Conventional synthesis various arylbis with bulky aryl group or an electron withdrawing aryl group which has been difficult (perfluoroalkyl sulfonyl) methane and a method of manufacturing at a high efficiency, the asymmetric catalyst, to various functional materials, etc. wide range of applications possible novel arylbis (perfluoroalkylsulfonyl) methane and of these metal salts, provide, and provides an excellent catalyst. Reacting the aryl halomethane and sodium trifluoromethanesulfinate, then the generated aryl triflone ​​reacted with t-BuLi and the like, the lithium salt of aryl triflone ​​obtained is reacted with trifluoromethanesulfonic anhydride Accordingly, pentafluorophenyl (triflyl) methane, {4- (pentafluorophenyl) -2,3,5,6-tetrafluorophenyl} bis (triflyl) arylbis such as methane (trifluoromethylsulfonyl) methane high yield get at a rate.