发明授权
- 专利标题: Low shrinkable unsaturated polyester resin composition
- 专利标题(中): 低收缩不饱和聚酯树脂组合物
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申请号: US686145申请日: 1984-12-26
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公开(公告)号: US4593067A公开(公告)日: 1986-06-03
- 发明人: Masaharu Nakayama , Kyosuke Fukushi , Yasuo Moriya , Nobuyoshi Suzuki
- 申请人: Masaharu Nakayama , Kyosuke Fukushi , Yasuo Moriya , Nobuyoshi Suzuki
- 申请人地址: JPX Tokyo
- 专利权人: Nippon Oil and Fats Co.
- 当前专利权人: Nippon Oil and Fats Co.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX58-248289 19831228
- 主分类号: C08L53/00
- IPC分类号: C08L53/00 ; C08F283/01 ; C08F287/00 ; C08F293/00 ; C08F295/00 ; C08F299/04 ; C08L23/00 ; C08L51/00 ; C08L51/02 ; C08L67/00 ; C08L67/06 ; C08L77/00 ; C08L101/00
摘要:
Disclosed herein is a low shrinkable unsaturated polyester resin composition consisting of (A) 20-70% by weight of an unsaturated polyester, (B) 28-60% by weight of a monomer polymerizable with the above unsaturated polyester, and (C) 2-20% by weight of a block copolymer mixture. The mixtures of the monomer (B) and the block copolymer mixture (C), and a mixture of the polyester (A), the monomer (B), and the block copolymer mixture (C) are in a non-aqueous dispersion state. The block copolymer mixture is obtained by polymerizing either one of the monomers defined below in (a) and (b) with a polymerization initiator a polymeric perioxide represented by the formula: ##STR1## in which R.sub.1 represents a divalent branched hydrocarbon group having 10-30 carbons, and R.sub.2 and R.sub.3 represent a hydrogen atom, a hydroxyl group or an alkali metal, and the average polymerization degree n is 2-40, and is used to obtain a first polymer having peroxy bonds in its molecule, and block-polymerizing the first polymer with the remaining monomer (a) or (b) which has not been used in the first polymerization reaction wherein, (a) is a monomer or a monomer mixture consisting of 70-100% by weight of styrene monomer and 30-0% by weight of a monomer polymerizable therewith.(b) is a monomer or a mixture of monomers consisting of 70-100% by weight of C.sub.1-4 alkyl ester of acrylic acid or methacrylic acid and 0-30% by weight of a monomer polymerizable therewith.
公开/授权文献
- US5169714A Heat-shrinkable polypropylene film with improved printability 公开/授权日:1992-12-08
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