An exhaust gas control system includes an upstream purification device disposed in an exhaust passage of the internal combustion engine, a downstream purification device disposed in a portion of the exhaust passage downstream from the upstream purification device, a fuel addition valve disposed in a portion of the exhaust passage upstream from the upstream purification device, and a urea addition valve disposed in a portion of the exhaust passage between the upstream purification device and the downstream purification device, and a cooling device. The cooling device is configured such that refrigerant cools the fuel addition valve first and then cools the urea addition valve subsequent to the fuel addition valve.