发明授权
- 专利标题: Unsaturated acrylic acid-oxazoline reaction products
- 专利标题(中): 不饱和丙烯酸 - 恶唑啉反应产物
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申请号: US537215申请日: 1974-12-30
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公开(公告)号: US4016192A公开(公告)日: 1977-04-05
- 发明人: Donald A. Tomalia , Bruce P. Thill , Thomas W. Regulski
- 申请人: Donald A. Tomalia , Bruce P. Thill , Thomas W. Regulski
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C08J5/12
- IPC分类号: C08J5/12 ; C07C101/00
摘要:
Ethylenically-unsaturated products are obtained by (a) reacting acrylic acid and 2-oxazoline or a 2-alkyl or aryl-2-oxazoline in an inert liquid reaction medium and (b) recovering the desired product from (a) by heating the reaction mixture under reduced pressure to strip away the liquid diluent and volatile components, thus leaving the desired product as a non-volatile residue. The reaction products can be cross-linked by conventional techniques (e.g. freeradical initiation) to form useful coatings and adhesives. For example, the product produced by heating equal molar amounts of acrylic acid and 2-ethyl-2-oxazoline in benzene gave an ethylenically-unsaturated oligomeric product having a number average molecular weight of 253 and a weight average molecular weight of 460 in approximately 95 percent yield.
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