-
1.发明申请Process For Making a Carbon Nanotubes/Ultra-High Molar Mass Polyethylene Composite Fibre 有权制备碳纳米管/超高摩尔质量聚乙烯复合纤维的方法公开(公告)号：US20080145301A1
公开(公告)日：2008-06-19
申请号：US11658155
申请日：2005-07-14
申请人： Harm Van Der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
发明人： Harm Van Der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
摘要： The invention relates to a process for making a carbon nanotubes/ultra-high molar mass polyethylene (CNTs/UHPE) composite fibre comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibres; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibres showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fibre obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fibre.
摘要翻译： 本发明涉及一种制备碳纳米管/超高摩尔质量聚乙烯（CNTs / UHPE）复合纤维的方法，包括以下步骤：a）用酸性水溶液预处理CNT; b）制备含有预处理的CNT分散在UHPE在旋转溶剂中的溶液中的组合物; 和c）将得到的组合物纺丝成纤维; 其中步骤b）包括将预处理的CNT分散在醇中，并将该分散体与UHPE和旋转溶剂的混合物混合。 通过这种方法，CNTs / UHPE复合纤维在较低的CNTs含量下得到显示出改善的拉伸性能。 另一个优点是不需要或几乎没有任何附加的组分，如分散助剂，以便使CNT在纺丝组合物中的稳定分散。 本发明还涉及通过本发明的方法获得的CNTs / UHPE复合纤维，以及含有所述复合纤维的半成品或最终用途制品。
-
2.发明授权Process for making a carbon nanotubes/ultra-high molar mass polyethylene composite fibre 有权制造碳纳米管/超高摩尔质量聚乙烯复合纤维的方法公开(公告)号：US07780888B2
公开(公告)日：2010-08-24
申请号：US11658155
申请日：2005-07-14
申请人： Harm van der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
发明人： Harm van der Werff , Shilun Ruan , Tongxi Yu , Ping Gao , Roelef Marissen
摘要： The invention relates to a process for making a carbon nanotubes/ultra-high molar mass polyethylene (CNTs/UHPE) composite fiber comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibers; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibers showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fiber obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fiber.
摘要翻译： 本发明涉及一种制备碳纳米管/超高摩尔质量聚乙烯（CNTs / UHPE）复合纤维的方法，包括以下步骤：a）用酸性水溶液预处理CNT; b）制备含有预处理的CNT分散在UHPE在旋转溶剂中的溶液中的组合物; 和c）将得到的组合物纺丝成纤维; 其中步骤b）包括将预处理的CNT分散在醇中，并将该分散体与UHPE和旋转溶剂的混合物混合。 通过这种方法，CNTs / UHPE复合纤维在较低的CNTs含量下得到显示出改善的拉伸性能。 另一个优点是不需要或几乎没有任何附加的组分，如分散助剂，以便使CNT在纺丝组合物中的稳定分散。 本发明还涉及通过本发明的方法获得的CNTs / UHPE复合纤维，以及含有所述复合纤维的半成品或最终用途制品。
-
搜索结果
2 条记录 (耗时 0.02 秒)
