公开(公告)号：WO2014158802A1

公开(公告)日：2014-10-02

申请号：PCT/US2014/020234

申请日：2014-03-04

申请人： TRANSITIONS OPTICAL, INC.

发明人： PARK, David ,  KUMAR, Anil

IPC分类号： B29D11/00

CPC分类号： B29D11/00644 ,  B29C47/0021 ,  B29C47/8845 ,  B29D11/00653

摘要： The present invention relates to a method of preparing a photochromic-dichroic film that includes a photochromic-dichroic layer. The method includes forming a molten thermoplastic photochromic-dichroic composition that includes a thermoplastic polymer and a photochromic-dichroic compound. Optionally at least one further molten thermoplastic composition is formed, each of which independently includes a further thermoplastic polymer. A molten stream is formed that includes a first molten layer (29) composed of the molten thermoplastic photochromic-dichroic composition, and at least one further molten layer (26, 32), each of which is independently composed of a further molten thermoplastic composition. The molten stream is passed between a rotating roll (11) and a continuous belt (14) that move in the same relative direction. A photochromic-dichroic film having reduced/minimal optical distortion is obtained (e.g., continuously) from between the rotating roll and the continuous belt.

摘要翻译： 本发明涉及一种制备包含光致变色二色性层的光致变色二色膜的方法。 该方法包括形成包含热塑性聚合物和光致变色二色性化合物的熔融热塑性光致变色二色性组合物。 任选地，形成至少一种另外的熔融热塑性组合物，其各自独立地包括另外的热塑性聚合物。 形成熔融流，其包括由熔融热塑性光致变色二色性组合物构成的第一熔融层（29）和至少一个另外的熔融层（26,32），每个熔融层独立地由另外的熔融热塑性组合物组成。 熔融物流在旋转辊（11）和在相同相对方向上移动的连续带（14）之间通过。 从旋转辊和连续带之间获得具有减小/最小光学变形的光致变色二色膜（例如，连续地）。

公开(公告)号：WO2013022610A1

公开(公告)日：2013-02-14

申请号：PCT/US2012/048320

申请日：2012-07-26

申请人： TRANSITIONS OPTICAL, INC.

发明人： DAI, Xiao-Man ,  XU, Ruisong ,  HE, Meng ,  KUMAR, Anil ,  YOEST, Rachael L. ,  LI, Chenguang

IPC分类号： C09K19/20 ,  C09K19/34 ,  C09K19/54

CPC分类号： C07D309/12 ,  C09K19/0403 ,  C09K19/2007 ,  C09K19/2014 ,  C09K19/3402 ,  C09K19/54 ,  C09K2019/0407 ,  C09K2019/0448 ,  C09K2019/3422

摘要： The present invention relates to compounds represented by the following Formula In Formula I, R 1 and R 2 are each independently selected from hydrogen, and optionally substituted hydrocarbyl, provided that at least one of R 1 and R 2 is selected from optionally substituted hydrocarbyl (e.g., tertiary butyl); n is 0, 1 or 2, and each R 3 is independently selected from optionally substituted hydrocarbyl; L 1 is a divalent linking group, such as a bond or C(O)O; each L 2 independently represents a flexible segment, such as divalent linear or branched C 1 -C 25 alkyl; each L3 independently represents a rigid segment including, for example, optionally substituted phenylen-1,4-diyl groups; t is from 1 to 4; m and p are each independently from 0 to 4 for each t, provided that the sum of m and p is at least 1 for each t; and E can be, for example, C 5 -C 18 aryl. The invention also relates to compositions and articles that include the compound.

摘要翻译： 本发明涉及由下式表示的化合物在式I中，R 1和R 2各自独立地选自氢和任选取代的烃基，条件是R 1和R 2中的至少一个选自任选取代的烃基（例如叔丁基 ）; n是0,1或2，并且每个R 3独立地选自任选取代的烃基; L 1是二价连接基团，例如键或C（O）O; 每个L2独立地表示柔性链段，例如二价直链或支链C 1 -C 25烷基; 每个L3独立地表示包括例如任选取代的亚苯基-1,4-二基的刚性链段; t为1〜4; 对于每个t，m和p各自独立地为0至4，条件是对于每个t，m和p之和至少为1; 和E可以是例如C 5 -C 18芳基。 本发明还涉及包含该化合物的组合物和制品。

公开(公告)号：WO2013022607A1

公开(公告)日：2013-02-14

申请号：PCT/US2012/048283

申请日：2012-07-26

申请人： TRANSITIONS OPTICAL, INC.

