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公开(公告)号：WO2022242292A1
公开(公告)日：2022-11-24
申请号：PCT/CN2022/081757
申请日：2022-03-18
Applicant: 华为技术有限公司
Abstract: 本申请提供一种苯并环丁烯类单体，结构式为：（I），其中，两个R1分别独立选自氢原子、甲基、甲氧基、乙基、酯基；R2选自氢原子、甲基、甲氧基、酯基；R3选自苯基、萘基、联苯基、芳香烷基、含有1～10个碳原子的脂肪链；R4选自氢原子、甲基、甲氧基、乙基、酯基；R5选自氢原子、甲基、甲氧基。本申请还提供苯并环丁烯类单体的制备方法、苯并环丁烯树脂及其制备方法、低介电复合材料及半导体器件。苯并环丁烯类单体具有多官能度；制备条件温和、易于制备、且成本低。所述苯并环丁烯类单体通过预聚合形成苯并环丁烯树脂，所述苯并环丁烯树脂具有高的交联密度、优异的耐热性、极低的热膨胀系数、极低的介电损耗。
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公开(公告)号：WO2022203985A1
公开(公告)日：2022-09-29
申请号：PCT/US2022/021081
申请日：2022-03-21
Applicant: BROWN UNIVERSITY , SK INNOVATION CO., LTD.
Inventor： PETERSON, Andrew , GOLDSMITH, Franklin , BAE, Jongyoon , YUN, Dongmin , IM, Juhwan , KIM, Dokyoung
Abstract: Aspects of the invention are associated with the discovery of processes for converting methane (CH4), present in a methane-containing feed that may be obtained from a variety of sources such as natural gas, to higher hydrocarbons (e.g., C2+ hydrocarbons) such as C2 hydrocarbons (e.g., ethane, ethylene, and acetylene) and aromatic hydrocarbons (e.g., benzene, one or more C1- or C2-substituted benzenes, and/or one or more fused ring aromatic hydrocarbons). Representative processes involve direct, non-oxidative methane conversion (NOMC), such that the need for an oxidant to form CO as an intermediate may advantageously be avoided. This reduces overall complexity and the tendency to promote unwanted side reactions that reduce hydrocarbon yields and lead to CO2 production.
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公开(公告)号：WO2022154480A1
公开(公告)日：2022-07-21
申请号：PCT/KR2022/000566
申请日：2022-01-12
Applicant: 한국화학연구원
Inventor： 황동원 , 엄인용 , 윤광남 , 히다잣마르셀 죠나단
IPC: C07C2/76 , C07C7/20 , B01J21/04 , C07C11/107
Abstract: 본 발명은 1-알코올의 탈수 반응용 첨가제 및 이를 이용한 1-올레핀의 제조방법에 관한 것으로, 보다 상세하게는 바이오유래 1-알코올의 탈수 반응시, 부반응을 억제하고, 이성질체의 생성을 효과적으로 저감시켜 1-올레핀의 높은 선택도와 순도를 동시에 만족시킬 수 있을 뿐만 아니라, 1-올레핀을 고수율로 수득할 수 있어 매우 경제적인 방법으로 1-올레핀을 대량 생산할 수 있는 1-알코올의 탈수 반응용 첨가제 및 이를 이용한 1-올레핀의 제조방법에 관한 것이다.
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公开(公告)号：WO2021126391A1
公开(公告)日：2021-06-24
申请号：PCT/US2020/059108
申请日：2020-11-05
Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS , SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY
Inventor： ARUDRA, Palani , AITANI, Abdullah M. , JIN, Yaming , KOSEOGLU, Omer Refa , AKHTAR, Muhammad Naseem
IPC: B01J29/40 , B01J37/02 , C07C5/22 , B01J35/00 , B01J35/10 , B01J2229/186 , B01J23/08 , B01J29/405 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0203 , B01J37/0207 , B01J37/0236 , B01J37/088 , C07C2/76 , C07C2523/08 , C07C2529/40 , C07C5/412
Abstract: Processes for aromatizing hydrocarbons include contacting the hydrocarbons with a catalyst composition comprising a metal oxide dispersed on a surface of a zeolite support, where contacting the hydrocarbons with the catalyst composition causes at least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons. The catalyst composition is prepared by a synthesis process that includes combining the zeolite support with a hydrocarbon solvent to form a zeolite mixture, where the hydrocarbon solvent pre-wets the pores of the zeolite support. The synthesis process further includes combining a polar solvent comprising a metal salt with the zeolite mixture to form an impregnated zeolite support. The synthesis process also includes drying the impregnated zeolite support and calcining the impregnated zeolite support to convert the metal salt to the metal oxide, thereby forming the catalyst composition.
