A metal sheet for separators of polymer electrolyte fuel cells having both excellent corrosion resistance in the use environment of separators of polymer electrolyte fuel cells and excellent adhesion property between a substrate and a surface-coating layer even in the case where the surface-coating layer is made thinner is provided. A metal sheet for separators of polymer electrolyte fuel cells includes: a substrate made of metal; and a surface-coating layer with which the substrate is coated, with a strike layer in between, wherein a coating weight of the strike layer is 0.001 g/m2 to 1.0 g/m2.