一种制备改性纤维素的方法及装置

    公开(公告)号:WO2022143214A1

    公开(公告)日:2022-07-07

    申请号:PCT/CN2021/139048

    申请日:2021-12-17

    Abstract: 一种制备改性纤维素的方法及装置,包括反应釜,反应釜内设有用于反应的固液空间,和用于容纳从固液空间内溢出的气体的气相空间,在反应釜外设有一外循环系统,外循环系统的入口端与反应釜内的气相空间连通设置,外循环系统的出口端深入到反应釜内设置。本申请用于纤维素制备羟丙基甲基纤维素、羟乙基甲基纤维素等物质,在纤维素醚化反应进行时,在固液空间内的液体受热气化,先进入到气相空间,然后再通过外循环系统循环进入到反应釜内,使得可以降低釜内压力,保证整体的安全性能,降低反应釜的耐压性能和密封性能,同时液体持续经过外循环系统回到反应釜内,使反应釜内反应液始终处于过剩状态,反应速度快,生产效率高。

    METHOD FOR CONTROLLED PREPARATION OF LOW MOLECULAR WEIGHT CELLULOSE ETHER

    公开(公告)号:WO2019036123A1

    公开(公告)日:2019-02-21

    申请号:PCT/US2018/040196

    申请日:2018-06-29

    Abstract: A process includes: (a) providing an initial cellulose ether powder containing 0.5 to 10 weight-percent water based on total cellulose ether powder weight; (b) heating the initial cellulose ether powder to a temperature in a range of 30 to 130 degrees Celsius; (c) before, during and/or after heating in step (b), adding solid base to the cellulose ether powder and mixing with the initial cellulose ether powder to form a cellulose ether/base mixture; (d) adding volatile acid to the cellulose ether/base mixture and mixing; and (e) allowing the volatile acid to hydrolyze the initial cellulose ether to form a final cellulose ether having a lower viscosity than the initial cellulose ether.

    ABSORBENT MATERIAL
    3.
    发明申请
    ABSORBENT MATERIAL 审中-公开
    吸收材料

    公开(公告)号:WO2010061225A3

    公开(公告)日:2010-08-12

    申请号:PCT/GB2009051608

    申请日:2009-11-27

    Inventor: LAW STEPHEN

    Abstract: This invention relates to absorbent materials useful in the manufacture of absorbent articles, in particular dressings for the advanced wound care market. The absorbent materials of the present invention are sulfonated polysaccharides, particularly water-insoluble cellulose alkyl sulfonates in which the cellulose is substituted by one type of alkyl sulfonate group. The invention also provides a process for the manufacture of such materials. The preferred cellulose alkyl sulfonate described herein is cellulose ethyl sulfonate. Reinforcing fibers and/or antimicrobial agents are optionally applied to the cellulose alkyl sulfonate.

    Abstract translation: 本发明涉及用于制造吸收性物品的吸收性材料,特别是用于高级伤口护理市场的敷料。 本发明的吸收材料是磺化多糖,特别是纤维素被一种烷基磺酸盐基团取代的不溶于水的纤维素烷基磺酸盐。 本发明还提供了用于制造这种材料的方法。 本文所述的优选的纤维素烷基磺酸盐是纤维素乙基磺酸盐。 任选地将增强纤维和/或抗微生物剂施加到纤维素烷基磺酸盐。

    INHIBITORS AGAINST SODIUM ION ABSORPTION, AND PREVENTIVE OR THERAPEUTIC AGENTS AND FOODS CONTAINING THE SAME
    4.
    发明申请
    INHIBITORS AGAINST SODIUM ION ABSORPTION, AND PREVENTIVE OR THERAPEUTIC AGENTS AND FOODS CONTAINING THE SAME 审中-公开
    禁止吸收钠的抑制剂,以及预防或治疗药物和含有其的食品

    公开(公告)号:WO01051063A1

    公开(公告)日:2001-07-19

    申请号:PCT/JP2001/000095

    申请日:2001-01-11

    Abstract: Inhibitors against the absorption of sodium ion containing as the active ingredient metal salts (excluding sodium salt) of cellulose derivatives of the general formula (I): R-O-A, which effectively inhibit excess common salt existing in the body from being absorbed into the body system and excrete the common salt outside the body actively and safely; preventive or therapeutic agents for disease attributed to the existence of excess common salt or those necessitating restriction on the ingestion of common salt, containing the above metal salts as the active ingredient; and foods containing the same. In said formula R is a cellulose residue; and A is a functional group having an ability to exchange cations.

