Abstract:
The present invention provides methods and materials for treating an oil and gas well by introducing a polyurethane composition into the well to plug perforations and other non-productive zones of an oil and gas well to greatly reduce or prevent the ingress of formation water during production. These methods include: (a) preparing a polyurethane composition by mixing a polyol-containing component and a polyisocyanate-containing component; and (b) introducing the polyurethane composition into the well. The polyol-containing component includes a polymeric polyol having a viscosity at 25°C of no m ore than 1000 mPa∙s and the isocyanate-containing component includes an unblocked (cyclo)aliphatic polyisocyanate polymer, optionally including allophanate groups, and having a viscosity at 25°C of no more t han 1000 mPa∙s and at least 99% solids content.
Abstract:
A method of treating a subterranean formation including combining a long chain hydrocarbon viscosifier, an ene curing agent, and a thiol crosslinking agent to form a resin compound; coating the resin compound onto at least a portion of proppant particles to create resin-coated proppant particles; and placing the coated proppant particles into the subterranean formation zone, wherein the resin compound does not substantially cure prior to placing the resin coated proppant particles into the subterranean formation zone.
Abstract:
The present disclosure relates to systems and methods for stabilizing portions of a subterranean formation, including portions of a subterranean formation having unconsolidated particulates, using a consolidating agent comprising polyamino-functionalized nanoparticles. Methods in accordance with the present disclosure include the steps of providing a treatment fluid comprising a base liquid and polyamino-functionalized nanoparticles; and introducing the treatment fluid into a portion of a subterranean formation. Treatment fluids comprising polyamino-functionalized nanoparticles include gravel packing fluids, consolidation fluids, and hydraulic fracturing fluids.
Abstract:
Consolidation compositions comprising a multipodal silane coupling agent comprising at least two silane groups and at least one amino group; a curable resin; and a resin hardening agent. The curable resin is selected from the group consisting of an epoxy resin, an aliphatic epoxy resin, a glycidylamine epoxy resin, and combinations thereof.
Abstract:
Methods and compositions for use in subterranean operations are disclosed comprising providing a treatment fluid that comprises a base fluid, a gelling agent, and a synergistic breaker composition, comprising: a controlled degradable acid generating material, and an oxidizing component; introducing the treatment fluid into a formation; allowing the synergistic breaker composition to substantially reduce the viscosity of the treatment fluid.
Abstract:
A method of treating a subterranean shale formation includes placing a first treatment fluid comprising a fracturing fluid in the formation; forming fractures; placing a second fluid including a sloughing agent or eroding agent in the formation; allowing gaps in the fracture faces to form; placing a third fluid including a formation stabilizer and an agglomerating agent into the fractures; and allowing the third fluid to absorb into the formation, thereby stabilizing the shale formation fracture faces and transforming the solid shale particulates into proppant clusters.
Abstract:
A method of treating a treatment zone of a subterranean formation penetrated by a wellbore of a well, the method including: (A) introducing into the treatment zone a first particulate, wherein: (i) the first particulate comprises a first degradable material; (ii) the first particulate comprises a first particulate size selected to bridge the pore throats of a first matrix permeability of the treatment zone; and (B) introducing into the treatment zone a second particulate, wherein: (i) the second particulate comprises a second degradable material; (ii) the second particulate comprises a second particulate having a second particulate size selected to bridge the pore throats of a second matrix permeability of the treatment zone; and (C) introducing into the treatment zone a liquid resin, wherein the liquid resin is introduced into the treatment zone.
Abstract:
The present application describes improved compositions for wellbore fluids for use in downhole (e.g. oilwell) applications. The compositions comprise a blocked isocyanate (BI) component having a tolerance improving group (such as a hydrophilic group, e.g. an amine) bonded to it, and an active hydrogen component. When the BI group is unblocked, it reacts with the active hydrogen component to form a gel which, by virtue of the tolerance improving group, is more tolerant to contaminants (such as aqueous inorganic salts or brines) than the corresponding gel forms from unmodified BI. The application also relates to methods of treating an earthen formation using such a composition.
Abstract:
Improved methods for stabilizing unconsolidated subterranean formation particulates and reducing permeability of a subterranean formation to water. Some methods describe methods of stabilizing unconsolidated subterranean formation particulates and reducing the permeability of water comprising providing a portion of a subterranean formation that comprises unconsolidated formation particulates; introducing a fluid comprising a relative permeability modifier into at least a portion of the subterranean formation so as to at least partially reduce the permeability of that portion of the subterranean formation to water; and, introducing a fluid comprising a consolidating agent into at least a portion of the subterranean formation so as to at least partially consolidate the unconsolidated formation particulates.
Abstract:
A method of increasing the recovery of hydrocarbons from a highly fractured reservoir is described using the steps of injecting into the reservoir a membrane- forming fluid to form a membrane over the surface of at least part of exposed formation, injecting into the reservoir a fluid to establish a chemical potential gradient across the membrane and letting fluid enter the formation across the membrane to increase the pressure inside the formation and to force additional hydrocarbon from the formation.