发明授权
- 专利标题: Block copolyesters which crystallize rapidly
- 专利标题(中): 封闭共聚酯快速结晶
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申请号: US875047申请日: 1978-02-03
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公开(公告)号: US4207230A公开(公告)日: 1980-06-10
- 发明人: Peter Bier , Rudolf Binsack
- 申请人: Peter Bier , Rudolf Binsack
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX2706124 19770201
- 主分类号: C08G63/00
- IPC分类号: C08G63/00 ; C08G63/18 ; C08G63/181 ; C08G63/183 ; C08G63/66 ; C08G63/672 ; C08G63/78 ; C08G63/91 ; C08L67/02 ; C08L71/02
摘要:
The current invention is concerned with block copolyesters of low glass transition temperature segments and ethylene glycol based polyester segments linked together by carboxylic acid ester groups and special diols, and a process for preparing these copolyesters. These copolyesters display molded resin properties similar to polyethylene terephthalate but crystallization behavior similar to polybutylene terephthalate, i.e. they have high strength and superior solvent resistance, but they also crystallize rapidly. They are made by subjecting low glass transition temperature (less than 0.degree. C.) polymers with carboxyl, hydroxyl or reactive ester end groups to esterification or transesterification conditions with ethylene glycol based polyester segments having a minimum intrinsic viscosity of 0.2 dl/g and special diols having four to ten carbon atoms with 3 or 4 carbon atoms between the hydroxyl groups in the presence of appropriate catalysts. In a preferred embodiment, the three components are subject to melt homogenization in an extruder and the solidified extrudate is subject to a solid state polycondensation reaction.
公开/授权文献
- US6063637A Sensors for sugars and other metal binding analytes 公开/授权日:2000-05-16
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