发明授权
US4457871A Preparation of trans cyclohexane,1,4-diisocyanate and related compounds
失效
制备反式环己烷,1,4-二异氰酸酯及相关化合物
- 专利标题: Preparation of trans cyclohexane,1,4-diisocyanate and related compounds
- 专利标题(中): 制备反式环己烷,1,4-二异氰酸酯及相关化合物
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申请号: US420185申请日: 1982-09-20
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公开(公告)号: US4457871A公开(公告)日: 1984-07-03
- 发明人: Hans Zengel , Manfred Bergfeld
- 申请人: Hans Zengel , Manfred Bergfeld
- 申请人地址: NC Asheville
- 专利权人: Akzona Incorporated
- 当前专利权人: Akzona Incorporated
- 当前专利权人地址: NC Asheville
- 优先权: DEX27105959 19720311
- 主分类号: C07C271/24
- IPC分类号: C07C271/24 ; C07C67/00 ; C07C209/00 ; C07C209/56 ; C07C211/36 ; C07C231/00 ; C07C231/02 ; C07C235/58 ; C07C239/00 ; C07C241/00 ; C07C263/06 ; C07C265/00 ; C07C265/14 ; C07C273/18 ; C07C275/04 ; C07C275/26 ; C07C311/56 ; C07D295/20 ; C07C118/00 ; C07C119/045
摘要:
A process is disclosed for selectively making trans-cyclohexane-1,4-diisocyanate, trans-cyclohexane-1,4-diamine, a trans-cyclohexane-1,4-diurethane, a trans-cyclohexane-1,4-diurea and trans-cyclohexane-1,4-disulphonyl urea by reacting ammonia with a mixture of cis and trans cyclohexane-1,4-dicarboxylic acid, a lower alkyl ester, a glycol ester, an oligomeric ester or a polyester to make a solid trans-dicarboxylic acid diamide in a first step. The diamide is chlorinated to form trans-cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide. The latter compound is then converted into a(a) trans-cyclohexane-1,4-diamine with an alkali metal hydroxide or alkaline earth metal hydroxide; or into a(b) a trans-cyclohexane-1,4-diurethane by reaction with an alcohol or glycol in a reaction mixture containing an alkali metal hydroxide or alkaline earth metal hydroxide; or into(c) a trans-cyclohexane-1,4-diurea by reaction with a primary or secondary amine in a reaction mixture containing an alkali metal hydroxide or alkaline earth metal hydroxide; or into a(d) trans-cyclohexane-1,4-sulphonyl urea by reaction with a primary sulphonamide in a reaction mixture containing an alkali metal hydroxide and dimethyl formamide and water. The diurea prepared in (c) may be converted into trans-cyclohexane-1,4-diisocyanate with gaseous hydrogen chloride in an inert solvent. The diurethane prepared in (b) and the disulphonyl urea prepared in (d) may be thermally decomposed into trans-cyclohexane-1,4-diisocyanate.
公开/授权文献
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