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公开(公告)号:US11459409B2
公开(公告)日:2022-10-04
申请号:US16494085
申请日:2018-03-14
发明人: Andrew J. Young , Hien Q. Do , Brad C. Bailey , Matthew D. Christianson , Jeffrey C. Munro , Edmund M. Carnahan
IPC分类号: C08F297/08 , C08F4/64
摘要: The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, (C) an activator, and (D) a chain shuttling agent.
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公开(公告)号:US20220025085A1
公开(公告)日:2022-01-27
申请号:US17311530
申请日:2019-12-19
发明人: Andrew M. Camelio , Endre Szuromi , David D. Devore , Robert DJ Froese , Brad C. Bailey , Matthew D. Christianson , Sukrit Mukhopadhyay , Jerzy Klosin
IPC分类号: C08F210/16 , C07F7/00
摘要: Catalyst systems that include a chain transfer agent and a metal-ligand complex according to formula (I).
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公开(公告)号:US20200277411A1
公开(公告)日:2020-09-03
申请号:US16089008
申请日:2017-03-30
IPC分类号: C08F4/64 , C08F2/38 , C08F210/16
摘要: Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R1 and R10 is a (C6-C40)aryl, substituted (C6-C40)aryl, (C3-C40)heteroaryl, or substituted (C3-C40)heteroaryl; each R2, R3, R4, R7, R8, and R9 is a hydrogen; (C1-C40)hydrocarbyl; substituted (C1-C40)hydrocarbyl; (C1-C40)heterohydrocarbyl; substituted (C1-C40)heterohydrocarbyl; halogen; or nitro (NO2) group; and each R5 and R6 is a (C1-C)alkyl; substituted (C1-C40)alkyl; or [(Si)1—(C+Si)40] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.
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公开(公告)号:US20180066129A1
公开(公告)日:2018-03-08
申请号:US15557627
申请日:2016-03-14
发明人: Mohamed Esseghir , Yichi Zhang , Brad C. Bailey , Yi Jin , Selim Yalvac
CPC分类号: C08L23/06 , B01J31/22 , B01J2231/20 , C08F2500/17 , C08L23/0815 , C08L23/14 , C08L2201/08 , C08L2205/02 , C08L2205/025 , C08L2207/324 , G02B6/441 , G02B6/4413 , G02B6/443 , G02B6/4434 , G02B6/4436 , G02B6/4483 , G02B6/4494 , H01B3/20 , H01B3/28 , H01B3/441
摘要: Flooding compounds for telecommunications cables. Such flooding compounds contain a polymeric filler and a branched olefinic fluid. The branched olefinic fluid has an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. Additionally, the average number of carbons per molecule in the branched olefinic fluid is from 25 to 200.
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公开(公告)号:US09643900B2
公开(公告)日:2017-05-09
申请号:US14893732
申请日:2014-06-24
发明人: Daniel J. Arriola , Brad C. Bailey , Jerzy Klosin , Zenon Lysenko , Gordon R. Roof , Austin J. Smith
IPC分类号: C07C2/34 , C08F10/00 , C10M105/00 , B01J31/00 , C10M107/02 , C10M107/04 , C10M107/10
CPC分类号: C07C2/34 , B01J31/00 , C07C2531/22 , C08F10/00 , C10M105/00 , C10M107/02 , C10M107/04 , C10M107/10 , C10M2203/02 , C10M2205/0225 , C10M2205/0285 , C10N2220/028 , C10N2250/10 , C10N2270/00 , C07C11/02 , C08F10/02 , C08F4/64193 , C08F110/02 , C08F2500/02
摘要: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.
