发明授权
- 专利标题: Intermediates for preparation of 3-bromo-4-fluoro-benzyl alcohol
- 专利标题(中): 用于制备3-溴-4-氟 - 苄醇的中间体
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申请号: US301510申请日: 1981-09-14
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公开(公告)号: US4386035A公开(公告)日: 1983-05-31
- 发明人: Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel , Rainer Fuchs , Erich Klauke
- 申请人: Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel , Rainer Fuchs , Erich Klauke
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX3036967 19801001
- 主分类号: C07C29/136
- IPC分类号: C07C29/136 ; B01J27/00 ; C07C27/00 ; C07C29/147 ; C07C33/46 ; C07C63/70 ; C07C67/00 ; C07C69/96
摘要:
A process for the preparation of 3-bromo-4-fluoro-benzyl alcohol of the formula ##STR1## comprising reacting 3-bromo-4-fluoro-benzoic acid or a derivative thereof of the formula ##STR2## in which R is a hydrogen atom, an alkyl radical or an alkoxycarbonyl radical,with a complex hydride of the formulaM(M'H.sub.4)in whichM is lithium, sodium or potassium, andM' is boron or aluminum,at a temperature between about -20.degree. and +150.degree. C. When R is alkoxycarbonyl the starting material can be produced by reacting the corresponding free acid with a chloroformic acid ester. Compounds wherein R is alkyl or alkoxycarbonyl are new. The end product is a known intermediate for insecticides.