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公开(公告)号：WO2021246630A1
公开(公告)日：2021-12-09
申请号：PCT/KR2021/004117
申请日：2021-04-02
申请人： 대구대학교 산학협력단
IPC分类号： B01J23/30 , B01J21/06 , B01J37/02 , B01D53/86 , B01D53/8628 , B01J21/063 , B01J37/0207 , C20
摘要： 본 발명은 철 이온이 교환된 이산화티타늄 지지체에 담지된 오산화바나듐-삼산화텅스텐 촉매 및 이를 이용한 질소산화물 제거방법에 관한 것으로, 보다 상세하게는, 철 이온이 교환된 이산화티타늄을 오산화바나듐 및 삼산화텅스텐의 지지체로 사용하여 아산화질소의 생성 및 배출을 획기적으로 저감한 탈질촉매 및 이를 이용한 질소산화물 제거방법에 관한 것이다. 본 발명에 따른 철 이온이 교환된 이산화티타늄 지지체에 담지된 오산화바나듐-삼산화텅스텐 촉매는 이산화티타늄 지지체의 표면을 개질하여 기능화시킨 후 철 이온의 전구물질과 혼합한 후, 고상이온교환법을 이용하여 승화온도에서 철 이온을 교환시킨 철 이온-이산화티타늄 지지체로 사용하여 질소산화물 제거반응에서 우수한 질소산화물 제거성능을 보유하면서도 부산물로 생성되는 아산화질소의 생성 및 배출수준을 획기적으로 저감할 수 있는 것을 특징으로 한다.
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公开(公告)号：WO2021144241A1
公开(公告)日：2021-07-22
申请号：PCT/EP2021/050442
申请日：2021-01-12
申请人： UMICORE AG & CO. KG
IPC分类号： B01J35/04 , B01J35/00 , B01D53/92 , B01D53/94 , B01J23/40 , B01J23/44 , B01J23/46 , B01J37/02 , B01J37/08 , F01N3/10 , F01N3/28 , B01D2255/1023 , B01D2255/1025 , B01D2255/9022 , B01D2255/9035 , B01D53/9454 , B01J23/464 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/0217 , B01J37/0228 , B01J37/0236 , B01J37/0244 , B01J37/088 , F01N2330/06 , F01N2370/02 , F01N2510/06 , F01N2510/0682 , F01N2510/0684 , F01N3/035 , F01N3/101 , F01N3/105 , F01N3/2828
摘要： The present invention relates to a three-way catalyst (TWC) for treatment of exhaust gases of internal combustion engines operated with a predominantly stoichiometric air/fuel ratio, so called spark ignited engines. Catalyst comprising a carrier substrate of the length L extending between substrate ends a and b and at least three washcoat zones A, B, and C, wherein washcoat zone A comprises Rh and a supporting oxide and extends starting from substrate end (a) over a part of the length L, and washcoat zone C comprises one or more platinum group metals, and a supporting oxide, and extends starting from substrate end (b) over a part of the length L, and washcoat zone B comprises Pd and a supporting oxide, and extends between washcoat zones A and C, wherein L = La + Lb + Lc, wherein La is the length of washcoat zone A, Lb is the length of washcoat zone B and Lc is the length of washcoat zone C. The catalyst is prepared by multiple coatings comprising the steps in this order: a. applying a hydrophobic masking zone extending from substrate end (a) over the length La, b. coating the carrier substrate from substrate end (a) with a coating to establish a PGM containing washcoat zone B over the length Lb, c. removing the masking zone, d. coating the remainder of the carrier substrate to establish a PGM containing washcoat zones A over length La and a PGM containing washcoat zone C of length Lc, e. drying and/or heating the coated carrier.