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5.发明申请
公开(公告)号：WO2021048693A1
公开(公告)日：2021-03-18
申请号：PCT/IB2020/058138
申请日：2020-09-01
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： SABNIS, Kaiwalya , BAZAZZADEH, Kevin , CONANT, Travis , STEVENSON, Scott
Abstract: Processes for dehydroaromatization of C6 paraffins to form aromatic hydrocarbons are disclosed. The processes include contacting a mixture of branched and linear paraffins with at least two catalysts to produce aromatic hydrocarbons. One catalyst has a higher relative aromatization reactivity and another catalyst has a higher relative isomerization activity. In a common example, a mixture of branched and linear hexanes is contacted with aromatization and isomerization catalysts to produce benzene.
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Patent Agency Ranking
公开(公告)号：WO2019211727A1
公开(公告)日：2019-11-07
申请号：PCT/IB2019/053502
申请日：2019-04-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： GAJULA, Sreenivasa Rao , KUMAR, Amit , KOTTAVARITHOTTIL, Ziyad , JANA, Suman Kumar , MUPPARAJU, Eswara Rao , DUBEY, Vinita , SREERAMAGIRI, Sivakumar
Abstract: A process for activating an aromatization catalyst includes contacting an aromatization catalyst with a carburizing gas in a carburization reactor at a carburization pressure in a range of greater than 300 kPa to 800 kPa, or 500 kPa to 600 kPa, to obtain a calcined aromatization catalyst. The carburizing gas provides a carbon source, preferably the carburizing gas comprises at least one of methane, ethane, propane, butane, or carbon monoxide.
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公开(公告)号：WO2018118347A1
公开(公告)日：2018-06-28
申请号：PCT/US2017/063385
申请日：2017-11-28
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor： WANG, Kun , MERCHANT, Shamel
Abstract: An integrated process for converting low-value paraffinic materials to high octane gasoline and high-cetane diesel light is disclosed. The process involves: (1) oxidation of an iso-paraffin to alkyl hydroperoxide and alcohol; (2) converting the alkyl hydroperoxide and alcohol to dialkyl peroxide; (3) converting low-octane, paraffinic gasoline molecules using the dialkyl peroxides as radical initiators, thereby forming high-cetane diesel, while the dialkyl peroxide is converted to an alcohol; (4) converting the alcohol to an olefin; and (5) alkylating the olefin with iso-butane to form high-octane alkylate. The net reaction is thus conversion of iso-paraffin to high-octane gasoline alkylate, and conversion of low-octane paraffinic gasoline to high-cetane diesel.
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公开(公告)号：WO2018080025A1
公开(公告)日：2018-05-03
申请号：PCT/KR2017/010371
申请日：2017-09-21
Applicant: (주) 엘지화학
IPC: C07C2/76 , C07C11/16 , C07C7/20 , B01J23/847 , B01J23/76 , B01J23/86 , B01J23/78 , B01J23/745 , B01J23/72 , B01J21/06
Abstract: 본 발명은 촉매의 재현성이 우수한 부타디엔의 제조방법에 관한 것으로, 보다 상세하게는 금속 산화물 촉매가 충진된 반응기에 구성성분으로 부텐, 산소, 질소 및 스팀을 포함한 반응물을 유입시켜, 반응온도 300 내지 450 ℃ 하에 산화적 탈수소화 반응을 수행하는 반응단계; 상기 반응단계 이후 상기 구성성분 각각의 유량 변화율이 ±40% 미만인 범위 내에서 상기 반응물 공급을 유지, 또는 상기 반응물 중 부텐의 공급만 중단한 뒤 상기 반응기를 200 ℃ 이하 내지 70 ℃ 초과 범위내로 냉각시키는 제1차 냉각단계; 및 상기 1차 냉각단계 이후 상기 반응물 공급을 중단, 또는 최소한 상기 반응물 중 부텐의 공급을 중단하고, 반응기를 70 ℃ 이하로 냉각시키는 제2차 냉각단계;를 포함하는 것을 특징으로 하는 촉매의 재현성이 우수한 부타디엔의 제조방법에 관한 것이다. 본 발명에 따르면, 반응공정의 운전을 중단할 필요성이 있어 산화적 탈수소화 반응을 중단한 경우, 이후 재가동시 발생 될 수 있는 촉매의 비활성화를 방지하여 운전 시간 및 비용의 손실을 줄일 수 있는 효과가 있다.
