- 专利标题: Aqueous copolymer dispersions and their use in coating compositions
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申请号: US17435129申请日: 2020-02-27
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公开(公告)号: US12071496B2公开(公告)日: 2024-08-27
- 发明人: Kerstin Wenzel , Narayan Raman , Tsz Ming Tsang , James Martin
- 申请人: CELANESE INTERNATIONAL CORPORATION
- 申请人地址: US TX Irving
- 专利权人: Celanese International Corporation
- 当前专利权人: Celanese International Corporation
- 当前专利权人地址: US TX Irving
- 代理机构: Kilpatrick Townsend & Stockton LLP
- 国际申请: PCT/US2020/020151 2020.02.27
- 国际公布: WO2020/180617A 2020.09.10
- 进入国家日期: 2021-08-31
- 主分类号: C08F210/02
- IPC分类号: C08F210/02 ; C08F2/00 ; C08F2/20 ; C08F2/26 ; C08F2/30 ; C08F218/08 ; C08F220/18 ; C09D5/02 ; C09D7/65
摘要:
An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a vinyl ester of a C1 to C18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C1 to C18 carboxylic acid and a C2 to C8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg≤20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.
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