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    BISCYCLOPENTADIENYL DIENE COMPLEXES
    2.
    发明申请
    BISCYCLOPENTADIENYL DIENE COMPLEXES 审中-公开
    双辛基二烯基二苯醚复合物

    公开(公告)号：WO1996004290A1

    公开(公告)日：1996-02-15

    申请号：PCT/US1995008813

    申请日：1995-07-14

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  TIMMERS, Francis, J. ,  DEVORE, David, D. ,  STEVENS, James, C. ,  ROSEN, Robert, K. ,  PATTON, Jasson, T. ,  NEITHAMER, David, R.

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  Y10S526/901 ,  Y10S526/943

    Abstract: Biscyclopentadienyl, Group 4 transition metal complexes are formed by contacting a biscyclopentadienyl Group 4 metal halide, hydrocarbyl, hydrocarbyloxy or amide complex with a conjugated diene. Uniquely, the ansa-rac diastereomer is selectively isolated and may be reconverted to the halide form if desired. When combined with standard activating cocatalysts or activated with an activating technique, the complexes form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

    Abstract translation: 通过使双环戊二烯基第4族金属卤化物，烃基，烃氧基或酰胺络合物与共轭二烯接触来形成双环戊二烯基，第4族过渡金属络合物。 独特的是，所述外消旋非对映异构体是选择性分离的，并且如果需要可以再转化为卤化物形式。 当与标准活化助催化剂结合或用活化技术活化时，络合物形成用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。

    METALLOCENE COCATALYST
    5.
    发明申请
    METALLOCENE COCATALYST 审中-公开

    公开(公告)号：WO1997036937A1

    公开(公告)日：1997-10-09

    申请号：PCT/US1997004247

    申请日：1997-03-20

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  TIMMERS, Francis, J. ,  NEITHAMER, David, R.

    IPC: C08F04/603

    CPC classification number: C08F10/00 ,  C08F4/61908 ,  C08F4/61916 ,  C08F4/6192 ,  C08F4/65908

    Abstract: Boratabenzene cocatalysts, especially novel pentafluorophenyl boratabenzenes, are useful cocatalysts or activators with metallocenes. They are less expensive than prior art activators, are soluble and offer more irreversible reactions. Compositions comprise at least one metallocene catalyst and at least one dihydroboratabenzene or anion thereof. Processes include polymerizations with metallocenes in the presence of boratabenzene cocatalyst and activation process including bulk electrolysis techniques.

    Abstract translation: 硼化物助催化剂，特别是新的五氟苯基硼苯偶氮，是具有金属茂的有用的助催化剂或活化剂。 它们比现有技术的活化剂便宜，是可溶的并且提供更多的不可逆反应。 组合物包含至少一种金属茂催化剂和至少一种二氢硼烷基或其阴离子。 方法包括在硼烷助催化剂存在下与茂金属的聚合，以及包括大量电解技术的活化方法。

    PREPARATION OF BISCYCLOPENTADIENYL DIENE COMPLEXES
    6.
    发明申请
    PREPARATION OF BISCYCLOPENTADIENYL DIENE COMPLEXES 审中-公开
    双联二苯基二烯配合物的制备

    公开(公告)号：WO1997025336A1

    公开(公告)日：1997-07-17

    申请号：PCT/US1996019281

    申请日：1996-12-05

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  TIMMERS, Francis, J. ,  DEVORE, David, D. ,  NEITHAMER, David, R.

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  Y10S526/943

    Abstract: Bicyclopentadienyl Group 4 transition metal complexes containing a conjugated diene ligand group wherein the diene is bound to the transition metal either in the form of a sigma -complex or a pi -complex are readily prepared by reacting in any order: a) a Group 4 metal salt corresponding to the formula M'X3 or M''X4, or a Lewis base adduct thereof, b) a conjugated diene, D', c) a reducing agent, and d) a compound of the formula: CpM* or (Cp-Cp)M*n, wherein M' is titanium, zirconium or hafnium in the +3 formal oxidation state; M'' is titanium, zirconium or hafnium in the +4 formal oxidation state; X is a halide, C1-6 hydrocarbyloxy or di(C1-6 hydrocarbyl)amido group; D' is an uncoordinated diene having the same number of carbons as D and the same substitution pattern as D; M* is a Group 1 or 2 metal cation, a Grignard reagent cation or a tri(C1-4 hydrocarbyl)silyl group; and n is 1 when M* is a Group 2 metal cation and n is 2 when M* is a Group 1 metal cation, a Grignard reagent cation, or a trihydrocarbylsisyl group with the proviso that reagents a) and d) are not contacted with one another in the absence of reagent c).

    Abstract translation: 含有共轭二烯配体基团的双环戊二烯基4过渡金属配合物，其中二烯与σ-复合物或π-复合物形式的过渡金属结合，可容易地通过以下任何顺序进行反应：a）第4族金属 对应于式M'X3或M'X4的盐或其路易斯碱加合物，b）共轭二烯，D'，c）还原剂，和d）下式化合物：CpM *或（Cp -Cp）M * n，其中M'为钛，锆或铪为+3形式氧化态; M“是+4形式氧化态的钛，锆或铪; X是卤素，C 1-6烃氧基或二（C 1-6烃基）酰氨基; D'是具有与D相同数目的碳和与D相同的取代模式的不饱和二烯烃; M *是1或2族金属阳离子，格氏试剂阳离子或三（C 1-4烃基）甲硅烷基; 当M *为第2族金属阳离子时，n为1，当M *为第1族金属阳离子时，n为2，格利雅试剂阳离子或三烃基硅烷基，条件是试剂a）和d）不与 在没有试剂c）的情况下。

    THERMOSET ELASTOMERS
    7.
    发明申请
    THERMOSET ELASTOMERS 审中-公开
    热敏弹性体

    公开(公告)号：WO1996007681A1

    公开(公告)日：1996-03-14

    申请号：PCT/US1995009945

    申请日：1995-08-04

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  MCKAY, Kevin, W. ,  TIMMERS, Francis, J. ,  FEIG, Edward, R.

