公开(公告)号：US07423183B2

公开(公告)日：2008-09-09

申请号：US10558162

申请日：2004-03-31

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C07C319/00 ,  C07C321/00 ,  C07C323/00 ,  C07C381/00

CPC分类号： B01J31/0237 ,  B01J27/24 ,  B01J31/04 ,  B01J31/28 ,  B01J31/32 ,  B01J2231/70 ,  C07C319/24 ,  C07C323/12

摘要： A process for preparing dihydroxyethylene disulfide by reacting mercaptoethanol with oxygen, in which mercaptoethanol is reacted with oxygen or an oxygenous gas in the presence of ammonia and/or amines using copper salts or manganese salts.

摘要翻译： 巯基乙醇与氧反应制备二羟基亚乙基二硫化物的方法，其中巯基乙醇在氨和/或胺的存在下与氧或氧气反应，使用铜盐或锰盐。

公开(公告)号：US20070249860A1

公开(公告)日：2007-10-25

申请号：US11664353

申请日：2005-09-16

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C07C321/14

CPC分类号： C08G18/6453

摘要： The invention relates to a method for production of polymeric hydroxylalkyl terminated polysulphides, whereby monomeric hydroxylalkyl terminated polysulphides are reacted with formaldehyde in the presence of an acid catalyst in the form of a solid acid, in particular, an acidic ion exchanger, in which the reaction water and optional added solvent and catalyst are separated off. The products are characterized by a very high uniformity (low polydispersity) and can advantageously be functionalized with subsequent reactions.

摘要翻译： 本发明涉及一种生产聚合羟基烷基封端的多硫化物的方法，其中单体羟基烷基封端的多硫化物在酸催化剂存在下与甲醛反应，其形式为固体酸，特别是酸性离子交换剂，其中反应 水和任选的添加溶剂和催化剂被分离出来。 产物的特征在于非常高的均匀性（低分散性），并且可以有利地随后续反应而官能化。

公开(公告)号：US20050131207A1

公开(公告)日：2005-06-16

申请号：US10507418

申请日：2003-03-08

申请人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

发明人： Michael Zeitler ,  Nils Kottner ,  Manfred Bergfeld

IPC分类号： C08G59/02 ,  C08L81/04 ,  C08F8/08

CPC分类号： C08G59/02 ,  C08G2650/02 ,  C08L81/04

摘要： Disclosed is a method for producing polymeric polysulfides containing terminal epoxy groups, according to which polysulfides containing terminal thiol groups are reacted with an excess of epichlorohydrin and alkaline lye, water is azeotropically distilled away with epichlorohydrin, the epichlorohydrin-containing epoxidized polysulfide solution is separated from the eliminated salt, the epichlorohydrin is distilled away, and the residue is optionally purified by means of thin film distillation. The reaction product is particularly suitable for the production of high-quality sealants, adhesives, and coatings. Said product has a high degree of purity and an extremely low chlorine content. The inventive method does not require any additional organic solvents and is very environmentally friendly.

摘要翻译： 公开了一种含有末端环氧基的聚合多硫化物的方法，根据该方法，含有末端巯基的多硫化物与过量的表氯醇和碱性碱液反应，将水与表氯醇共沸蒸馏掉，将含表氯醇的环氧化多硫化物溶液与 除去的盐，表氯醇被蒸馏除去，并且残余物任选地通过薄膜蒸馏进行纯化。 反应产物特别适用于生产高质量的密封剂，粘合剂和涂料。 所述产品具有高纯度和极低的氯含量。 本发明的方法不需要任何额外的有机溶剂，并且是非常环境友好的。

公开(公告)号：US6166232A

公开(公告)日：2000-12-26

申请号：US180942

申请日：1998-12-08

申请人： Manfred Bergfeld ,  Hartmut Ahrens ,  Axel Carstens

发明人： Manfred Bergfeld ,  Hartmut Ahrens ,  Axel Carstens

IPC分类号： B01J27/16 ,  C07B61/00 ,  C07C213/06 ,  C07C219/06 ,  C07C219/08 ,  C07F9/02

CPC分类号： C07C213/06

摘要： A process is described for producing ester quats of the formula (I) ##STR1## where X.sup.- is an anion of an inorganic or organic acid, R.sub.a is a C.sub.1 to C.sub.4 alkyl group, R.sub.b and R.sub.c are each, independently of one another, a C.sub.1 to C.sub.3 alkylene group, and R.sub.d is a C.sub.1 to C.sub.22 fragment of a saturated and/or unsaturated aliphatic carboxylic acid, m, n, p, and q are integers, m has a value from 1 to 3, n a value from 0 to 3, p a value from 0 to 1, m+n+p=4, and q has the value 1 or, if m=3, n=0, and p=1, the value 2, in which process a quaternary compound of the formula (II) ##STR2## where X.sup.-, R.sub.a, R.sub.b, R.sub.c, m, n, p, and q have the above meanings, is esterified, in the presence of an oxo acid of phosphorus and/or one of its alkali or alkaline-earth salts as a catalyst, with a saturated and/or unsaturated C.sub.1 to C.sub.22 carboxylic acid, alone or in a mixture, while withdrawing water.

