发明授权
- 专利标题: Lithium zinc secondary battery, battery pack, vehicle, and stationary power supply
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申请号: US16804268申请日: 2020-02-28
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公开(公告)号: US11316153B2公开(公告)日: 2022-04-26
- 发明人: Kazuki Ise , Yasunobu Yamashita , Kazuomi Yoshima , Shinsuke Matsuno , Norio Takami , Hiroki Inagaki
- 申请人: KABUSHIKI KAISHA TOSHIBA
- 申请人地址: JP Minato-ku
- 专利权人: KABUSHIKI KAISHA TOSHIBA
- 当前专利权人: KABUSHIKI KAISHA TOSHIBA
- 当前专利权人地址: JP Minato-ku
- 代理机构: Oblon, McClelland, Maier & Neustadt, L.L.P.
- 优先权: JPJP2018-175273 20180919,JPJP2019-043630 20190311
- 主分类号: H01M4/36
- IPC分类号: H01M4/36 ; H01M4/38 ; H01M4/48 ; H01M10/052 ; H01M10/42 ; H01M4/02
摘要:
According to one embodiment, provided is a lithium zinc secondary battery including a positive electrode, a negative electrode, an aqueous electrolyte, and a separator between the positive electrode and the negative electrode. The negative electrode includes a zinc-including metal body and an oxide on at least a part of a surface of the metal body. The aqueous electrolyte includes zinc and a lithium salt. Zinc is dissolved and deposited at the negative electrode. Lithium is inserted and extracted from the oxide in a range of −1.4 V (vs. SCE) or more and −1.0 V (vs. SCE) or less. A specific surface area of the oxide is 10 m2/g or more and 350 m2/g or less. A mol concentration ratio Zn/Li between zinc and lithium in the aqueous electrolyte is 1.0×10−5 or more and 0.3 or less.
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