    IPC: C08F212/00

    CPC classification number: C08L25/08 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/18 ,  C08F212/00 ,  C08F212/08 ,  C08L23/08 ,  C08L23/0838 ,  C08L23/16 ,  C08L25/00 ,  C08L53/02 ,  C08L53/025 ,  C08F4/6592 ,  C08L2666/04 ,  C08F236/06 ,  C08F2500/12 ,  C08F2500/21 ,  C08F2500/03 ,  C08F210/06

    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one alpha -olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials.

    Abstract translation: 本发明提供了一种热固性弹性体，其包含交联的伪随机或基本上无规的互聚物：（a）15至70重量％的至少一种α-烯烃，（b）30至70重量％的至少一种亚乙烯基芳族化合物 ，和（c）0至15重量％的至少一种二烯。 本发明进一步提供了一种包含热塑性聚烯烃基质中提供的本发明的热固性弹性体的热塑性硫化橡胶。 本发明还提供了制备本发明的热固性弹性体和热塑性硫化橡胶以及由其制造的部件的方法。 与EPM和EPDM基材料相比，本发明的材料具有优异的性能平衡。

    GROUP 4 METAL DIENE COMPLEXES AND ADDITION POLYMERIZATION CATALYSTS THEREFROM
    9.
    发明申请
    GROUP 4 METAL DIENE COMPLEXES AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 审中-公开
    第4组金属二烯配合物及其加成聚合催化剂

    公开(公告)号：WO1996000734A1

    公开(公告)日：1996-01-11

    申请号：PCT/US1995007776

    申请日：1995-06-19

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  TIMMERS, Francis, J. ,  STEVENS, James, C. ,  ROSEN, Robert, K.

    IPC: C07F17/00

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  Y10S526/943

    Abstract: Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, pi -bonded group wherein the metal is in the + 4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

    Abstract translation: 含有一个且仅一个环离域，阴离子，π键合基团的新型4族金属络合物，其中金属处于+ 4正式氧化态并具有桥连配体结构，也称为约束几何配合物和共轭二烯二价阴离子 配体基团 这种络合物的催化衍生物，包括新型的三嗪配合物; 以及其作为用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂的用途。

    COMPATIBILIZED BLEND OF OLEFINIC POLYMERS AND MONOVINYLIDENE AROMATIC POLYMERS
    10.
    发明申请
    COMPATIBILIZED BLEND OF OLEFINIC POLYMERS AND MONOVINYLIDENE AROMATIC POLYMERS 审中-公开
    烯烃聚合物和单烯烃芳族聚合物的混合混合物

    公开(公告)号：WO1995027755A1

    公开(公告)日：1995-10-19

    申请号：PCT/US1995004314

    申请日：1995-04-12

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  PARK, Chung, P. ,  CLINGERMAN, George, P. ,  TIMMERS, Francis, J. ,  STEVENS, James, C. ,  HENTON, David, E.

    IPC: C08L25/08

    CPC classification number: C08L23/06 ,  C08L23/00 ,  C08L23/04 ,  C08L25/02 ,  C08L25/06 ,  C08L2205/02 ,  C08L2666/04

    Abstract: A polymer blend composition comprising: (a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic alpha -olefin homopolymer or interpolymer, or an interpolymer of an alpha -olefin and a non-aromatic monomer interpolymerizable therewith; (b) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a homopolymer or interpolymer of monovinylidene aromatic monomers, or an interpolymer of monovinylidene aromatic monomer and a monomer interpolymerizable therewith other than an aliphatic alpha -olefin; and (c) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a substantially random interpolymer comprising an alpha -olefin and a vinylidene aromatic monomer. An expandable composition, comprising such polymer blend composition and an expanding agent; a foamed composition obtained by subjecting such an expandable composition to a foaming process; an article of manufacture molded from such a polymer blend composition; and a method of packaging using such a polymer blend composition.

    Abstract translation: 一种聚合物共混物组合物，其包含：（a）基于（a），（b）和（c）的脂肪族α-烯烃均聚物或互聚物的总重量的0.5〜99重量％ 可与其共聚的α-烯烃和非芳族单体; （b）基于单亚乙烯基芳族单体的均聚物或互聚物或单亚乙烯基芳族单体和单体的互聚物（a），（b）和（c））的总重量为0.5-99重量％ 除脂肪族α-烯烃以外可与其进行聚合; 和（c）基于包含α-烯烃和亚乙烯基芳族单体的基本上无规共聚体的（a），（b）和（c））的总重量的0.5至99重量％。 包含这种聚合物共混物组合物和膨胀剂的可发性组合物; 通过将这样的可发性组合物进行发泡处理获得的发泡组合物; 由这种聚合物共混组合物模制的制品; 以及使用这种聚合物共混组合物的包装方法。

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