发明人： DAI, Xiao-Man ,  XU, Ruisong ,  HE, Meng ,  KUMAR, Anil ,  YOEST, Rachael L. ,  LI, Chenguang

IPC分类号： C09K19/34 ,  C09K19/54

CPC分类号： C09K19/54 ,  C07D211/46 ,  C09K19/3483 ,  C09K19/60

摘要： The present invention relates to compounds represented by the following Formula Ia (formula Ia), in which each R 1 -R 6 can in each case be independently selected from hydrogen or hydrocarbyl (e.g., methyl); R 7 is a multivalent linking group, such as — O -C(O) -CH-C(O) -O- I; L 1 is a divalent linking group, such as a bond or divalent optionally substituted hydrocarbyl; each L 2 independently represents a flexible segment, such as divalent linear or branched C 1 -C 25 alkyl; each L 3 independently represents a rigid segment including, for example, optionally substituted phenylen-1,4-diyl groups; t is from 1 to 4; m and p are each independently from 0 to 4 for each t, provided that the sum of m and p is at least 1 for each t; and E can be hydrogen or optionally substituted hydrocarbyl. The invention also relates to compositions and articles that include the compound represented by Formula Ia.

摘要翻译： 本发明涉及由下式Ia（式Ia）表示的化合物，其中每个R 1 -R 6可各自独立地选自氢或烃基（例如甲基）; R7是多价连接基团，例如-O-C（O）-CH-C（O）-O- I; L1是二价连接基团，例如键或二价任选取代的烃基; 每个L2独立地表示柔性链段，例如二价直链或支链C 1 -C 25烷基; 每个L3独立地表示包括例如任选取代的亚苯基-1,4-二基的刚性链段; t为1〜4; 对于每个t，m和p各自独立地为0至4，条件是对于每个t，m和p之和至少为1; 并且E可以是氢或任选取代的烃基。 本发明还涉及包含由式Ia表示的化合物的组合物和制品。

公开(公告)号：WO2011071794A1

公开(公告)日：2011-06-16

申请号：PCT/US2010/059035

申请日：2010-12-06

申请人： TRANSITIONS OPTICAL, INC.

发明人： SAHA, Gobinda ,  KUMAR, Anil

IPC分类号： C08F220/30 ,  C08F220/62 ,  C08G65/331 ,  C09K9/02 ,  G02B1/04

CPC分类号： C08F222/20 ,  C08F220/30 ,  C08F220/62 ,  C08F2220/301 ,  C08F2220/303 ,  C08F2220/305 ,  C08F2220/365 ,  C09K19/56 ,  G02B1/04 ,  G02F1/1337 ,  G02F1/133788 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31931 ,  C08L33/10 ,  C08L101/12 ,  C08F220/34 ,  C08F2220/343 ,  C08F230/08 ,  C08F2220/281

摘要： The present disclosure provides for new photoalignment (co)polymer materials which demonstrate improved adhesion to a substrate. The (co)polymeric structure includes at least one photochemically active chromophore and at least one adhesion promoter group. Articles of manufacture, optical elements, ophthalmic elements and liquid crystal cells which include at least one photoalignment layer made from the photoalignment (co)polymer materials and methods for formation are also disclosed.

摘要翻译： 本公开提供了新的光取向（共）聚合物材料，其表现出对基材的改善的粘合性。 （共）聚合物结构包括至少一种光化学活性发色团和至少一个粘合促进剂基团。 还公开了包括由光取向（共）聚合物材料和形成方法制成的至少一个光取向层的制造物，光学元件，眼用元件和液晶单元。

公开(公告)号：WO2007038662A3

公开(公告)日：2007-04-05

申请号：PCT/US2006/037799

申请日：2006-09-27

申请人： TRANSITIONS OPTICAL, INC.

发明人： FOLLER, Peter C. ,  KUMAR, Anil

IPC分类号： G02C7/02

摘要： Provided is a method for making a customized lens including applying a customizable material onto a surface of an ophthalmic substrate; and writing index-change information to the material to form a variable-index layer on the substrate surface. Also provided is a customized ophthalmic element including an ophthalmic substrate; and a variable-index layer of a liquid crystal material connected to at least a portion of the substrate. Further provided is an ophthalmic element having a pair of complementary substrates, each of which has a complementary surface and being positioned such that their complementary surfaces are spaced apart and facing each other, an alignment layer of a patterned alignment material connected to at least one of the complementary surfaces of the pair of substrates, and a variable-index coating interposed between the pair of substrates, such that the liquid crystal material of the variable-index coating is aligned with the patterned alignment material.

