发明申请
US20080145301A1 Process For Making a Carbon Nanotubes/Ultra-High Molar Mass Polyethylene Composite Fibre
有权
制备碳纳米管/超高摩尔质量聚乙烯复合纤维的方法
- 专利标题: Process For Making a Carbon Nanotubes/Ultra-High Molar Mass Polyethylene Composite Fibre
- 专利标题(中): 制备碳纳米管/超高摩尔质量聚乙烯复合纤维的方法
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申请号: US11658155申请日: 2005-07-14
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公开(公告)号: US20080145301A1公开(公告)日: 2008-06-19
- 发明人: Harm Van Der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
- 申请人: Harm Van Der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
- 优先权: EP04077162.8 20040727
- 国际申请: PCT/EP2005/007816 WO 20050714
- 主分类号: D01F9/12
- IPC分类号: D01F9/12 ; B28B11/00
摘要:
The invention relates to a process for making a carbon nanotubes/ultra-high molar mass polyethylene (CNTs/UHPE) composite fibre comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibres; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibres showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fibre obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fibre.
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