摘要翻译： PCT No.PCT / EP97 / 02941 Sec。 371日期1998年12月8日第 102（e）日期1998年12月8日PCT提交1997年6月6日PCT公布。 第WO97 / 47588号公报 日本1997年12月18日描述了制备式（I）的酯季铵盐的方法，其中X是无机或有机酸的阴离子，Ra是C1-C4烷基，Rb和Rc各自独立地为一个 另一个是C1至C3亚烷基，Rd是饱和和/或不饱和脂族羧酸的C1至C22片段，m，n，p和q是整数，m具有1至3的值，na值 从0到3，pa值从0到1，m + n + p = 4，并且q具有值1，或者如果m = 3，n = 0和p = 1，则值2，其中过程a 其中X，Ra，Rb，Rc，m，n，p和q具有上述含义的式（II）的季铵化合物在磷的含氧酸和/或其碱之一的存在下被酯化 或碱土金属盐作为催化剂，同时具有饱和和/或不饱和的C1至C22羧酸，单独或混合，同时取出水。

公开(公告)号：US5977350A

公开(公告)日：1999-11-02

申请号：US149743

申请日：1998-09-08

申请人： Manfred Bergfeld ,  Ludwig Eisenhuth

发明人： Manfred Bergfeld ,  Ludwig Eisenhuth

IPC分类号： C07H1/00 ,  C07C51/235 ,  C07C51/31 ,  C07C59/105 ,  C07C59/265 ,  C07C59/285 ,  C07H3/02 ,  C07C17/00 ,  C13K13/00

CPC分类号： C07C51/313

摘要： A process is provided for preparing polyhydroxycarboxylic acids by the selective oxidation of di-, tri-, oligo- and polysaccharides in an alkaline medium using an oxygenous gas in the presence of palladium on a carrier as catalyst and bismuth as promoter at a palladium concentration in the reaction mixture of at least about 40 mg/l and a molar ratio of bismuth to palladium in the range of from about 1:5 to about 1:40, in which process towards the end of the reaction, as soon as a strong increase is observed in the oxygen concentration in the liquid phase, the oxygen supply is reduced until it is not more than about 20 ppm. In this manner, virtually all of the polysaccharide added beforehand is converted into the desired end product without an unacceptably high concentration of bismuth in the end product.

摘要翻译： 提供了一种制备多羟基羧酸的方法，其通过在载体作为催化剂的钯存在下使用含氧气体在碱性介质中选择性氧化二羟基，三 - ，寡 - 和多糖，并以钯浓度将铋作为助催化剂 反应混合物至少约40mg / l，铋与钯的摩尔比在约1:5至约1:40的范围内，其中在反应结束的过程中，一旦强烈增加 在液相中的氧浓度中观察到，供氧减少直到不超过约20p​​pm。 以这种方式，预先添加的几乎所有的多糖都转化成所需的最终产物，而在最终产物中不会有不可接受的高浓度的铋。

公开(公告)号：US5015752A

公开(公告)日：1991-05-14

申请号：US732299

申请日：1985-05-09

申请人： Manfred Bergfeld

发明人： Manfred Bergfeld

IPC分类号： C07C333/32 ,  B01J23/10 ,  B01J23/22 ,  B01J23/28 ,  B01J23/34 ,  B01J23/70 ,  B01J23/889 ,  B01J31/02 ,  B01J31/04 ,  C07B61/00 ,  C07C67/00 ,  C07C325/00 ,  C07D295/21

CPC分类号： C07D295/21

摘要： A process for the production of thiuram polysulfides substituted by aliphatic, araliphatic, cycloaliphatic aromatic and/or hydrocarbon radicals is disclosed. In this process, correspondingly substituted secondary amines are reacted with carbon disulfide and sulfur in a solvent at 0.degree. to 150.degree. C. in the presence of a tertiary amine, a metal-containing catalyst and oxygen or an oxygen-containing gas.By virtue of its high purity, the product obtained by this process may be used directly, i.e., without preceeding purification, for its intended purpose, for examples as a vulcanization accelerator or sulfur donor.This process is particularly desirable for the substantially quantitative yields and selectivities and also for its high economy arising from the reaction being carried out in a single stage without expensive auxiliaries and from the elimination of an additional purification step.