公开(公告)号：WO2005090327A1

公开(公告)日：2005-09-29

申请号：PCT/US2004/008156

申请日：2004-03-16

申请人： TRANSITIONS OPTICAL, INC.

发明人： WALTERS, Robert, W. ,  KUMAR, Anil ,  NELSON, Clara, E. ,  CHOPRA, Anu

IPC分类号： C07D311/94

CPC分类号： C07D405/04 ,  C07D491/04 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T442/259

摘要： Described are photochromic materials of indeno [2',3':3,4]naphtho[1,2-b]pyran structure, characterized in that they have a nitrogen or sulfur containing substituent at the 11-position ring atom, are substantially free of spiro-substituents at the 13-position and have been adapted to provide an increase in the sensitivity, visible lambda max or a combination thereof as measured in the Indenonaphthopyran Photochromic Performance Test. Optional substituents can be present at the other positions of the indeno [2',3':3,4]naphtho [1,2-b]pyran structure. Also described are naphthols used to produce the photochromic materials and photochromic articles that contain or that have coatings containing at least one of the novel photochromic materials or combinations thereof with other photochromic materials.

摘要翻译： 描述茚并[2'，3'：3,4]萘并[1,2-b]吡喃结构的光致变色材料，其特征在于它们在11位环原子上具有含氮或硫的取代基， 的螺取代基在13位，并且已经适于提供灵敏度，可见λmax或其组合的增加，如在茚氢萘酚光致变色性能测试中所测量的。 茚并[2'，3'：3,4]萘并[1,2-b]吡喃结构的其它位置可以存在任选的取代基。 还描述了用于生产光致变色材料和光致变色制品的萘酚，其含有或具有包含至少一种新型光致变色材料或其与其它光致变色材料的组合的涂层。

公开(公告)号：WO2017074434A1

公开(公告)日：2017-05-04

申请号：PCT/US2015/058385

申请日：2015-10-30

申请人： TRANSITIONS OPTICAL, INC.

发明人： KUMAR, Anil ,  PARK, David, John ,  SMYTH, Brian ,  JACKSON, Delwin, S. ,  NGUYEN, Henry ,  LIGAS, John, S. ,  ANDERSON, Linda, K.

IPC分类号： G02B5/23 ,  G02B5/30 ,  G02C7/10 ,  G02C7/12

CPC分类号： G02B5/3016 ,  B29D11/00644 ,  B29D11/00653 ,  B29D11/00865 ,  B29D11/00884 ,  G02B5/23 ,  G02C7/022 ,  G02C7/102 ,  G02C7/105 ,  G02C7/12

摘要： An optical article that includes an optical element and an anisotropic coating layer formed over at least a portion of the optical element. The anisotropic coating layer can include a first light-influencing zone comprising at least one first anisotropic material and a second light-influencing zone comprising at least one second anisotropic material. The at least one of the first light-influencing zone and the second light-influencing zone further include at least one dichroic material and/or at least one photochromic-dichroic material such that the first light-influencing zone and the second light-influencing zone exhibit a different color property, a different photochromic-dichroic reversible change, a different amount of polarization, or a combination thereof.

摘要翻译： 包括光学元件和在光学元件的至少一部分上形成的各向异性涂层的光学制品。 各向异性涂层可以包括包含至少一种第一各向异性材料的第一光影响区和包含至少一种第二各向异性材料的第二光影响区。 第一光影响区域和第二光影响区域中的至少一个还包括至少一种二色性材料和/或至少一种光致变色二色性材料，使得第一光影响区域和第二光影响区域 表现出不同的颜色特性，不同的光致变色 - 二向色性可逆变化，不同量的偏振或其组合。

公开(公告)号：WO2015077264A1

公开(公告)日：2015-05-28

申请号：PCT/US2014/066256

申请日：2014-11-19

申请人： TRANSITIONS OPTICAL, INC.

发明人： HE, Meng ,  TOMASULO, Massimiliano ,  KUMAR, Anil

IPC分类号： C07D491/052 ,  C07D493/04 ,  C07D311/94 ,  C09K9/02 ,  C09K19/54 ,  G02B1/04 ,  G02B5/23

CPC分类号： C07D493/04 ,  C07D311/94 ,  C07D491/052 ,  C09K9/02 ,  C09K19/32 ,  C09K19/3488 ,  C09K19/3491 ,  C09K19/36 ,  C09K19/60 ,  C09K2019/3408 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/1088 ,  G02B1/043 ,  G02B5/23

摘要： The present invention relates to photochromic indeno-fused ring pyran compounds represented by the following Formula (I-A): The present invention also relates to photochromic dichroic compounds, such as represented by Formula (I-A), in which (i) Z 2 is a group N-R 13 in which R 13 is a group L, and (ii) optionally at least one R1 independently for each n is selected from a group L, in which the group L independently in each case is a lengthening group that provides the photochromic compound with dichroic properties, in accordance with some embodiments. The present invention also relates to photochromic articles, such as photochromic ophthalmic articles, that include one or more photochromic compounds according to the present invention, such as represented by Formula (I-A).

