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    PROCESS FOR MAKING POLYPHENOLS FROM KETONES OR ALDEHYDES AND PHENOLS
    2.
    发明申请
    PROCESS FOR MAKING POLYPHENOLS FROM KETONES OR ALDEHYDES AND PHENOLS 审中-公开
    从酮，醛和酚生产多酚的方法

    公开(公告)号：WO1996006819A1

    公开(公告)日：1996-03-07

    申请号：PCT/US1995009648

    申请日：1995-07-31

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  WEHMEYER, Richard, M. ,  WALTERS, Marlin, E. ,  TASSET, Emmett, L. ,  BREWSTER, Steven, L.

    IPC: C07C37/20

    CPC classification number: B01J31/4007 ,  B01J31/0217 ,  B01J31/10 ,  B01J2231/347 ,  C07C37/20 ,  C07C2603/18 ,  Y02P20/584 ,  C07C39/17 ,  C07C39/16

    Abstract: A catalyst useful for the condensation of an aldehyde or ketone starting material with a phenol is an insoluble mercaptosulfonic acid compound. The heterogeneous catalysts comprise catalytically-active species represented by formula (a). L is an optional linking group and is a bond, which catalytically active species is attached by the bond to an insoluble organic or inorganic support; or a catalytically-active species represented by formula (b), wherein L' is an optional linking group, is a bond and theta ' and theta '' are residues of theta , and a and b are independently selected from integers equal to or greater than 1.

    Abstract translation: 用于醛或酮原料与苯酚缩合的催化剂是不溶性巯基磺酸化合物。 非均相催化剂包含由式（a）表示的催化活性物质。 L是任选的连接基团，并且是键，其中催化活性物质通过键连接到不溶性有机或无机载体上; 或由式（b）表示的催化活性物质，其中L'是任选的连接基团，是键，θ'和θ“是θ的残基，a和b独立地选自等于或大于 比1。

    INITIATION METHOD OF A METHOD FOR PRODUCING 2,2-BIS(4-HYDROXYPHENYL)PROPANE
    4.
    发明申请
    INITIATION METHOD OF A METHOD FOR PRODUCING 2,2-BIS(4-HYDROXYPHENYL)PROPANE 审中-公开
    2,2-双（4-羟基苯基）丙烷制造工艺的操作的方法

    公开(公告)号：WO01040155A1

    公开(公告)日：2001-06-07

    申请号：PCT/EP2000/011465

    申请日：2000-11-17

    IPC: B01J31/10 ,  C07C37/20 ,  C07C39/16 ,  B01J31/40

    CPC classification number: C07C37/20 ,  B01J31/10 ,  B01J2231/347 ,  Y02P20/52 ,  C07C39/16

    Abstract: The invention relates to the initiation of a method for producing bisphenols by reacting phenol with acetone in the presence of sulfonated cross-linked polystyrene resins. The invention is characterized in that: a) the initiation is carried out with an acetone concentration, which is reduced compared to the optimal continuous operation state, and with a phenol concentration, which is increased compared to the optimal continuous operation state, under a reduced throughput, and; b) under temperature control, the educt quantity and the acetone content of the reactor inflow are subsequently increased in stages or continuously until the continuous operation state is attained.

    Abstract translation: 本申请涉及的处理的调试用于通过在slufonierten交联聚苯乙烯树脂的存在，其特征在于a）所述调试用gegnüber最佳稳态减小丙酮浓度和降低的定量可以通过下增加苯酚浓度的苯酚与丙酮反应制备双酚，和b） 温度控制随后起始材料的量和Reaktozulaufs的丙酮含量增加阶段性地或者连续直到Dauerbetiebszustand实现。

    PROCESS FOR PRODUCING BISPHENOL A
    5.
    发明申请
    PROCESS FOR PRODUCING BISPHENOL A 审中-公开
    生产双酚A的方法

    公开(公告)号：WO99048854A1

    公开(公告)日：1999-09-30

    申请号：PCT/JP1999/001417

    申请日：1999-03-19

    IPC: B01J31/08 ,  C07C37/20 ,  C07C39/16

    CPC classification number: C07C37/20 ,  B01J31/08 ,  B01J2231/347 ,  C07C39/16

    Abstract: A process for producing bisphenol A which comprises reacting excess phenol and acetone with an acid ion-exchange resin catalyst to yield bisphenol A, sending it to a crystallization/separation step where the bisphenol A is precipitated as crystals of an adduct thereof with phenol, isolating the crystals, and removing the phenol to recover purified bisphenol A, wherein at least part of the phenol to be reacted with acetone is the phenol which has been obtained from the crystallization/separation step and has undergone adsorption with an adsorbent which is a cross-linked gel-form resin in which the molar ratio of units derived from a cross-linking agent to units derived from a monovinylaromatic compound is from 0.01 to 0.8. The adsorption is advantageously conducted by passing the phenol through a fixed-bed adsorbent layer packed with the adsorbent having an average diameter of 0.05 to 2 mm at a temperature of 50 to 80 DEG C and a linear velocity of 0.5 to 30 m/hr. Thus, compounds causative of catalyst deterioration are adsorptively removed. Since the catalytic activity can hence be prevented from deteriorating, the catalyst has a prolonged life.