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公开(公告)号：WO2022002674A1
公开(公告)日：2022-01-06
申请号：PCT/EP2021/066879
申请日：2021-06-21
发明人： BOUALLEG, Malika , JOTHIE, Laetitia
IPC分类号： B01J23/755 , B01J35/00 , B01J37/02 , B01J37/16 , C10G45/48 , B01J35/006 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0236
摘要： Procédé de préparation d'un catalyseur d'hydrogénation de composés aromatiques ou polyaromatiques comprenant les étapes suivantes : - mise en contact du support avec un additif organique comprenant de l'oxygène et/ou de l'azote; - mise en contact du support avec un sel métallique de nickel, à une température inférieure à la température de fusion dudit sel métallique de nickel, pour former un mélange solide; - chauffage sous agitation du mélange solide à une température comprise entre la température de fusion dudit sel métallique et 200°C; - mise en contact du support avec une solution contenant au moins un précurseur de cuivre et un précurseur de nickel à une concentration en cuivre voulue pour obtenir sur le catalyseur final une teneur comprise entre 0,5 et 15 % poids en élément cuivre par rapport au poids total du catalyseur final.
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公开(公告)号：WO2021226277A1
公开(公告)日：2021-11-11
申请号：PCT/US2021/030951
申请日：2021-05-05
申请人： CHEVRON U.S.A. INC.
IPC分类号： B01J29/48 , B01J29/90 , B01J38/02 , B01J23/888 , B01J35/026 , B01J37/0009 , B01J37/0207
摘要： The present process comprises hydrocracking a hydrocarbon feed in a first stage. The catalyst in the first stage is a conventional hydrocracking catalyst. The product from the first stage can then be transferred to a second hydrocracking stage. The catalyst used in the second stage of the present hydrocracking process comprises a base impregnated with metals from Group 6 and Groups 8 through 10 of the Periodic Table. The base of the catalyst used in the present second hydrocracking stage comprises alumina, an amorphous silica-alumina (ASA) material, a USY zeolite and zeolite ZSM-12.
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公开(公告)号：WO2021252452A1
公开(公告)日：2021-12-16
申请号：PCT/US2021/036344
申请日：2021-06-08
IPC分类号： B01J21/12 , B01J23/66 , B01J35/00 , B01J37/02 , B01J37/08 , B01J37/16 , B01J37/18 , B01J23/44 , B01J23/52 , B01J35/002 , B01J37/0205 , B01J37/0207 , B01J37/088
摘要： Methods of producing gold-palladium catalysts suitable for use in the production of vinyl acetate may include drying the catalyst after the incorporation of a promoter at higher temperatures (e.g., 160°C or greater) to restructure the metals and/or alloys on the catalyst. The restructured catalyst advantageously has increased catalytic activity and improved stability.
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公开(公告)号：WO2021121978A1
公开(公告)日：2021-06-24
申请号：PCT/EP2020/084173
申请日：2020-12-01
IPC分类号： C01B3/04 , C01B3/22 , B01J21/08 , B01J21/12 , B01J23/28 , B01J23/30 , B01J35/00 , B01J37/02 , B01J37/20 , B01J37/08 , B01J35/0013 , B01J37/0207 , B01J37/086
摘要： L'invention décrit un procédé de production photocatalytique de dihydrogène effectué en phase liquide et/ou en phase gazeuse sous irradiation mettant en œuvre un photocatalyseur comprenant un support et des nanoparticules de sulfure de molybdène ou de sulfure de tungstène présentant une bande interdite supérieure à 2,3 eV, ledit photocatalyseur étant préparé par imprégnation en milieu fondu suivie d'une sulfuration. Ledit procédé est effectué en mettant en contact une charge avec au moins une molécule contenant au moins un atome d'hydrogène et au moins un composé sacrificiel avec ledit photocatalyseur, puis en irradiant le photocatalyseur de manière à produire du dihydrogène et oxyder le composé sacrificiel.
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公开(公告)号：WO2021250613A1
公开(公告)日：2021-12-16
申请号：PCT/IB2021/055123
申请日：2021-06-10
IPC分类号： B01J21/12 , B01J23/04 , B01J23/10 , B01J23/22 , B01J35/10 , C07C5/333 , B01J37/02 , B01J37/0207 , C07C2521/12 , C07C2523/04 , C07C2523/10 , C07C2523/22 , C07C5/3332
摘要： A supported non-oxidative alkane dehydrogenation catalyst and a method for making and using the same is disclosed. The supported non-oxidative alkane dehydrogenation catalyst can include a vanadium oxide, a rare earth metal oxide, an alkali metal oxide, and a support containing silica and alumina.
