发明授权
- 专利标题： Ruthenium-phosphine complex
- 专利标题（中）： 钌膦络合物
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申请号： US61770申请日： 1987-06-15
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公开(公告)号： US4739085A公开(公告)日： 1988-04-19
- 发明人: Hidemasa Takaya , Tetsuo Ohta , Ryoli Noyori , Noboru Sayo , Hidenori Kumobayashi , Susumu Akutagawa
- 申请人： Hidemasa Takaya , Tetsuo Ohta , Ryoli Noyori , Noboru Sayo , Hidenori Kumobayashi , Susumu Akutagawa
- 申请人地址： JPX Tokyo
- 专利权人： Takasago Perfumery Co., Ltd.
- 当前专利权人： Takasago Perfumery Co., Ltd.
- 当前专利权人地址： JPX Tokyo
- 优先权： JPX61-184651 19860806
- 主分类号： B01J31/00
- IPC分类号： B01J31/00 ; B01J31/24 ; C07B61/00 ; C07C29/17 ; C07C51/36 ; C07F15/00 ; C07F9/50
摘要：
A ruthenium-phosphine complex represented by formula (I):[RuH.sub.l (R-BINAP).sub.m ]X.sub.n' (I)wherein R-BINAP is a tertiary phosphine represented by formula (II): ##STR1## R is a hydrogen atom or a methyl group; X is a ClO.sub.4, BF.sub.4, or PF.sub.6 ; and when l is 0, then m is 1 and n' is 2, and when l is 1, then m is 2 and n' is 1, is disclosed. The complex is inexpensive and exhibits excellent performances as a catalyst for various organic syntheses, and particularly for asymmetric hydrogenation.
公开/授权文献
- US5306226A Urinary control with inflatable seal and method of using same 公开/授权日：1994-04-26
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