    Abstract translation: 一种生产双酚A的方法，其包括用酸离子交换树脂催化剂使过量的苯酚和丙酮反应以产生双酚A，将其送入结晶/分离步骤，其中双酚A作为其与苯酚的加合物的结晶沉淀，分离 晶体，除去苯酚以回收纯化的双酚A，其中与丙酮反应的至少部分苯酚是从结晶/分离步骤获得的苯酚，并且用作为交联剂的吸附剂进行吸附， 其中衍生自交联剂的单元的摩尔比与衍生自单乙烯基芳族化合物的单元的摩尔比为0.01至0.8。 通过使苯酚通过在50〜80℃的温度和0.5〜30m / hr的线速度下使平均直径为0.05〜2mm的吸附剂填充的固定床吸附剂层进行吸附。 因此，吸附除去导致催化剂劣化的化合物。 由于催化活性因此可以防止恶化，所以催化剂寿命延长。

    AN ION-EXCHANGE RESIN CATALYST AND A METHOD OF MAKING AND FOR USING THE SAME IN THE PREPARATION OF A BISPHENOL
    7.
    发明申请
    AN ION-EXCHANGE RESIN CATALYST AND A METHOD OF MAKING AND FOR USING THE SAME IN THE PREPARATION OF A BISPHENOL 审中-公开
    离子交换树脂催化剂及其制备方法和用于制备双酚的方法

    公开(公告)号：WO2017013605A1

    公开(公告)日：2017-01-26

    申请号：PCT/IB2016/054325

    申请日：2016-07-20

    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

    Inventor： NAIR, Vinod S. ,  DHAR, Dwairath ,  GURRAM, Kishan

    IPC: B01J31/10

    CPC classification number: B01J31/10 ,  B01J2231/347

    Abstract: In an embodiment, a catalyst comprises a sulfonated polymerization product of a monovinylaromatic monomer and less than 2.0 wt% of a polyvinyl aromatic monomer, based on the total amount of monomer, and wherein the catalyst comprises 0.1 to 1.0 millimole of sulfone bridges per gram of dry catalyst. In another embodiment, a method of producing a bisphenol comprises reacting a phenolic compound with one or both of an aldehyde and a ketone in the presence of a catalyst to produce a bisphenol; wherein the catalyst is a sulfonated polymerization product of a monovinylaromatic monomer and less than 2.0 wt% of a polyvinyl aromatic monomer, based on the total amount of monomer, and wherein the catalyst comprises 0.1 to 1.0 millimole of sulfone bridges per gram of dry catalyst.

    Abstract translation: 在一个实施方案中，催化剂包含基于单体总量的单乙烯基芳族单体和小于2.0重量％的聚乙烯基芳族单体的磺化聚合产物，并且其中所述催化剂包含0.1至1.0毫摩尔的砜桥/克 干催化剂。 在另一个实施方案中，制备双酚的方法包括在催化剂存在下使酚类化合物与醛和酮之一或两者反应以产生双酚; 其中所述催化剂是基于单体总量的单乙烯基芳族单体和小于2.0重量％的聚乙烯基芳族单体的磺化聚合产物，并且其中所述催化剂包含每克干催化剂0.1至1.0毫摩尔的砜桥。

    ビスフェノールＡの製造方法
    8.
    发明申请
    ビスフェノールＡの製造方法 审中-公开
    生产双酚A的方法

    公开(公告)号：WO2005026237A1

    公开(公告)日：2005-03-24

    申请号：PCT/JP2004/012634

    申请日：2004-09-01

    Applicant: 三井化学株式会社 ,  寺嶋 隆 ,  丸山 裕子 ,  高井 敏浩 ,  藤原 謙二

    Inventor： 寺嶋 隆 ,  丸山 裕子 ,  高井 敏浩 ,  藤原 謙二

    IPC: C08G85/00

    CPC classification number: C07C39/16 ,  B01J31/10 ,  B01J2231/347 ,  C07C37/20 ,  C08F8/32 ,  C08F8/36 ,  C08F12/08 ,  C08F212/08