摘要翻译： 公开了由脂族，芳脂族，脂环族芳族和/或烃基取代的秋兰姆多硫化物的生产方法。 在该方法中，在叔胺，含金属的催化剂和氧气或含氧气体的存在下，相应地取代的仲胺在0℃至150℃的溶剂中与二硫化碳和硫反应。 由于其高纯度，通过该方法获得的产物可以直接使用，即不经纯化，用于其预期目的，例如作为硫化促进剂或硫供体。 该方法对于基本上定量的产率和选择性以及由于反应在单一阶段中进行而没有昂贵的助剂和从另外的纯化步骤的消除而产生的高经济性是特别希望的。

公开(公告)号：US4853475A

公开(公告)日：1989-08-01

申请号：US911364

申请日：1986-09-25

申请人： Manfred Bergfeld ,  Ludwig Eisenhuth

发明人： Manfred Bergfeld ,  Ludwig Eisenhuth

IPC分类号： C07C333/16 ,  C07C67/00 ,  C07C325/00 ,  C07F11/00 ,  C07F13/00

CPC分类号： C07C333/16

摘要： The invention relates to a process for synthesizing alkylene bisdithiocarbamates or the ammonia adducts thereof as well as mixtures that can be synthesized thereby. The starting materials are carbon disulfide, ammonia, a diamine and a metal oxide, which may be manganese(II) oxide, or the hydrate or hydroxide thereof. The metal oxide, its hydrate or hydroxide thereof is allowed to react either with a mixture syntheiszed from an alkylenediamine, carbon disulfide and ammonia in water, or with an aqueous solution of the ammonium alkylene bisdithiocarbamate. The concentration of the individual starting materials both relative to each other and to water is of prime importances as to which compounds in particular are ultimately obtained.

摘要翻译： 本发明涉及一种合成亚二烷基双二硫代氨基甲酸酯或其氨加成物的方法以及可由其合成的混合物。 原料是二硫化碳，氨，二胺和金属氧化物，其可以是氧化锰（II）或其水合物或氢氧化物。 使金属氧化物，其水合物或氢氧化物与由亚烷基二胺，二硫化碳和氨在水中合成的混合物或与二亚硫代氨基甲酸亚烷基亚铵的水溶液反应。 各个起始材料相对于彼此和水的浓度对于最终获得哪些化合物是重要的。

公开(公告)号：US4356289A

公开(公告)日：1982-10-26

申请号：US223720

申请日：1981-01-09

申请人： Hans-Georg Zengel ,  Manfred Bergfeld ,  Rainer Zielke

发明人： Hans-Georg Zengel ,  Manfred Bergfeld ,  Rainer Zielke

IPC分类号： C08F8/22

CPC分类号： C08F8/22

摘要： A process is disclosed for making polyfunctional N-chloramide derivatives of homo--or copolymers of acrylamide or metharylamide wherein a homo--or copolymer of acrylamide or methacrylamide is chlorinated by means of chloride in a dilute aqueous suspension of a mineral acid at a temperature of 0.degree. to 40.degree. C.

摘要翻译： 公开了一种制备丙烯酰胺或甲基丙烯酰胺的均聚或共聚物的多官能N-氯酰胺衍生物的方法，其中丙烯酰胺或甲基丙烯酰胺的均聚物或共聚物通过氯化物在无机酸的稀无水悬浮液中在0℃的温度下氯化 DEG至40℃

公开(公告)号：US4157450A

公开(公告)日：1979-06-05

申请号：US901669

申请日：1978-05-01

申请人： Hans Zengel ,  Manfred Bergfeld

发明人： Hans Zengel ,  Manfred Bergfeld

IPC分类号： C07C37/045 ,  C07C37/05 ,  C07C39/10

CPC分类号： C07C37/045 ,  C07C37/05

摘要： Phloroglucinol may be produced by converting s-triacetyl benzene to benzene-1,3,5-tris-acetoxime which is a novel compound. Said acetoxime is subjected to a Beckmann rearrangement and the resulting mixture subsequently hydrolyzed to produce phloroglucinol.

公开(公告)号：US4071555A

公开(公告)日：1978-01-31

申请号：US796109

申请日：1977-05-12

申请人： Hans Zengel ,  Manfred Bergfeld

发明人： Hans Zengel ,  Manfred Bergfeld

IPC分类号： C07C27/00 ,  C07C37/045 ,  C07C37/05 ,  C07C39/10 ,  C07C67/00 ,  C07C131/00

CPC分类号： C07C37/05 ,  C07C37/045

摘要： Phloroglucinol may be produced by converting s-triacetyl benzene to benzene-1,3,5-tris-acetoxime which is a novel compound. Said acetoxime is subjected to a Beckmann rearrangement and the resulting mixture subsequently hydrolyzed to produce phloroglucinol.