发明公开
EP1383857A2 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
有权
VERWENDUNG VON METALLKOMPLEXVERBINDUNGEN ALS氧化剂KATALYSATOREN
- 专利标题: USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
- 专利标题(中): VERWENDUNG VON METALLKOMPLEXVERBINDUNGEN ALS氧化剂KATALYSATOREN
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申请号: EP02740514.1申请日: 2002-04-25
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公开(公告)号: EP1383857A2公开(公告)日: 2004-01-28
- 发明人: SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , HÄNSLER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
- 申请人: Ciba Specialty Chemicals Holding Inc.
- 申请人地址: Klybeckstrasse 141 4057 Basel CH
- 专利权人: Ciba Specialty Chemicals Holding Inc.
- 当前专利权人: Ciba Specialty Chemicals Holding Inc.
- 当前专利权人地址: Klybeckstrasse 141 4057 Basel CH
- 优先权: EP01810425 20010430; CH227801 20011213
- 国际公布: WO2002088289 20021107
- 主分类号: C11D3/39
- IPC分类号: C11D3/39 ; B01J31/18 ; D21C9/10 ; D21C9/16 ; C07D213/70 ; C07D213/61 ; C07D213/77 ; C07D213/74 ; C07D213/30 ; C07D301/12 ; C07F13/00
摘要:
Use of metal complex compounds of formula (1): [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R'13 wherein R13, R'13 and R'13 are as defined above for R13; -NR14R15 or -N+R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
公开/授权文献
- EP1383857B1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 公开/授权日:2006-05-31
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