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公开(公告)号：US09643900B2
公开(公告)日：2017-05-09
申请号：US14893732
申请日：2014-06-24
Applicant: Dow Global Technologies LLC
Inventor： Daniel J. Arriola , Brad C. Bailey , Jerzy Klosin , Zenon Lysenko , Gordon R. Roof , Austin J. Smith
IPC: C07C2/34 , C08F10/00 , C10M105/00 , B01J31/00 , C10M107/02 , C10M107/04 , C10M107/10
CPC classification number: C07C2/34 , B01J31/00 , C07C2531/22 , C08F10/00 , C10M105/00 , C10M107/02 , C10M107/04 , C10M107/10 , C10M2203/02 , C10M2205/0225 , C10M2205/0285 , C10N2220/028 , C10N2250/10 , C10N2270/00 , C07C11/02 , C08F10/02 , C08F4/64193 , C08F110/02 , C08F2500/02
Abstract: A process to prepare a relatively inexpensive utility fluid comprises contacting together ethylene and a coordination-insertion catalyst and, optionally, an alpha-olefin, in a continuously-fed backmixed reactor zone under conditions such that a mixture of a hyperbranched oligomer and a branched oligomer is formed. The hyperbranched oligomer has an average of at least 1.5 methine carbons per oligomer molecule, and at least 40 methine carbons per one-thousand total carbons, and at least 40 percent of the methine carbons is derived from the ethylene, and the average number of carbons per molecule is from 25 to 100, and at least 25 percent of the hyperbranched oligomer molecules has a vinyl group and can be separated from the branched oligomer, which has an average number of carbons per molecule of up to 20. The coordination-insertion catalyst is characterized as having an ethylene/octene reactivity ratio up to 20 and a kinetic chain length up to 20 monomer units.
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公开(公告)号：US09416089B2
公开(公告)日：2016-08-16
申请号：US14344937
申请日：2012-09-26
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Suh Joon Han , Dirk B. Zinkweg , Zenon Lysenko
IPC: C09K5/00 , C07C59/01 , H01B3/20 , C07C51/377 , H01B3/24
CPC classification number: H01B3/20 , C07C51/367 , C07C51/377 , C07C59/01 , H01B3/24
Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized 12-hydroxy stearic acid having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein 12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form an alkyl-12-hydroxy stearate, followed by esterification thereof with a linear or branched C4-C20 carboxylic acid. This acid may be a free acid chloride, a fatty acid, a carboxylic acid anhydride, or combination thereof. The resulting functionalized 12-hydroxy stearic acid exhibits improved thermoxidative capability, low temperature flowability, and increased fire point.
Abstract translation: 用于电气设备的电介质流体组合物包括具有所需性质的功能化的12-羟基硬脂酸，其包括倾点小于-30℃和大于250℃的点。其可以通过以下方法制备：其中将12-羟基 甲基硬脂酸酯通过与C 3 -C 20醇反应以酯交换形成烷基-12-羟基硬脂酸酯，然后用直链或支链C 4 -C 20羧酸酯化。 该酸可以是游离酰氯，脂肪酸，羧酸酐或其组合。 得到的功能化的12-羟基硬脂酸表现出改善的热氧化能力，低温流动性和增加的火点。
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3.发明申请PROCESSES FOR PREPARING CARBON FIBERS USING SULFUR TRIOXIDE IN A HALOGENATED SOLVENT 有权用三氯化硫在硫化氢溶液中制备碳纤维的方法公开(公告)号：US20150197878A1
公开(公告)日：2015-07-16
申请号：US14413456
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Jasson T. Patton , Bryan E. Barton , Mark T. Bernius , Xiaoyun Chen , Eric J. Hukkanen , Christina A. Rhoton , Zenon Lysenko
IPC: D01F9/21
CPC classification number: D01F9/21 , D01F9/14 , D06M11/55 , D06M2101/20
Abstract: Disclosed here are processes for preparing carbonized polymers (preferably carbon fibers), comprising sulfonating a polymer with a sulfonating agent that comprises SO3 dissolved in a solvent to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of the solvent is at least 95° C.; and carbonizing the resulting product by heating it to a temperature of 500-3000° C. Carbon fibers made according to these methods are also disclosed herein.
