composition; and at a fixed phosphor concentration, combining the phosphor-polycarbonate composition with a diffusing agent comprising polytetrafluoroethylene (PTFE), wherein the diffusing agent diffuses light, and wherein the phosphor-polycarbonate composition exhibits an increase in chromaticity coordinate (CIEx) as determined by CIE 1931 or increase in CIE 1976 (u',v') of at least about 5% relative to a substantially similar reference composition in the absence of PTFE. Also described are methods to increase yield and reduce product accumulation of an extruded thermoplastic polycarbonate composition through the mixing of PTFE with a phosphor-polycarbonate (PCP)to form a PCP-PTFE component as well as a method forming a phosphor-polycarbonate master batch (PPCMB) composition, and during extrusion, adding PTFE to the PPCMB composition to form a PPCMB-PTFE composition.
摘要:
A method for predicting the material performance of a polyimide, the method comprising: dissolving a sample of the polyimide in a solvent to form a polyimide solution; determining a transmittance of the polyimide solution at a wavelength of 400 to 800 nm, preferably at a wavelength of 450 to 600 nm to obtain a test value; inputting the test value into a predetermined prediction equation to obtain a predicted material performance value; and determining if the predicted material performance value is within a desired range of material performance.
摘要:
A thermoplastic composition includes: a thermoplastic polymer including from about 30 wt% to about 90 wt% poly(methyl methacrylate) (PMMA) and from about 5 wt% to about 70 wt% of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 20 wt% to about 60 wt%; and a plurality of photoluminescent materials including quantum dots.
摘要:
A multi-layer film may comprise a first quantum dot layer comprising a first polymer matrix and a plurality of first quantum dots disposed therein. A second quantum dot layer may be disposed adjacent the first quantum dot layer and may comprise a second polymer matrix and a plurality of second quantum dots disposed therein. The plurality of first quantum dots may be spaced from each other within the first polymer matrix to define gaps there between. The plurality of first quantum dots may emit a first secondary light upon excitation by light produced from a light source. At least a portion of the plurality of second quantum dots may be positioned to align with the gaps defined in the first polymer matrix along an axis that is orthogonal to the first quantum dot layer and the second quantum dot layer.
摘要:
A composition for electroless plating comprises: from 9 to 29 weight percent, 9.7 to 29 weight percent, or 10 to 29 weight percent, of a first graft rubber copolymer which comprises the polymerized form of at least one conjugated diene monomer and at least one monovinyl aromatic monomer, from 70 to 90 weight percent, preferably 70-89.7 weight percent, more preferably 70 to 85 weight percent, of ungrafted styrenic polymer, from 0.1 to 10 weight percent of a core/shell diene-based rubber having particle size of 100 to 500 nanometers (nm), one or more of a stabilizer and/or antioxidant in total amount of from 0.1 to 5 weight percent, a fatty acid or a salt of fatty acid in an amount of from 0.1 to 2 weight percent, 0 to 5 weight percent of a mold release agent, 0 to 1 weight percent of a metal oxide, 0 to 3 weight percent of a lubricant, and 0 to 20 weight percent of polycarbonate wherein weight percent and ppm are based on total weight of the composition. The composition can be formed into an article having a metal coating electroless plated on the composition.
摘要:
A method of forming articles from acrylonitrile-butadiene-styrene, the method comprising: feeding a monomer stream comprising a petrochemical monomer into a reactor; contacting the petrochemical monomer with a polymerization activator within the reactor to produce a polymerized stream comprising rubber, latex, or a combination thereof and withdrawing the polymerized stream from the reactor; passing the polymerized stream through a filter to produce a filtered product stream, wherein the filter is a continuously self-cleaning filter; passing the filtered product stream through a grafting unit comprising acrylonitrile and styrene to produce acrylonitrile-butadiene-styrene; and forming an article from the acrylonitrile- butadiene - styrene, wherein the article is an extruded sheet, a molded part, or a combination thereof.
摘要:
In an embodiment, an analytical method comprises dissolving a polycarbonate in a non-chlorinated solvent to form a polycarbonate solution; adding the polycarbonate solution dropwise to boiling water to form a mixture comprising a chloride solution fraction and a polycarbonate fraction; separating the polycarbonate fraction from the chloride solution fraction; measuring at least one of a polymeric chloride content of the polycarbonate fraction and a ionic chloride content of the chloride solution fraction. In another embodiment, a polycarbonate polymerization process comprises analyzing a chlorate content of an alkali metal hydroxide solution and interfacially polymerizing phosgene and a dihydroxy compound in the presence of the alkali metal hydroxide solution and an interfacial catalyst to form a polycarbonate.
摘要:
Thermoplastic compositions include: (a) from about 30 wt% to about 95 wt% poly(methyl methacrylate) (PMMA); and (b) from about 5 wt% to about 70 wt% of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt% to about 45 wt%. Methods for making a molded article, include: (a) combining from about 30 wt% to about 95 wt% PMMA and from about 5 wt% to about 70 wt% of a poly(carbonate-siloxane) copolymer having a siloxane content of from about 25 wt% to about 45 wt% to form a blend; (b) melt processing and pelletizing the blend; and (c) injection molding the article from the melt processed and pelletized blend.