    Abstract translation: 抑制含有作为活性成分的钠离子的钠离子通式(I)的纤维素衍生物的金属盐(不包括钠盐):有效抑制身体中存在的多余的共同盐被吸收到身体系统中的ROA, 积极安全地排出身体外的常见盐; 含有上述金属盐作为活性成分的,由于存在过量的常用盐或者需要限制食盐的疾病的预防或治疗剂; 和含有它的食物。 在所述式中,R是纤维素残基; 而A是具有交换阳离子能力的官能团。

    POLYSACCHARIDE DERIVATIVES AND HYDRAULIC COMPOSITIONS
    7.
    发明申请
    POLYSACCHARIDE DERIVATIVES AND HYDRAULIC COMPOSITIONS 审中-公开
    多糖衍生物和液压组合物

    公开(公告)号:WO1998023647A1

    公开(公告)日:1998-06-04

    申请号:PCT/JP1997004316

    申请日:1997-11-26

    Inventor: KAO CORPORATION

    Abstract: Polysaccharide derivatives in which some or all of the hydroxyl groups have been substituted by hydrophobic substituent(s) (A) having as the partial structure a C8-43 hydrocarbon group, and ionic hydrophilic substituent(s) (B) having as the partial structure at least one group selected from the group consisting of sulfonate, carboxyl, phosphate and sulfate groups and salts thereof, which have an average degree of substitution per constituting monosaccharide residue by the substituent (A), determined by Zeisel's method or the diazomethane method, of at least 0.0001 but less than 0.001 and an average degree of substitution per constituting monosaccharide residue by the substituent (B), determined by the colloidal titration method, of from 0.01 to 2.0. These derivatives are useful as chemical admixtures for hydraulic materials and give hydraulic compositions excellent in dispersibility and stability.

    Abstract translation: 其中一些或全部羟基已经被作为部分结构的疏水取代基(A)取代为C8-43烃基的多糖衍生物和具有部分结构的离子亲水取代基(B) 选自由磺酸盐,羧基,磷酸盐和硫酸盐基团组成的组中的至少一个基团及其盐,其通过Zeisel方法或重氮甲烷法测定由取代基(A)构成单糖残基的平均取代度) 至少0.0001但小于0.001,通过胶体滴定法测定的由取代基(B)构成的单糖残基的平均取代度为0.01〜2.0。 这些衍生物可用作水硬性材料的化学混合物,并且具有优异的分散性和稳定性的水硬性组合物。

    ABSORBENT MATERIAL
    8.
    发明申请
    ABSORBENT MATERIAL 审中-公开
    吸收材料

    公开(公告)号:WO2010061225A2

    公开(公告)日:2010-06-03

    申请号:PCT/GB2009/051608

    申请日:2009-11-27

    Inventor: LAW, Stephen

    Abstract: This invention relates to absorbent materials useful in the manufacture of absorbent articles, in particular dressings for the advanced wound care market. The absorbent materials of the present invention are sulfonated polysaccharides, particularly water-insoluble cellulose alkyl sulfonates in which the cellulose is substituted by one type of alkyl sulfonate group. The invention also provides a process for the manufacture of such materials. The preferred cellulose alkyl sulfonate described herein is cellulose ethyl sulfonate. Reinforcing fibers and/or antimicrobial agents are optionally applied to the cellulose alkyl sulfonate.

    Abstract translation: 本发明涉及可用于制造吸收制品的吸收材料,特别是用于先进伤口护理市场的敷料。 本发明的吸收材料是磺化多糖,特别是其中纤维素被一种烷基磺酸盐基团取代的水不溶性纤维素烷基磺酸盐。 本发明还提供了制造这种材料的方法。 本文所述的优选的烷基磺酸纤维素是纤维素乙基磺酸盐。 增强纤维和/或抗微生物剂任选地加到纤维素烷基磺酸盐上。

    PROCESS FOR SELECTIVE OXIDATION OF CELLULOSE
    10.
    发明申请
    PROCESS FOR SELECTIVE OXIDATION OF CELLULOSE 审中-公开
    选择性氧化纤维素的方法

    公开(公告)号:WO00050463A1

    公开(公告)日:2000-08-31

    申请号:PCT/NL2000/000119

    申请日:2000-02-24

    CPC classification number: D21H11/20 C08B15/02 D21C9/002

    Abstract: A process for oxidising cellulose, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine, or an oxidative enzyme, and the resulting nitrosonium ion is used to selectively oxidise the cellulose 6-hydroxy-methylene groups to carbaldehyde groups and carboxylic acid groups.

    Abstract translation: 氧化纤维素的方法,其中在诸如Mn,Fe,Cu等过渡金属和络合剂如多胺或氧化剂的复合物存在下,使用氧化剂氧化诸如TEMPO的硝酰基化合物 酶,并且所得的亚硝鎓离子用于选择性地将纤维素6-羟基 - 亚甲基氧化成甲醛基团和羧酸基团。

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