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    BISCYCLOPENTADIENYL DIENE COMPLEXES
    1.
    发明申请
    BISCYCLOPENTADIENYL DIENE COMPLEXES 审中-公开
    双辛基二烯基二苯醚复合物

    公开(公告)号：WO1996004290A1

    公开(公告)日：1996-02-15

    申请号：PCT/US1995008813

    申请日：1995-07-14

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  TIMMERS, Francis, J. ,  DEVORE, David, D. ,  STEVENS, James, C. ,  ROSEN, Robert, K. ,  PATTON, Jasson, T. ,  NEITHAMER, David, R.

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  Y10S526/901 ,  Y10S526/943

    Abstract: Biscyclopentadienyl, Group 4 transition metal complexes are formed by contacting a biscyclopentadienyl Group 4 metal halide, hydrocarbyl, hydrocarbyloxy or amide complex with a conjugated diene. Uniquely, the ansa-rac diastereomer is selectively isolated and may be reconverted to the halide form if desired. When combined with standard activating cocatalysts or activated with an activating technique, the complexes form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

    Abstract translation: 通过使双环戊二烯基第4族金属卤化物，烃基，烃氧基或酰胺络合物与共轭二烯接触来形成双环戊二烯基，第4族过渡金属络合物。 独特的是，所述外消旋非对映异构体是选择性分离的，并且如果需要可以再转化为卤化物形式。 当与标准活化助催化剂结合或用活化技术活化时，络合物形成用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。

    METALLOCENE COCATALYST
    4.
    发明申请
    METALLOCENE COCATALYST 审中-公开

    公开(公告)号：WO1997036937A1

    公开(公告)日：1997-10-09

    申请号：PCT/US1997004247

    申请日：1997-03-20

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  TIMMERS, Francis, J. ,  NEITHAMER, David, R.

    IPC: C08F04/603

    CPC classification number: C08F10/00 ,  C08F4/61908 ,  C08F4/61916 ,  C08F4/6192 ,  C08F4/65908

    Abstract: Boratabenzene cocatalysts, especially novel pentafluorophenyl boratabenzenes, are useful cocatalysts or activators with metallocenes. They are less expensive than prior art activators, are soluble and offer more irreversible reactions. Compositions comprise at least one metallocene catalyst and at least one dihydroboratabenzene or anion thereof. Processes include polymerizations with metallocenes in the presence of boratabenzene cocatalyst and activation process including bulk electrolysis techniques.

    Abstract translation: 硼化物助催化剂，特别是新的五氟苯基硼苯偶氮，是具有金属茂的有用的助催化剂或活化剂。 它们比现有技术的活化剂便宜，是可溶的并且提供更多的不可逆反应。 组合物包含至少一种金属茂催化剂和至少一种二氢硼烷基或其阴离子。 方法包括在硼烷助催化剂存在下与茂金属的聚合，以及包括大量电解技术的活化方法。

    PREPARATION OF BISCYCLOPENTADIENYL DIENE COMPLEXES
    5.
    发明申请
    PREPARATION OF BISCYCLOPENTADIENYL DIENE COMPLEXES 审中-公开
    双联二苯基二烯配合物的制备

    公开(公告)号：WO1997025336A1

    公开(公告)日：1997-07-17

    申请号：PCT/US1996019281

    申请日：1996-12-05

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  TIMMERS, Francis, J. ,  DEVORE, David, D. ,  NEITHAMER, David, R.

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  Y10S526/943

    Abstract: Bicyclopentadienyl Group 4 transition metal complexes containing a conjugated diene ligand group wherein the diene is bound to the transition metal either in the form of a sigma -complex or a pi -complex are readily prepared by reacting in any order: a) a Group 4 metal salt corresponding to the formula M'X3 or M''X4, or a Lewis base adduct thereof, b) a conjugated diene, D', c) a reducing agent, and d) a compound of the formula: CpM* or (Cp-Cp)M*n, wherein M' is titanium, zirconium or hafnium in the +3 formal oxidation state; M'' is titanium, zirconium or hafnium in the +4 formal oxidation state; X is a halide, C1-6 hydrocarbyloxy or di(C1-6 hydrocarbyl)amido group; D' is an uncoordinated diene having the same number of carbons as D and the same substitution pattern as D; M* is a Group 1 or 2 metal cation, a Grignard reagent cation or a tri(C1-4 hydrocarbyl)silyl group; and n is 1 when M* is a Group 2 metal cation and n is 2 when M* is a Group 1 metal cation, a Grignard reagent cation, or a trihydrocarbylsisyl group with the proviso that reagents a) and d) are not contacted with one another in the absence of reagent c).

    Abstract translation: 含有共轭二烯配体基团的双环戊二烯基4过渡金属配合物，其中二烯与σ-复合物或π-复合物形式的过渡金属结合，可容易地通过以下任何顺序进行反应：a）第4族金属 对应于式M'X3或M'X4的盐或其路易斯碱加合物，b）共轭二烯，D'，c）还原剂，和d）下式化合物：CpM *或（Cp -Cp）M * n，其中M'为钛，锆或铪为+3形式氧化态; M“是+4形式氧化态的钛，锆或铪; X是卤素，C 1-6烃氧基或二（C 1-6烃基）酰氨基; D'是具有与D相同数目的碳和与D相同的取代模式的不饱和二烯烃; M *是1或2族金属阳离子，格氏试剂阳离子或三（C 1-4烃基）甲硅烷基; 当M *为第2族金属阳离子时，n为1，当M *为第1族金属阳离子时，n为2，格利雅试剂阳离子或三烃基硅烷基，条件是试剂a）和d）不与 在没有试剂c）的情况下。

    ETHYLENE HOMOPOLYMERIZATION USING GROUP 3 METAL COMPLEXES
    6.
    发明申请
    ETHYLENE HOMOPOLYMERIZATION USING GROUP 3 METAL COMPLEXES 审中-公开
    乙烯共聚合使用组3金属络合物

    公开(公告)号：WO1996016095A1

    公开(公告)日：1996-05-30

    申请号：PCT/US1995008840

    申请日：1995-07-14

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  PATTON, Jasson, T. ,  NEITHAMER, David, R.

    IPC: C08F110/02

    CPC classification number: C08F110/02 ,  C08F4/54

    Abstract: Ethylene is homopolymerized in the presence of a catalyst consisting essentially of a Group 3 metal complex, preferably a scandium complex, having a bridged ligand structure. Optionally polymer blends are prepared by combining the process with another polymerization process, either in series or in parallel.

    Abstract translation: 乙烯在基本上由具有桥连配体结构的第3族金属络合物，优选钪络合物组成的催化剂存在下均聚。 任选地，聚合物共混物通过将该方法与另一种串联或并联的聚合方法组合来制备。

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