Invention Grant
US5066729A Diene polymers and copolymers terminated by reaction with N-alkyl and
N-aryl imines
失效
通过与N-烷基和N-亚氨基反应终止的二烯聚合物和共聚物
- Patent Title: Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
- Patent Title (中): 通过与N-烷基和N-亚氨基反应终止的二烯聚合物和共聚物
-
Application No.: US506306Application Date: 1990-04-09
-
Publication No.: US5066729APublication Date: 1991-11-19
- Inventor: Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
- Applicant: Mark L. Stayer, Jr. , Thomas A. Antkowiak , David F. Lawson , Russell W. Koch
- Applicant Address: OH Akron
- Assignee: Bridgestone/Firestone, Inc.
- Current Assignee: Bridgestone/Firestone, Inc.
- Current Assignee Address: OH Akron
- Main IPC: C08C19/22
- IPC: C08C19/22 ; B60C1/00 ; C08C19/44 ; C08F8/30 ; C08F36/00 ; C08F36/04 ; C08F136/04 ; C08F236/10 ; C08L47/00
Abstract:
A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.
Public/Granted literature
- US5794120A Method and apparatus for default node operation in a multi-nodal communication system Public/Granted day:1998-08-11
Information query