Process For Making a Carbon Nanotubes/Ultra-High Molar Mass Polyethylene Composite Fibre
    1.
    发明申请
    Process For Making a Carbon Nanotubes/Ultra-High Molar Mass Polyethylene Composite Fibre 有权
    制备碳纳米管/超高摩尔质量聚乙烯复合纤维的方法

    公开(公告)号:US20080145301A1

    公开(公告)日:2008-06-19

    申请号:US11658155

    申请日:2005-07-14

    IPC分类号: D01F9/12 B28B11/00

    CPC分类号: B82Y30/00 D01F1/10 D01F6/04

    摘要: The invention relates to a process for making a carbon nanotubes/ultra-high molar mass polyethylene (CNTs/UHPE) composite fibre comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibres; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibres showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fibre obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fibre.

    摘要翻译: 本发明涉及一种制备碳纳米管/超高摩尔质量聚乙烯(CNTs / UHPE)复合纤维的方法,包括以下步骤:a)用酸性水溶液预处理CNT; b)制备含有预处理的CNT分散在UHPE在旋转溶剂中的溶液中的组合物; 和c)将得到的组合物纺丝成纤维; 其中步骤b)包括将预处理的CNT分散在醇中,并将该分散体与UHPE和旋转溶剂的混合物混合。 通过这种方法,CNTs / UHPE复合纤维在较低的CNTs含量下得到显示出改善的拉伸性能。 另一个优点是不需要或几乎没有任何附加的组分,如分散助剂,以便使CNT在纺丝组合物中的稳定分散。 本发明还涉及通过本发明的方法获得的CNTs / UHPE复合纤维,以及含有所述复合纤维的半成品或最终用途制品。

    Polyketone yarn and a method of manufacturing same
    2.
    发明授权
    Polyketone yarn and a method of manufacturing same 失效
    聚酮纱线及其制造方法

    公开(公告)号:US5552218A

    公开(公告)日:1996-09-03

    申请号:US360703

    申请日:1994-12-21

    摘要: The invention relates to polyketone yarns of which the maximum tangential modulus at an elongation of more than 0.2% is at least 10 N/tex which display both high strength and, if so desired, a high elongation at break. The quality number, which is measured on a single filament out of a bundle of at least about 30 filaments spun simultaneously through one spinneret and given as .sigma...epsilon., is higher than 85 mN/tex, preferably higher than 100 mN/tex. The quality number of a yarn spun through one spinneret of one or more holes is higher than 110 mN/tex, preferably higher than 120 mN/tex. The yarns are manufactured by extruding a solution of a linear polymer of alternating ethylene and carbon monoxide units in a resorcinol-containing solvent, after which the solvent is removed with the aid of methanol as coagulant.

    摘要翻译: PCT No.PCT / EP93 / 01586 Sec。 371日期1994年12月21日 102(e)1994年12月21日日期PCT 1993年6月21日PCT公布。 出版物WO94 / 00623 日本1994年1月6日本发明涉及聚酮纱线,其伸长率大于0.2%时的最大切向模量为至少10N / tex,其显示出高强度,如果需要,其断裂伸长率高。 质量数量是通过一根喷丝头同时纺丝的一束至少约30根细丝的单根细丝上测量的,并以西格玛的形式给出。 ε高于85mN / tex,优选高于100mN / tex。 通过一个或多个孔的一个喷丝头纺丝的纱线的质量数目高于110mN / tex,优选高于120mN / tex。 通过在含间苯二酚的溶剂中挤出交替的乙烯和一氧化碳单元的线性聚合物的溶液来制造纱线,然后借助于甲醇作为凝结剂除去溶剂。

    BALLISTIC RESISTANT ARTICLE
    4.
    发明申请
    BALLISTIC RESISTANT ARTICLE 有权
    抗争性文章

    公开(公告)号:US20130220106A1

    公开(公告)日:2013-08-29

    申请号:US13812943

    申请日:2011-07-28

    IPC分类号: F41H5/04 F41H5/013

    摘要: The invention relates to an armor comprising in front to back order at least one rigid first panel comprising inorganic fibers and at least one second panel comprising polymeric fibers, characterized in that the at least one rigid first panel has a flexural strength of at least 300 MPa and the at least one second panel has a flexural strength of at most 250 MPa.

    摘要翻译: 本发明涉及一种装甲,其包括从前到后的顺序,包括至少一个包含无机纤维的刚性第一面板和至少一个包含聚合物纤维的第二面板,其特征在于,所述至少一个刚性第一面板的弯曲强度为至少300MPa 并且所述至少一个第二面板具有至多250MPa的弯曲强度。

    Process of making polyketon yarn
    5.
    发明授权
    Process of making polyketon yarn 失效
    制造聚酮纱的工艺

    公开(公告)号:US5714101A

    公开(公告)日:1998-02-03

    申请号:US586125

    申请日:1996-01-16

    摘要: The invention relates to polyketone yarns of which the maximum tangential modulus at an elongation of more than 0.2% is at least 10 N/tex which display both high strength and, if so desired, a high elongation at break. The quality number, which is measured on a single filament out of a bundle of at least about 30 filaments spun simultaneously through one spinneret and given as .sigma., .epsilon., is higher than 85 mN/tex, preferably higher than 100 mN/tex. The quality number of a yarn spun through one spinneret of one or more holes is higher than 110 mN/tex, preferably higher than 120 mN/tex. The yarns are manufactured by extruding a solution of a linear polymer of alternating ethylene and carbon monoxide units in a resorcinol-containing solvent, after which the solvent is removed with the aid of methanol as coagulant.

    摘要翻译: 本发明涉及聚酮纱线,其伸长率大于0.2%时的最大切向模量为至少10N / tex,其显示出高强度,如果需要,其断裂伸长率高。 通过一个喷丝头同时旋转并以西格玛ε给出的至少约30根长丝束的单个长丝上测量的质量数量高于85mN / tex,优选高于100mN / tex。 通过一个或多个孔的一个喷丝头纺丝的纱线的质量数目高于110mN / tex,优选高于120mN / tex。 通过在含间苯二酚的溶剂中挤出交替的乙烯和一氧化碳单元的线性聚合物的溶液来制造纱线,然后借助于甲醇作为凝结剂除去溶剂。