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    PREPARATION OF 4,4'-DIHYDROXY-ALPHA-ALKYLSTILBENES AND 4,4'-DIHYDROXY-ALPHA, ALPHA'-DIALKYLSTILBENES
    2.
    发明申请
    PREPARATION OF 4,4'-DIHYDROXY-ALPHA-ALKYLSTILBENES AND 4,4'-DIHYDROXY-ALPHA, ALPHA'-DIALKYLSTILBENES 审中-公开
    4,4'-二羟基-AlPHA-ALKYLSTILBENES的制备和4,4'-二羟基-AlPHA，ALPHA-二烷基

    公开(公告)号：WO1995015301A1

    公开(公告)日：1995-06-08

    申请号：PCT/US1994013480

    申请日：1994-11-21

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HEFNER, Robert, E., Jr. ,  VILLARREAL, Maria, I. ,  CARR, David, A.

    IPC: C07C37/20

    CPC classification number: C07C39/215 ,  C07C37/20

    Abstract: 4,4'-Dihydroxy-alpha-alkylstilbenes of high purity were prepared by reacting at a temperature of from -20 DEG C to 20 DEG C a mixture of: (1) at least one alpha-haloketone; (2) at least one phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound; and (3) at least one strong protonic acid or Lewis acid, such that the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound: alpha-haloketone(s) is from 0.1:1 to 1.9:1, and the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound: alpha-haloketone(s):strong protonic acid or Lewis acid is from 0.1:1:0.0026 to 1.9:1:0.95. The high purity 4,4'-dihydroxy-alpha-alkylstilbenes are useful for the advancement of epoxy resins, for the preparation of phenoxy resins and for the preparation of epoxy resins.

    Abstract translation: 通过在-20℃至20℃的温度下使下列混合物反应制备高纯度的4,4'-二羟基-α-烷基二苯乙烯：（1）至少一种α-卤代酮; （2）至少一种含酚羟基的化合物或含烷氧基的芳族化合物; 和（3）至少一种强质子酸或路易斯酸，使得含酚羟基的化合物或含烷氧基的芳族化合物：α-卤代酮的摩尔比为0.1:1至1.9:1，并且 含酚羟基化合物或含烷氧基的芳族化合物：α-卤代酮：强质子酸或路易斯酸的摩尔比为0.1：1：0.0026至1.9：1：0.95。 高纯度4,4'-二羟基-α-烷基芪可用于环氧树脂的前进，苯氧基树脂的制备和环氧树脂的制备。

    BIS(AMINOPHENOXY)-ALPHA-SUBSTITUTED STILBENES, CURABLE MIXTURES WITH EPOXY RESINS AND CURED PRODUCTS
    3.
    发明申请
    BIS(AMINOPHENOXY)-ALPHA-SUBSTITUTED STILBENES, CURABLE MIXTURES WITH EPOXY RESINS AND CURED PRODUCTS 审中-公开
    BIS（氨基苯氧基）-ALPHA-取代的苯乙烯，可固化的混合物与环氧树脂和固化产品

    公开(公告)号：WO1994026690A1

    公开(公告)日：1994-11-24

    申请号：PCT/US1993012060

    申请日：1993-12-10

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  DURVASULA, V., Rao ,  HEFNER, Robert, E., Jr. ,  EARLS, Jimmy, D.

    IPC: C07C217/90

    CPC classification number: C08G59/504 ,  C07D303/24 ,  C08G59/20

    Abstract: The present invention concerns bis(aminophenoxy)-alpha-substituted stilbenes represented by Formula (I) wherein each R is independently hydrogen or a hydrocarbyl or hydrocarbyloxy group having from one to about 10, preferably one to about 4, carbon atoms, a halogen atom, preferably chlorine, bromine or fluorine, a nitro group, a nitrile group or a -CO-R group; each R is independently hydrogen or a hydrocarbyl group having from one to about 10, preferably one to about 6, carbon atoms; X is a (a) or (b) group, each R is independently hydrogen or a hydrocarbyl group having from one to about 10, preferably one to about 2, carbon atoms; R is a hydrocarbyl group having from one to about 10, preferably one to about 2, carbon atoms and may be chlorine or a nitrile group, when n has a value of zero; and n has a value of zero or one. Bis(aminophenoxy)-alpha-substituted stilbenes are prepared by reacting a dihydroxy-alpha-substituted stilbene with a halonitrobenzene in the presence of a basic acting substance such as potassium carbonate and hydrogenating the resulting bis(nitrophenoxy)-alpha-substituted stilbene to convert the nitro groups to amino groups. These compounds are useful as curing agents for epoxy resins.

