- 专利标题: PROCESS FOR THE PRODUCTION OF POLYESTER COPOLYMERS
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申请号: US18294888申请日: 2022-08-01
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公开(公告)号: US20240336731A1公开(公告)日: 2024-10-10
- 发明人: Bing WANG , Gerardus Johannes Maria Gruter , Robert-Jan VAN PUTTEN
- 申请人: Avantium Knowledge Centre B.V.
- 申请人地址: NL Amsterdam
- 专利权人: Avantium Knowledge Centre B.V.
- 当前专利权人: Avantium Knowledge Centre B.V.
- 当前专利权人地址: NL Amsterdam
- 优先权: EP 189198.1 2021.08.02
- 国际申请: PCT/EP2022/071578 2022.08.01
- 进入国家日期: 2024-02-02
- 主分类号: C08G63/80
- IPC分类号: C08G63/80 ; C08G63/183 ; C08G63/672 ; C08G63/85 ; C08G63/91
摘要:
A polymerization process for the production of a polyester copolymer A comprising simultaneously reacting a polyester (i) with one or more diols (ii) and one or more (hetero) aromatic dicarboxylic acids or any esters thereof (iii), wherein the polyester (i) is polyethylene terephthalate, polyethylene furanoate or polyethylene terephthalate-co-furanoate; and wherein no ethylene glycol is added as a diol (ii); and wherein at least one of the one or more diols (ii) is selected from (bi) cyclic secondary diols; and wherein the components (i) and (ii) are used in sufficient quantities to produce a polyester copolymer A comprising at least 40 mole % of ethylene glycol derived from the starting polyethylene terephthalate, polyethylene furanoate or polyethylene terephthalate-co-furanoate, and at least 5 mole %, of monomers derived from said (bi) cyclic secondary diol(s), the percentages based on the total amount of diol-derived monomer units in polyester copolymer A.
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