Abstract translation: 这里公开了制备碳化聚合物（优选碳纤维）的方法，包括用包含溶解在溶剂中的SO 3的磺化剂磺化聚合物以形成磺化聚合物; 用加热的溶剂处理磺化聚合物，其中溶剂的温度为至少95℃。 并将所得产物加热至500-3000℃的温度进行碳化。本文还公开了根据这些方法制备的碳纤维。
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公开(公告)号：US20140346414A1
公开(公告)日：2014-11-27
申请号：US14344937
申请日：2012-09-26
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Suh Joon Han , Dirk B. Zinkweg , Zenon Lysenko
IPC: C07C59/01 , H01B3/24 , C07C51/377 , H01B3/20
CPC classification number: H01B3/20 , C07C51/367 , C07C51/377 , C07C59/01 , H01B3/24
Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized 12-hydroxy stearic acid having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein 12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form an alkyl-12-hydroxy stearate, followed by esterification thereof with a linear or branched C4-C20 carboxylic acid. This acid may be a free acid chloride, a fatty acid, a carboxylic acid anhydride, or combination thereof. The resulting functionalized 12-hydroxy stearic acid exhibits improved thermoxidative capability, low temperature flowability, and increased fire point.
Abstract translation: 用于电气设备的电介质流体组合物包括具有所需性质的功能化的12-羟基硬脂酸，其包括倾点小于-30℃和大于250℃的点。其可以通过以下方法制备：其中将12-羟基 甲基硬脂酸酯通过与C 3 -C 20醇反应以酯交换形成烷基-12-羟基硬脂酸酯，然后用直链或支链C 4 -C 20羧酸酯化。 该酸可以是游离酰氯，脂肪酸，羧酸酐或其组合。 得到的功能化的12-羟基硬脂酸表现出改善的热氧化能力，低温流动性和增加的火点。
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公开(公告)号：US09601231B2
公开(公告)日：2017-03-21
申请号：US14362420
申请日：2012-11-28
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Jerzy Klosin , Zenon Lysenko , Suh Joon Han
CPC classification number: H01B3/22 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F4/64193 , C08F210/16 , C08F210/14 , C08F2500/02 , C08F110/14
Abstract: The present invention generally relates to a dielectric composition which is a poly-α-olefin or poly(co-ethylene-α-olefin) having a backbone weight average molecular weight less than 10,000 daltons. The dielectric composition uses a metal-ligand complex as a precatalyst and exhibits a hyperbranched structure that enables low viscosity, and therefore good flow characteristics, combined with high fire point due to ability to increase molecular weight via branching rather than backbone growth. Other desirable properties include lowered pour point due to crystallization disruption, and desirable thermal oxidative stability.
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Patent Agency Ranking
公开(公告)号：US20160260517A1
公开(公告)日：2016-09-08
申请号：US15156795
申请日：2016-05-17
Applicant: Dow Global Technologies LLC
Inventor： Suh Joon Han , Dirk B. Zinkweg , Zenon Lysenko
IPC: H01B3/20 , C07C51/367
CPC classification number: H01B3/20 , C07C51/367 , C07C51/377 , C07C59/01 , H01B3/24
Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized 12-hydroxy stearic acid having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein 12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form an alkyl-12-hydroxy stearate, followed by esterification thereof with a linear or branched C4-C20 carboxylic acid. This acid may be a free acid chloride, a fatty acid, a carboxylic acid anhydride, or combination thereof. The resulting functionalized 12-hydroxy stearic acid exhibits improved thermoxidative capability, low temperature flowability, and increased fire point.
Abstract translation: 用于电气设备的电介质流体组合物包括具有所需性质的功能化的12-羟基硬脂酸，其包括倾点小于-30℃和大于250℃的点。其可以通过以下方法制备：其中将12-羟基 甲基硬脂酸酯通过与C 3 -C 20醇反应以酯交换形成烷基-12-羟基硬脂酸酯，然后用直链或支链C 4 -C 20羧酸酯化。 该酸可以是游离酰氯，脂肪酸，羧酸酐或其组合。 得到的功能化的12-羟基硬脂酸表现出改善的热氧化能力，低温流动性和增加的火点。
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公开(公告)号：US09228276B2
公开(公告)日：2016-01-05
申请号：US14413457
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Bryan E. Barton , Zenon Lysenko , Mark T. Bernius , Eric J. Hukkanen
Abstract: Disclosed herein are processes for preparing carbonized polymers, such as carbon fibers, comprising: sulfonating a polymer with a sulfonating agent that comprises SO3 gas to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of said solvent is at least 95° C.; and carbonizing the resulting product by heating it to a temperature of 500-3000° C.