    Abstract translation: 本发明涉及由式（I）表示的双（氨基苯氧基）-α-取代的二苯乙烯，其中每个R独立地为氢或具有1至约10个，优选1至约4个碳原子的烃基或烃氧基，卤素原子 优选氯，溴或氟，硝基，腈基或-CO-R 2基团; 每个R 1独立地为氢或具有1至约10个，优选1至约6个碳原子的烃基; X为（a）或（b）基团，每个R 2独立地为氢或具有1至约10个，优选1至2个碳原子的烃基; 当n为零时，R 3为具有1至约10个，优选1至约2个碳原子的烃基，并且可为氯或腈基; n的值为零或一。 双（氨基苯氧基）-α-取代的二苯乙烯通过在碱性作用物质如碳酸钾存在下使二羟基-α-取代的二苯乙烯与卤代硝基苯反应并氢化得到的双（硝基苯氧基）-α-取代的二苯乙烯来转化 硝基为氨基。 这些化合物可用作环氧树脂的固化剂。

    POLYESTERAMIDE CONCRETE
    4.
    发明申请
    POLYESTERAMIDE CONCRETE 审中-公开
    聚酰胺混凝土

    公开(公告)号：WO1985001948A1

    公开(公告)日：1985-05-09

    申请号：PCT/US1984001689

    申请日：1984-10-18

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HEFNER, Robert, E., Jr.

    IPC: C08L67/06

    CPC classification number: C04B26/10 ,  C04B26/04 ,  C08F290/062 ,  C08G69/44 ,  C08L77/12 ,  Y02W30/92 ,  C04B14/06 ,  C04B14/30 ,  C04B14/34 ,  C04B18/08 ,  C04B20/0048

    Abstract: Polymer concrete compositions are made from norbornyl modified unsaturated polyesteramide compositions. The curable concrete composition contains 2 to 20 percent by weight of the polyesteramide composition and 98 to 80 percent by weight of an aggregate such as sand, gravel, silica flour, etc. The polyesteramide composition contains norbornyl modified polyesteramide, ethylenically unsaturated monomers, such as styrene with or without a vinyl reactive additive. The polyesteramide can be further modified to contain a copolymerized polyether polyol having a functionality of three or more, a copolymerized poly (2-alkyl-2-oxazoline) or a copolymerized carboxylated rubber. The vinyl reactive additive can be a vinyl ester resin or a vinyl terminated urethane oligomer. When cured, the curable concrete composition gives a polymer concrete with better tensile and compressive strength with the advantage that the composition cures under water and in the presence of moisture.

    Abstract translation: 聚合物混凝土组合物由降冰片烯基改性的不饱和聚酯酰胺组合物制成。 可固化混凝土组合物含有2-20重量％的聚酯酰胺组合物和98-80重量％的骨料如沙子，砾石，二氧化硅粉等。聚酯酰胺组合物含有降冰片烯基改性聚酯酰胺，烯属不饱和单体，如 具有或不具有乙烯基反应性添加剂的苯乙烯。 可以将聚酯酰胺进一步改性为含有官能度为3以上的共聚聚醚多元醇，共聚的聚（2-烷基-2-恶唑啉）或共聚的羧化橡胶。 乙烯基反应性添加剂可以是乙烯基酯树脂或乙烯基封端的聚氨酯低聚物。 当固化时，可固化的混凝土组合物得到具有更好拉伸强度和抗压强度的聚合物混凝土，其优点是组合物在水和湿气存在下固化。

    HYDROXY ETHER POLYMERS AS THERMOPLASTIC BARRIER RESINS
    5.
    发明申请
    HYDROXY ETHER POLYMERS AS THERMOPLASTIC BARRIER RESINS 审中-公开
    羟基醚聚合物作为热塑性树脂树脂

    公开(公告)号：WO1999023134A1

    公开(公告)日：1999-05-14

    申请号：PCT/US1997020096

    申请日：1997-11-04

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  WHITE, Jerry, E. ,  SILVIS, H., Craig ,  MANG, Michael, N. ,  KRAM, Shari, L. ,  HEFNER, Robert, E., Jr.

