The present application relates to a gel polymer electrolyte and an electrochemical device comprising the gel polymer electrolyte. The gel polymer electrolyte according to the present application comprises a polymer film and an organic electrolytic solution comprising a lithium salt, a phosphate ester compound, and a fluoroether compound. The gel polymer electrolyte according to the present application has higher ionic conductivity and better electrochemical stability, and is capable of significantly improving the safety and cycle performance of the electrochemical device.