    Abstract: 本発明は、フェノールとアセトンを反応させてビスフェノールＡを製造する方法において、高い選択性を維持しながらより高い温度で反応を行い、その結果高い生産性をもたらすビスフェノールＡの製造方法を提供することを目的とする。 本発明は、シンジオタクティックポリスチレン系重合体にカチオン交換基を導入してなり、かつその酸量が０．８ミリ当量／ｇ以上であることを特徴とするカチオン交換樹脂、カチオン交換樹脂からなる触媒、及びカチオン交換樹脂触媒を用いるビスフェノールＡの製造方法に関するものである。

    Abstract translation: 一种生产双酚A的方法，其包括使苯酚与丙酮反应。 反应在更高温度下进行，同时保持高选择性，从而获得高生产率。 还提供了：阳离子交换树脂，其特征在于包含间同立构聚苯乙烯聚合物和掺入其中的阳离子交换基团，并且具有0.8meq / g以上的酸量; 和包含阳离子交换树脂的催化剂。 双酚A生产方法采用阳离子交换树脂催化剂。

    PROCESS FOR PRODUCING BISPHENOL A
    9.
    发明申请
    PROCESS FOR PRODUCING BISPHENOL A 审中-公开
    生产双酚A的方法

    公开(公告)号：WO01049640A1

    公开(公告)日：2001-07-12

    申请号：PCT/JP2000/009405

    申请日：2000-12-28

    IPC: B01J31/08 ,  C07C37/20 ,  C07C39/16 ,  C07B61/00

    CPC classification number: C07C37/20 ,  B01J31/08 ,  B01J2231/347 ,  C07C39/16

    Abstract: A process for producing bisphenol A whereby the life of an acid type ion exchange resin, which has been partly modified with a sulfur-containing amine compound, employed as a catalyst can be prolonged and a high bisphenol productivity per catalytic unit can be achieved. A process for producing bisphenol A by reacting acetone and phenol with the use of an acid type ion exchange resin, which has been partly modified with a sulfur-containing amine compound, as a catalyst and an alkyl mercaptan as a promoter, characterized in that use is made of a multi-step reactor provided with at least two reactors connected in series and the molar ratio of total alkyl mercaptan/total acetone and the molar ratio of total acetone/phenol are increased with a decrease in the conversion ratio of phenol.

    Abstract translation: 可以延长生产双酚A的方法，由此可以延长已经用含硫胺化合物部分改性的酸型离子交换树脂的使用寿命，并且可以实现每个催化单元的高双酚生产率。 通过使丙酮和苯酚与使用含硫胺化合物部分改性的酸型离子交换树脂作为催化剂和烷基硫醇作为助催化剂生产双酚A的方法，其特征在于使用 由具有串联连接的至少两个反应器的多步反应器制成，并且总烷基硫醇/总丙酮的摩尔比和总丙酮/苯酚的摩尔比随苯酚转化率的降低而增加。

    CATIONIC EXCHANGE RESIN
    10.
    发明申请
    CATIONIC EXCHANGE RESIN 审中-公开
    阳离子交换树脂

    公开(公告)号：WO00058009A1

    公开(公告)日：2000-10-05

    申请号：PCT/JP2000/001893

    申请日：2000-03-28

    IPC: B01J31/10 ,  B01J39/20 ,  C07C37/20 ,  B01J31/08

    CPC classification number: C07C37/20 ,  B01J31/10 ,  B01J39/20 ,  B01J2231/347 ,  C07C39/16

    Abstract: A cationic exchange resin which is obtained by sulfonating a copolymer resin from a monovinyl monomer, which is mainly a styrenic monomer, and a divinyl monomer, characterized in that at least a part of the divinyl monomer is a polycyclic aromatic divinyl monomer, and it has a crosslinking degree represented by polycyclic aromatic divinyl monomer/total monomer of 1 mole % or more and has an exchange volume of 0.7 meq/ml-wet resin or more, and the ion exchange resin particles have an average crushing strength (Chatillon value) of 200 g or more/particle at a particle diameter of 600 mu m. The polycyclic aromatic divinyl monomer is preferably diphenyl biphenyl. The cationic exchange resin has high strength and is excellent in activity, and is useful as a catalyst for producing bisphenol A from phenol and acetone.

    Abstract translation: 由主要是苯乙烯类单体的单乙烯基单体和二乙烯基单体磺化共聚物树脂得到的阳离子交换树脂，其特征在于，所述二乙烯基单体的至少一部分为多环芳香族二乙烯基单体， 由多环芳族二乙烯基单体/总单体表示的交联度为1摩尔％以上，交换容积为0.7meq / ml-湿树脂或更多，离子交换树脂颗粒的平均抗碎强度（Chatillon值）为 200g以上/粒径为600μm的粒子。 多环芳族二乙烯基单体优选为二苯基联苯。 阳离子交换树脂具有高强度，活性优异，可用作由苯酚和丙酮生产双酚A的催化剂。

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