    IPC: C08G59/14

    CPC classification number: C08G59/66 ,  C08G59/1433 ,  C08G59/245 ,  C08G59/42 ,  C08G59/444 ,  C08G59/50 ,  C08G59/621

    Abstract: Thermoplastic hydroxy ether polymers containing inertly substituted or unsubstituted stillbene and ether linkages in the backbone chain and pendant hydroxyl moieties are prepared by reacting (a) an inertly substituted or unsubstituted dihydroxy-stillbene with (b) a diglycidyl ether and, optionally, (c) a difunctional monomer under conditions sufficient to cause the hydroxyl moieties to react with the epoxy moieties to form ether linkages and pendant hydroxyl moieties. The polymers exhibit excellent oxygen barrier properties and are useful in packaging oxygen-sensitive materials.

    Abstract translation: 通过（a）惰性取代或未取代的二羟基 - 还原酚与（b）二缩水甘油醚和任选地（c）的二缩水甘油醚反应，制备在主链和侧羟基部分含惰性取代或未取代的未丁苯和醚键的热塑性羟基醚聚合物， 双官能单体在足以使羟基部分与环氧部分反应以形成醚键和侧羟基部分的条件下进行。 聚合物表现出优异的氧气阻隔性能，并且可用于包装氧敏感材料。

    LOW GLOSS, HIGH IMPACT STRENGTH POWDER COATING RESINS
    9.
    发明申请
    LOW GLOSS, HIGH IMPACT STRENGTH POWDER COATING RESINS 审中-公开
    低光泽，高冲击强度粉末涂料树脂

    公开(公告)号：WO1987006242A1

    公开(公告)日：1987-10-22

    申请号：PCT/US1987000794

    申请日：1987-04-06

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HEFNER, Robert, E., Jr. ,  HAYNES, Deborah, I.

    IPC: C08F212/08

    CPC classification number: C08F299/026 ,  C08G59/066 ,  C08G59/1433 ,  C08G59/226

    Abstract: Advanced epoxy resin compositions provide improvements in processability, filler acceptability and rheology through the employment of epoxy resins with reduced viscosity per unit epoxide equivalent weight. The compositions are useful as powder coatings on metallic substrates. The products are obtained through the polymerization in the presence of a polymerization catalyst of a monomer mixture containing at least one vinyl aromatic monomer such as styrene, an epoxide group - reactive functionality and polymerizable ethylenically unsaturated group - containing compound such as methacrylic acid, and optionally a hydroxyalkyl(meth)acrylate or alkyl(meth)acrylic such as hydroxyethyl acrylate. The monomer mixture is polymerized in the presence of a reaction product of a digllycidyl ether of a dihydric phenol such as bisphenol A and an epoxide group - reactive functionality and polymerizable ethylenically unsaturated group - containing compound such as methacrylic acid. The resulting polymerization product is advanced in the presence of an advancement catalyst with a dihydric phenol such as bisphenol A.

    Abstract translation: 先进的环氧树脂组合物通过使用每单位环氧当量重量降低的粘度的环氧树脂，提高了加工性，填料可接受性和流变性。 该组合物可用作金属基材上的粉末涂料。 在含有至少一种乙烯基芳族单体如苯乙烯，环氧基 - 反应性官能团和可聚合的含烯属不饱和基团的化合物如甲基丙烯酸的单体混合物的聚合催化剂存在下，通过聚合获得产物，和任选地 （甲基）丙烯酸羟烷基酯或（甲基）丙烯酸烷基酯如丙烯酸羟乙酯。 单体混合物在二羟基苯酚如双酚A的二缩水甘油醚和环氧基 - 反应性官能团的反应产物和可聚合的含烯属不饱和基团的化合物如甲基丙烯酸的存在下聚合。 所得到的聚合产物在二羟基酚如双酚A的进行催化剂存在下进行。

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