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8.发明申请
公开(公告)号：WO2021198276A1
公开(公告)日：2021-10-07
申请号：PCT/EP2021/058331
申请日：2021-03-30
申请人： BASF CORPORATION , BASF SE
发明人： HUENNEKES, Edgar Viktor , MCGUIRE, Nicholas , CORDES, Petra , BEARD, Kevin , BECKER, Jan Martin , HOCHMUTH, John K , VOSS, Kenneth E , PATCHETT, Joseph A , MUNDING, Andreas R.
IPC分类号： B01D53/00 , B01J21/06 , B01J23/745 , B01J29/68 , B01J29/72 , B01J35/00 , B01J37/02 , B01D2251/2067 , B01D2255/1021 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9025 , B01D2255/9032 , B01D2255/9207 , B01D2257/404 , B01D2257/406 , B01D53/9418 , B01D53/9436 , B01J21/066 , B01J29/7215 , B01J29/723 , B01J35/002 , B01J37/0201 , B01J37/0207 , B01J37/0244 , B01J37/0246 , B01J37/0248
摘要： The present invention relates to a process for preparing a catalyst for the selective catalytic reduction of nitrogen oxide comprising, among other steps, preparing a second aqueous mixture comprising water and an iron salt; and disposing the second mixture on the substrate obtained according to (ii), comprising a coating comprising a zeolitic material comprising copper, over y % of the substrate axial length from the inlet end to the outlet end of the substrate, wherein y is in the range of from 10 to x, obtaining a substrate comprising, in a first zone, the coating comprising a zeolitic material comprising copper and over y % of the substrate axial length an iron salt; and, if x > y, in a second zone extending from y % to x % of the substrate axial length from the inlet end to the outlet end, the coating comprising a zeolitic material comprising copper.
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公开(公告)号：WO2021126391A1
公开(公告)日：2021-06-24
申请号：PCT/US2020/059108
申请日：2020-11-05
申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS , SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
发明人： ARUDRA, Palani , AITANI, Abdullah M. , JIN, Yaming , KOSEOGLU, Omer Refa , AKHTAR, Muhammad Naseem
IPC分类号： B01J29/40 , B01J37/02 , C07C5/22 , B01J35/00 , B01J35/10 , B01J2229/186 , B01J23/08 , B01J29/405 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0203 , B01J37/0207 , B01J37/0236 , B01J37/088 , C07C2/76 , C07C2523/08 , C07C2529/40 , C07C5/412
摘要： Processes for aromatizing hydrocarbons include contacting the hydrocarbons with a catalyst composition comprising a metal oxide dispersed on a surface of a zeolite support, where contacting the hydrocarbons with the catalyst composition causes at least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons. The catalyst composition is prepared by a synthesis process that includes combining the zeolite support with a hydrocarbon solvent to form a zeolite mixture, where the hydrocarbon solvent pre-wets the pores of the zeolite support. The synthesis process further includes combining a polar solvent comprising a metal salt with the zeolite mixture to form an impregnated zeolite support. The synthesis process also includes drying the impregnated zeolite support and calcining the impregnated zeolite support to convert the metal salt to the metal oxide, thereby forming the catalyst composition.
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10.发明申请
公开(公告)号：WO2021122061A1
公开(公告)日：2021-06-24
申请号：PCT/EP2020/084662
申请日：2020-12-04
发明人： BOUALLEG, Malika , JOTHIE, Laetitia
IPC分类号： C10G49/04 , B01J23/755 , B01J37/00 , B01J37/02 , B01J35/1014 , B01J35/1042 , B01J35/1061 , B01J37/0081 , B01J37/0203 , B01J37/0207 , B01J37/088 , B01J37/18
摘要： Catalyseur d'hydrogénation sélective susceptible d'être obtenu par le procédé comprenant au moins les étapes suivantes: a) on met en contact le support d'alumine avec au moins un additif organique b) on met en contact le support d'alumine avec au moins un sel métallique de nickel, dont la température de fusion dudit sel métallique est comprise entre 20°C et 150°C; c) on chauffe sous agitation le mélange solide obtenu à l'issue des étapes a) et b); d) on sèche le précurseur de catalyseur à l'issue de l'étape c); e) on réalise une étape de traitement thermique du précurseur de catalyseur séché obtenu à l'issue de l'étape d).
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