The present invention relates to a polymer composition comprising: (i) one or more dendritic polymers; and (ii) a reactive diluent that is capable of being chemically coupled to the functional groups of the dendritic polymers, wherein when the dendritic polymer is coupled to the reactive diluent in the presence of a cross-linker, a polymerized solid is formed at high concentrations in a liquid medium. The present invention further relates to methods of preparing the polymer composition and its use in forming coatings.