Invention Application
- Patent Title: HYPERBRANCHED ETHYLENE-BASED OILS AND GREASES
- Patent Title (中): 超乙烯基乙烯和油脂
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Application No.: US14893732Application Date: 2014-06-24
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Publication No.: US20160122259A1Publication Date: 2016-05-05
- Inventor: Daniel J. Arriola , Brad C. Bailey , Jerzy Klosin , Zenon Lysenko , Gordon R. Roof , Austin J. Smith
- Applicant: DOW GLOBAL TECHNOLOGIES LLC
- Applicant Address: US MI Midland
- Assignee: DOW GLOBAL TECHNOLOGIES LLC
- Current Assignee: DOW GLOBAL TECHNOLOGIES LLC
- Current Assignee Address: US MI Midland
- International Application: PCT/US14/43754 WO 20140624
- Main IPC: C07C2/34
- IPC: C07C2/34 ; C07C5/03 ; C07C11/21

Abstract:
A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.
Public/Granted literature
- US09643900B2 Hyperbranched ethylene-based oils and greases Public/Granted day:2017-05-09
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