Abstract translation: 生产丁二烯，氧气，氮气和蒸汽的方法技术领域本发明涉及一种生产具有优异催化剂再现性的丁二烯的方法，更具体地涉及生产丁二烯，氧气，氮气和蒸汽的方法， 在300〜450℃的反应温度下进行氧化脱氢反应的反应工序; 反应物供给维持在反应工序后的各成分的流量的变化率小于40％或仅停止反应物中的丁烯的供给的范围内， 主要冷却步骤; 第二冷却步骤，在第一冷却步骤后停止反应物的供应或至少停止反应物中丁烯的供应并将反应器冷却到70℃或更低。 和一种生产优异丁二烯的方法。 根据本发明，在所述情况下需要停止反应步骤的操作中，其停止所述氧化脱氢反应，能够防止催化剂的失活，减少的操作时间和成本的损失的效果之后重新启动时可能出现的
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公开(公告)号：WO2017189137A1
公开(公告)日：2017-11-02
申请号：PCT/US2017/024234
申请日：2017-03-27
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： KEUSENKOTHEN, Paul, F. , ILIAS, Samia , BUCHANAN, John, Scott , SHEKHAR, Mayank , KOC-KARABOCEK, Reyyan , XU, Teng
Abstract: The invention relates to catalytic aromatization, e.g., for the conversion of nonaromatic hydrocarbon to higher-value aromatic hydrocarbon, to catalysts useful for such aromatization, and to methods for making such catalysts. The aromatization catalyst comprises at least one molecular sieve component and at least one dehydrogenation component, and the molecular sieve component is present in an amount of 80 wt% or more.
Abstract translation: 本发明涉及催化芳构化，例如用于将非芳香烃转化为更高价值的芳烃的催化芳构化，以及用于这种芳构化的催化剂，以及制备这种催化剂的方法。 芳构化催化剂包含至少一种分子筛组分和至少一种脱氢组分，并且分子筛组分的存在量为80重量％或更多。
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10.发明申请PROCESS FOR SEPARATION OF AROMATIC HYDROCARBONS FROM A MIXED HYDROCARBON STREAM 审中-公开从混合碳氢化合物流中分离芳香烃的方法
公开(公告)号：WO2017102641A1
公开(公告)日：2017-06-22
申请号：PCT/EP2016/080624
申请日：2016-12-12
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor： JAIN, Kokil , DITTRICH, Christoph , KUMAR, Prashant
CPC classification number: C10G21/14 , C07C7/11 , C10G21/28 , C10G31/06 , C10G45/68 , C10G2300/1096 , C10G2300/4081 , C10G2400/30 , C07C15/00
Abstract: The present invention relates to a process for the separation of aromatic hydrocarbons from a hydrocarbon feed stream comprising contacting a hydrocarbon feed stream with a solvent for aromatics (aromatics solvent) to provide an aromatics-laden solvent stream and subjecting the aromatics-laden solvent stream to solvent regeneration to provide regenerated aromatics solvent and an aromatics stream.
Abstract translation: 本发明涉及从烃进料流中分离芳烃的方法，其包括使烃进料流与芳族化合物溶剂（芳族溶剂）接触以提供载有芳族化合物的溶剂流和 使充满芳香剂的溶剂流进行溶剂再生以提供再生的芳烃溶剂和芳烃流。
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