According to various embodiments, an electronic device includes at least one processor. The at least one processor may be configured to: confirm a data session establishment request from a first application executed by the at least one processor; confirm at least one first descriptor corresponding to the first application for path selection; confirm a first network interface corresponding to the at least one first confirmed descriptor based on the at least one first confirmed descriptor; establish a first data session corresponding to the at least one first confirmed descriptor; and transmit and/or receive data related to the first application through the first network interface using the first data session.