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    USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    1.
    发明公开
    USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
    金属络合物作为氧化催化剂使用

    公开(公告)号：EP1521820A1

    公开(公告)日：2005-04-13

    申请号：EP03763699.0

    申请日：2003-07-03

    申请人： Ciba Specialty Chemicals Holding Inc.

    发明人： SCHLINGLOFF, Gunther ,  WIEPRECHT, Torsten ,  BACHMANN, Frank ,  DANNACHER, Josef ,  DUBS, Marie-Josée ,  HAZENKAMP, Menno ,  HEINZ, Uwe ,  FREY, Markus ,  SCHNEIDER, Albert

    IPC分类号： C11D3/395 ,  C11D3/16 ,  C07D213/68 ,  C07D213/74 ,  C11D3/39

    CPC分类号： C11D3/168 ,  C07D213/68 ,  C07D213/74 ,  C11D3/3932

    摘要： Use of metal complex compounds of formula (1) [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO12R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -NoR14R15R16; -(C1-C6alkylene)-NoR14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-NoR14R15R16, -N[C1-C6alkylene)-NoR14R15R16]2; -N(R13)-N-R14R15 or -N(R13)-NoR14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R1-R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R1-R5 and R7-R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.

    MANGANKOMPLEXE ALS KATALYSATOREN FÜR PERSAUERSTOFFVERBINDUNGEN ZUR REINIGUNG VON HARTEN OBERFLÄCHEN, INSBESONDERE VON GESCHIRR
    7.
    发明公开
    MANGANKOMPLEXE ALS KATALYSATOREN FÜR PERSAUERSTOFFVERBINDUNGEN ZUR REINIGUNG VON HARTEN OBERFLÄCHEN, INSBESONDERE VON GESCHIRR 审中-公开
    MANGA复杂的催化剂的过氧用于清洁硬表面，尤其是线束

    公开(公告)号：EP1105454A1

    公开(公告)日：2001-06-13

    申请号：EP99941530.0

    申请日：1999-08-06

    申请人： Ciba Specialty Chemicals Holding Inc.

    发明人： HAZENKAMP, Menno ,  DUBS, Marie-Josée ,  BACHMANN, Frank ,  SCHLINGLOFF, Gunther ,  ALLEMANN, Rachel ,  DANNACHER, Josef

    IPC分类号： C11D3/39

    CPC分类号： C11D3/3932

    摘要： Manganese complexes of formula (1) or (2) are used as activators for peroxygenated compounds in dishwashing detergents, wherein Y represents linear or branched alkylene of formula -C(R1)2]m, wherein m is a whole number ranging from 2-8 and the radicals R1 represent independently from each other hydrogen or C1-C4-alkyl, -CX=CX-, whereby X is cyano, linear or branched C1-C8 -alkyl or di-(linear or branched C1-C8 alkyl)-amino; -(CH2)q-NR1-(CH2)q-, wherein R1 has the meaning thus cited and q is 1, 2, 3 or 4 or stands for a 1,2-cyclohexylene or 1,2 phenyl radical of formula (a) or (b), wherein R8 represents hydrogen, CH2OH, CH2NH2 or SO3M, wherein M represents hydrogen, an alkaline metal atom, ammonium or the cation of an organic amine, R?5 and R6¿ represent independently from each other hydrogen, linear or branched C¿1?-C4 -lkyl; linear or branched C1-C8alkene-R2, wherein R2 is OR1, COOR1 or NR3R4, unsubstituted aryl or aryl that is substituted by cyano, halogen, OR1, COOR1, nitro, linear or branched C1-C8-alkyl, NR3R4, wherein R3 and R4 mean independently from each other hydrogen or linear or branched C1-C12-alkyl; or substituted by -N?oR¿1R3R4, wherein R1, R3, R4 have the meanings thus cited, the radicals R7 represent independently from each other hydrogen or C1-C4 alkyl, Z1 and Z2 represent independently from each other hydrogen, hydroxy, C1-C4 alkoxy or di-(C1-C4-alkyl)amino and A stands for a charge-equalising anion ligand.

    USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    8.
    发明公开
    USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
    VERWENDUNG VON METALLKOMPLEXVERBINDUNGEN ALS氧化剂KATALYSATOREN

    公开(公告)号：EP1383857A2

    公开(公告)日：2004-01-28

    申请号：EP02740514.1

    申请日：2002-04-25

    申请人： Ciba Specialty Chemicals Holding Inc.

    发明人： SCHLINGLOFF, Gunther ,  WIEPRECHT, Torsten ,  BACHMANN, Frank ,  DANNACHER, Joseph ,  DUBS, Marie-Josée ,  HAZENKAMP, Menno ,  HÄNSLER, Grit ,  SCHMIDT, Brigitte ,  SCHNEIDER, Albert ,  WEINGARTNER, Peter

    IPC分类号： C11D3/39 ,  B01J31/18 ,  D21C9/10 ,  D21C9/16 ,  C07D213/70 ,  C07D213/61 ,  C07D213/77 ,  C07D213/74 ,  C07D213/30 ,  C07D301/12 ,  C07F13/00

    CPC分类号： B01J31/1815 ,  B01J23/34 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/16 ,  B01J2531/46 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F13/005 ,  C11D3/3932 ,  D06L4/10 ,  D06L4/12 ,  D06P5/02 ,  D06P5/153 ,  D21C9/1036 ,  D21C9/163

    摘要： Use of metal complex compounds of formula (1): [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18 alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl;-N(R13)-NR'13R'13 wherein R13, R'13 and R'13 are as defined above for R13; -NR14R15 or -N+R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

    摘要翻译： 使用式[LnMemXp] zYq（1）的金属络合物，其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥连基团，n和m各自独立地是另一个具有 值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为 其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12各自为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR'13R“13其中R 13，R 13和R 13如上述R 13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 - ，6或7元环，其可以任选地含有另外的杂原子; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物 式（2）的配体。