公开(公告)号：WO1996006819A1

公开(公告)日：1996-03-07

申请号：PCT/US1995009648

申请日：1995-07-31

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  WEHMEYER, Richard, M. ,  WALTERS, Marlin, E. ,  TASSET, Emmett, L. ,  BREWSTER, Steven, L.

IPC: C07C37/20

CPC classification number: B01J31/4007 ,  B01J31/0217 ,  B01J31/10 ,  B01J2231/347 ,  C07C37/20 ,  C07C2603/18 ,  Y02P20/584 ,  C07C39/17 ,  C07C39/16

Abstract: A catalyst useful for the condensation of an aldehyde or ketone starting material with a phenol is an insoluble mercaptosulfonic acid compound. The heterogeneous catalysts comprise catalytically-active species represented by formula (a). L is an optional linking group and is a bond, which catalytically active species is attached by the bond to an insoluble organic or inorganic support; or a catalytically-active species represented by formula (b), wherein L' is an optional linking group, is a bond and theta ' and theta '' are residues of theta , and a and b are independently selected from integers equal to or greater than 1.

Abstract translation: 用于醛或酮原料与苯酚缩合的催化剂是不溶性巯基磺酸化合物。 非均相催化剂包含由式（a）表示的催化活性物质。 L是任选的连接基团，并且是键，其中催化活性物质通过键连接到不溶性有机或无机载体上; 或由式（b）表示的催化活性物质，其中L'是任选的连接基团，是键，θ'和θ“是θ的残基，a和b独立地选自等于或大于 比1。