Abstract translation: 本文公开了制备碳化聚合物如碳纤维的方法，其包括：用包含SO 3气体的磺化剂磺化聚合物以形成磺化聚合物; 用加热的溶剂处理磺化聚合物，其中所述溶剂的温度为至少95℃。 并将所得产物加热至500-3000℃的温度进行碳化。
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8.发明授权Processes for preparing carbon fibers using sulfur trioxide in a halogenated solvent 有权在卤化溶剂中使用三氧化硫制备碳纤维的方法公开(公告)号：US09222201B2
公开(公告)日：2015-12-29
申请号：US14413456
申请日：2013-07-03
Applicant: Dow Global Technologies LLC
Inventor： Jasson T. Patton , Bryan E. Barton , Mark T. Bernius , Xiaoyun Chen , Eric J. Hukkanen , Christina A. Rhoton , Zenon Lysenko
IPC: D01F9/21 , D06M11/55 , D01F9/14 , D06M101/20
CPC classification number: D01F9/21 , D01F9/14 , D06M11/55 , D06M2101/20
Abstract: Disclosed here are processes for preparing carbonized polymers (preferably carbon fibers), comprising sulfonating a polymer with a sulfonating agent that comprises SO3 dissolved in a solvent to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of the solvent is at least 95° C.; and carbonizing the resulting product by heating it to a temperature of 500-3000° C. Carbon fibers made according to these methods are also disclosed herein.
Abstract translation: 这里公开了制备碳化聚合物（优选碳纤维）的方法，包括用包含溶解在溶剂中的SO 3的磺化剂磺化聚合物以形成磺化聚合物; 用加热的溶剂处理磺化聚合物，其中溶剂的温度为至少95℃。 并将所得产物加热至500-3000℃的温度进行碳化。本文还公开了根据这些方法制备的碳纤维。
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公开(公告)号：US09793027B2
公开(公告)日：2017-10-17
申请号：US15156795
申请日：2016-05-17
Applicant: Dow Global Technologies LLC
Inventor： Suh Joon Han , Dirk B. Zinkweg , Zenon Lysenko
IPC: H01B3/20 , C07C51/377 , C07C59/01 , H01B3/24 , C07C51/367
CPC classification number: H01B3/20 , C07C51/367 , C07C51/377 , C07C59/01 , H01B3/24
Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized 12-hydroxy stearic acid having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein 12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form an alkyl-12-hydroxy stearate, followed by esterification thereof with a linear or branched C4-C20 carboxylic acid. This acid may be a free acid chloride, a fatty acid, a carboxylic acid anhydride, or combination thereof. The resulting functionalized 12-hydroxy stearic acid exhibits improved thermoxidative capability, low temperature flowability, and increased fire point.
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10.发明授权Synthetic ester-based dielectric fluid compositions for enhanced thermal management 有权用于增强热管理的合成酯基介电流体组合物公开(公告)号：US09330810B2
公开(公告)日：2016-05-03
申请号：US14348360
申请日：2012-09-26
Applicant: Dow Global Technologies LLC
Inventor： Suh Joon Han , Dirk B. Zinkweg , Zenon Lysenko
Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized methyl-12-carboxy methyl stearate having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein methyl-12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form the hydroxy methyl ester, followed by reaction with a linear or branched C4-C20 carboxylic acid selected from free acid chlorides, fatty acids, carboxylic acid anhydrides, and combinations thereof. The second step serves to end-cap the hydroxyl groups, thereby producing the functionalized methyl-12-carboxy methyl stearate compound that exhibits improved thermoxidative stability and low temperature flowability, as well as increased fire point.
Abstract translation: 用于电气设备的介电流体组合物包括官能化的甲基-12-羧甲基硬脂酸酯，其具有包括倾点小于-30℃和高于250℃的点的所需性质。其可以通过以下方法制备：其中甲基 -12-羟基甲基硬脂酸酯通过与C 3 -C 20醇反应来酯交换以形成羟甲基酯，然后与选自游离酰氯，脂肪酸，羧酸酐的直链或支链C 4 -C 20羧酸反应，和 其组合。 第二步用于封端羟基，从而产生表现出改善的热氧稳定性和低温流动性以及增加的火点的官能化甲基-12-羧甲基硬脂酸酯化合物。
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