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公开(公告)号:US08936900B2
公开(公告)日:2015-01-20
申请号:US13624579
申请日:2012-09-21
IPC分类号: G03F7/004 , C07C43/02 , C07C309/00
CPC分类号: C07C67/29 , C07C69/76 , G03F7/0392
摘要: A molecular glass compound comprises a vinyl ether adduct of an aromatic vinyl ether of formula C(R1)2═C(R2)—O-(L)n-Ar1, and a calix[4]arene, wherein R1 and R2 are each independently a single bond, H, C1-20 alkyl, C1-20 haloalkyl, C6-20 aryl, C6-20 haloaryl, C7-20 aralkyl, or C7-20 haloaralkyl, L is a C1-20 linking group, n is 0 or 1, and Ar1 is a halo-containing monocyclic, or substituted or unsubstituted polycyclic or fused polycyclic C6-20 aromatic-containing moiety, wherein R1 and R2 are connected to Ar1 when either or both of R1 and R2 is a single bond and n is 0. A photoresist, comprising the molecular glass compound, a solvent, and a photoacid generator, a coated substrate, comprising (a) a substrate having one or more layers to be patterned on a surface thereof; and (b) a layer of a photoresist composition over the one or more layers to be patterned, and a method of forming the molecular glass compound, are also disclosed.
摘要翻译: 分子玻璃化合物包括式C(R 1)2 = C(R 2)-O-(L)n -Ar 1的芳族乙烯基醚和杯[4]芳烃的乙烯基醚加合物,其中R 1和R 2各自 独立地单键,H,C 1-20烷基,C 1-20卤代烷基,C 6-20芳基,C 6-20卤代芳基,C 7-20芳烷基或C 7-20卤代烷基,L是C 1-20连接基团,n是0 或1,并且Ar 1是含卤素的单环或取代或未取代的多环或稠合多环C 6-20芳族部分,其中当R 1和R 2中的任一个或两个为单键时,R 1和R 2连接到Ar 1,n 包括分子玻璃化合物,溶剂和光致酸产生剂的涂覆基材,包括(a)在其表面上具有待图案化的一层或多层的基材; 和(b)一层或多层待图案化的光致抗蚀剂组合物层,以及形成分子玻璃化合物的方法。
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公开(公告)号:US12104002B2
公开(公告)日:2024-10-01
申请号:US17437275
申请日:2020-03-19
发明人: Andrew M. Camelio , Brad C. Bailey , Tomas D. Paine , Sukrit Mukhopadhyay , Matthew D. Christianson
IPC分类号: C08F210/02 , C08F2/04 , C08F2/16 , C08F4/659 , C08F210/16
CPC分类号: C08F4/65908 , C08F2/04 , C08F210/16
摘要: Processes for polymerizing polyolefins include contacting ethylene and optionally one or more (C3-C12)α-olefin in the presence of a catalyst system, wherein the catalyst system comprises a metal-ligand complex having a structure according to formula (I):
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公开(公告)号:US20230348641A1
公开(公告)日:2023-11-02
申请号:US17796531
申请日:2021-01-29
发明人: Rhett A. Baillie , Philip P. Fontaine , Johnathan E. DeLorbe , Rafael Huacuja , Evelyn Auyeung , Jerzy Klosin , Robert David Grigg , Sudipta Pal , Brad C. Bailey
IPC分类号: C08F210/16 , C08F4/54
CPC分类号: C08F210/16 , C08F4/545
摘要: Embodiments of this disclosure are directed to polymerization process comprising contacting ethylene and optionally one or more α-olefins in solution in the presence of one or more catalyst systems and a chain transfer agent, wherein the catalyst system comprises a metal-ligand complex according to formula (I).
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公开(公告)号:US20230133760A1
公开(公告)日:2023-05-04
申请号:US17796560
申请日:2021-01-29
发明人: Rhett A. Baillie , Philip P. Fontaine , Jerzy Klosin , Todd D. Senecal , Johnathan E. DeLorbe , Rafael Huacuja , Evelyn Auyeung , Robert David Grigg , Sudipta Pal , Brad C. Bailey
摘要: Embodiments of this disclosure are directed to catalyst systems comprising a metal-ligand complex according to formula (I).
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10.
公开(公告)号:US20220332858A1
公开(公告)日:2022-10-20
申请号:US17636048
申请日:2020-08-18
发明人: Theodor Agapie , Shuoyan Xiong , Brad C. Bailey , Heather A. Spinney , Alex J. Nett , David R. Wilson , Jerzy Klosin
IPC分类号: C08F4/70 , C08F210/02
摘要: Processes of polymerizing olefin monomers using catalyst systems and catalysts systems that include a procatalyst having a structure according to formula (I): (I).
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