摘要翻译： 本发明涉及由下式（IA）表示的光致变色茚并稠环吡喃化合物：本发明还涉及由式（IA）表示的光致变色二色性化合物，其中（i）Z2是基团N -R13，其中R13是基团L，和（ii）每个n独立地选自至少一个R 1，其中基团L在每种情况下独立地是提供具有二色性的光致变色化合物的延长基团 属性，根据一些实施例。 本发明还涉及包含一种或多种根据本发明的光致变色化合物的光致变色制品，例如光致变色眼用制品，如由式（I-A）表示的。

公开(公告)号：WO2014164046A1

公开(公告)日：2014-10-09

申请号：PCT/US2014/020189

申请日：2014-03-04

申请人： TRANSITIONS OPTICAL, INC.

发明人： DABIDEEN, Darrin R. ,  HE, Meng ,  KUMAR, Anil

IPC分类号： C07D493/04 ,  G03C1/73

CPC分类号： G02B1/04 ,  C07D493/04 ,  C09K9/02 ,  C09K2211/1029 ,  C09K2211/1088 ,  G03C1/73

摘要： The present invention relates to naphthopyran compounds that include at least one compound represented by the following Formulas (I), (II), and (III): With reference to Formulas (I), (II), and (III), there is the proviso that: (i) at least one R 1 is a group L; and/or (ii) B and/or B' is substituted with at least one group L. The group L can be described as a lengthening group. The present invention also relates to photochromic-dichroic naphthopyran compounds and photochromic-dichroic articles containing such compounds.

摘要翻译： 本发明涉及包含由下式（I），（II）和（III）表示的至少一种化合物的萘并吡喃化合物：参考式（I），（II）和（III） 条件是：（i）至少一个R1是基团L; 和/或（ii）B和/或B'被至少一个基团L取代。基团L可以被描述为延长基团。 本发明还涉及含有这些化合物的光致变色二色萘并吡喃化合物和光致变色二色性物品。

公开(公告)号：WO2013022605A1

公开(公告)日：2013-02-14

申请号：PCT/US2012/048249

申请日：2012-07-26

申请人： TRANSITIONS OPTICAL, INC.

发明人： XU, Ruisong ,  DAI, Xiao-Man ,  KUMAR, Anil ,  HE, Meng ,  LI, Chenguang ,  YOEST, Rachael L.

IPC分类号： C09K19/34 ,  C09K19/54

CPC分类号： C09K19/3483 ,  C07D211/48 ,  C07D401/12 ,  C09K19/54 ,  C09K19/60 ,  C09K2019/0448 ,  Y10T428/10 ,  Y10T428/1036

摘要： The present invention relates to compounds represented by the following Formula I, in which R 1 -R 6 can each independently be selected from hydrogen or hydrocarbyl (e.g., methyl); L 1 is a divalent linking group, such as a bond or -OC(O)-R 8 -C(O)O, where R8 can be divalent hydrocarbyl (e.g., -CH2CH2-); each L 2 independently represents a flexible segment, such as divalent linear or branched C 1 -C 25 alkyl; each L 3 independently represents a rigid segment including, for example, optionally substituted phenylen-1,4-diyl groups; t is from 1 to 4; m and p are each independently from 0 to 4 for each t, provided that the sum of m and p is at least 1 for each t; and E can be hydrogen or hydrocarbyl. The present invention also relates to compositions and articles that include the compound represented by Formula I.

摘要翻译： 本发明涉及由下式I表示的化合物，其中R 1 -R 6各自独立地选自氢或烃基（例如甲基）; L 1是二价连接基团，例如键或-OC（O）-R 8 -C（O）O，其中R 8可以是二价烃基（例如-CH 2 CH 2 - ）。 每个L2独立地表示柔性链段，例如二价直链或支链C 1 -C 25烷基; 每个L3独立地表示包括例如任选取代的亚苯基-1,4-二基的刚性链段; t为1〜4; 对于每个t，m和p各自独立地为0至4，条件是对于每个t，m和p之和至少为1; 并且E可以是氢或烃基。 本发明还涉及包含由式I表示的化合物的组合物和制品。